• 제목/요약/키워드: pseudoplastic

검색결과 138건 처리시간 0.022초

밤전분 호화액의 유동특성 (Rheological Properties of Gelatinized Chestnut Starch Solution)

  • 박영희;김성곤;이신영;김주봉
    • 한국식품과학회지
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    • 제16권3호
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    • pp.314-318
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    • 1984
  • 밤전분 희석호화액$(1.2{\sim}1.8)$의 유동특성을 Brook-field(LVT) nallow gap 회전점도계를 사용하여 측정하였다. 밤전분 호화액은 전단속도 $0.349{\sim}13.576s^{-1}$의 범위에서 의가소성 유체의 거동을 보였으며, 1.65및 1.8%에서는 틱소트로픽 유체의 거동을 나타내었다. 1.65% 이상에서 전단응력의 시간의존성은 초기 5분 이내에 급격하였으며, 평형에 도달하는 시간은 약 40분이었다. 유동거동지수값은 1.5% 이하에서 평균 약0.91. 1.65% 에서는 약 0.71로 농도의 증가에 따라 의가소성의 정도가 커졌다. 점조도지수값은 농도의 증가에 따라 증가하였으며, 지수함수식으로 표시될 수 있었다. 1.5% 이하에서와 1.65%이상에서 직선의 기울기가 서로 다른 경향을 보였다. 항복응력값은 1.5%이하에서 측정 전단응력 범위에서 거의 무시할 수 있는 낮은 값으로서 농도증가에 따라 차이를 보이지 않았으나, 1.65%이상에서는 무시할 수 없는 값을 나타내었으며, 농도 증가에 따라 급격히 증가하였다. 점조도 지수와 온도변화의 관계는 아레니우스식의 형태로 표현할 수 있었으며, 밤전분 호화액(1.65%)의 활성화에너지는 5.15kcal/g.mol이었다.

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Methylobacterium organophilum에 의한 메탄올로부터 생성되는 새로운 생물고분자 (New Extracellular Biopolymer Produced by Methylobacterium organophilum from Methanol)

  • 최준호;이운택;김정회;이준식
    • 한국미생물·생명공학회지
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    • 제17권4호
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    • pp.397-402
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    • 1989
  • Methylobacterium organophilum 이 탄소원과 에너지원으로서 메탄올로부터 생성하는 새로운 다당류계 생물고분자의 화학적 성질과 물성학적 성질을 관찰하였다. 분리정제한 다당류의 분자량은 약 4-5$\times$$10^6$ dalton 정도로 고분자량을 지니고 있다. 다당류의 화학적 조성은 건조중량의 66%가 탄수화물로 구성되어 있으며 이들의 88%가 환원당으로 구성되어 있다. 특이하게 본 고분자는 건조중량의 4.7%가 단백질로 구성되어 있다. 다당류는 glucose, galactose, 그리고 mannose을 몰비로 2:3:2 함유하고 있으며 탄수화물 이외에도 pyruvic acid, uronic acid, acetic acid 등을 함유하고 있다. 정제된 다당류를 증류수에 용해시켜 농도별로 점도를 측정한 결과 비뉴톤성 성질 중 pseudoplastic 성질을 보였으며 농도가 증가함에 따라서 겉보기점도 증가가 월등히 높았다. 동일한 1% 용액의 경우 K(consistency index)값을 비교하면 xanthan gum에 비해 약 10배정도 높은 18,000 cp 값을 나타내었다.

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장섬유강화 플라스틱 복합재의 압축성형 공정에 관한 연구 -점도에 미치는 니들펀칭의 영향- (A Study on Compression Molding Process of Long Fiber Reinforced Plastic Composites -Effect of Needle Punching on Viscosity-)

  • 송기형;조선형;이용신
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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    • pp.184-187
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    • 2002
  • Compression molding was specifically developed for replacement of metal components with composites. As the mechanical properties of the products are dependent on the separation and orientation, it is important to research the fiber mat structure and molding conditions. In this study, the effects of the fiber mat structure(NP: 5, 10, 25punches/$\textrm{cm}^2$) and the mold closure speed($\dot{\textrm{h}}$=0.1, 1, 10mm/min) on the viscosity of composites were discussed. The composites is treated as a Non-Newtonian power-law fluid. The parallel-plate plastometer is used and the viscosity is obtained from the relationship between the compression load and the thickness of the specimen.

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Bacillus sp. K-1과 변이주들에 의해 생산된 Biopolymer의 물성에 미치는 온도 및 농도의 영향 (Effects of Temperature and Concentration on the Rheological Properties of the Biopolymer Produced by Bacillus sp. K-1 Strain and Mutants)

  • 정낙현;윤광섭;임무현
    • 한국식품저장유통학회지
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    • 제4권3호
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    • pp.343-349
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    • 1997
  • The rheological Voperties of biopolymers produced by Bacilli sp. K-1 and its mutant strains(KM-21, KM-83) were studied at the temperature ranges with 20∼80$^{\circ}C$, at the concenration of 2∼6%, at the pH ranges from 3.0 to 9.0 and at the shear rate of 9.3-930sec-1 The apparent viscosity of biopolymers was decreased with increasing shear rate, and thereby biopolymers showed pseudoplastic characteristics. It was found that the apparent viscosity models respected 19 temperature, concentration and both temperature and concentration were expressed by Arrhenius Model, Exponential Model and combined of the above two Models. Therefore, the apparent viscosity could be predictable by Arrhenius and Exponential Models with high R2.

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알루미나-활석계에서 알루미나의 입자 크기가 테이프 케스팅 및 소결 거동에 미치는 영향 (Effects of Particle Size of Alumina on the Behaviors of Tape Casting and Sintering of Alumina-Talc System)

  • 윤원균;김호양;이정아;김정주
    • 한국세라믹학회지
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    • 제34권12호
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    • pp.1213-1220
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    • 1997
  • Effect of particle size of alumina and amount of talc on tape casting and densification behaviors of alumina-talc system were investigated. The pseudoplastic behaviors of slurries increased with increase in amount of talc addition and decrease in alumina particle size. In case of using coarse alumina powder, densification of specimens were accelerated with increase of sintering temperature and amount of talc addition. On the contrary, fine alumina powder retarded of rearrangement of alumina particle during liquid phase sintering due to premature densification of alumina matrix region before formation of liquid phase and then densification of specimens were suppressed with increase of sintering temperature and amount of talc addition.

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시판된장의 리올로지(Rheology) 특성에 관한 연구 (Flow Properties of Doenjang)

  • 양신철;김선화
    • 한국관광식음료학회지:관광식음료경영연구
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    • 제13권1호
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    • pp.55-68
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    • 2002
  • Flow properties of doenjang samples at various total solid contents (30, 32, 34, 36, 38, 40%) were evaluated in this study. Flow properties of doenjang samples was determined by using Haake concentric cylinderical viscometer and Instron testing machine with capillary extrusion viscometer, and consistency index(K), and flow behavior index(n) was also determined from power models, and yield stress was derived form Casson models and vanes methods. Doenjang samples showed shear-thinning (pseudoplastic) fluid with small magnitude of flow behavior index(n) (n=0.30-0.55). Casson yield stress was from 2.11 to 64.02(Pa). Vane yield stress was more effective than casson yield stress in property of reactivation. Apparent viscosity was decreased with the increase in temperature and activation energy was in the range of 6.58 to 10.70 kJ/mole. From the capillary extrusion method, K and n was increased with the increase in solid content with good correlation with. The result revealed that capillary extrusion method is useful for measuring the flow properties of doenjang.

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Pseudomonas delafieldii가 생성하는 다당류의 레올로지 특성 (Rheological Properties of Biopolymer Produced by Pseudomonas delafieldii)

  • Yoo, Jin-Young;Chung, Dong-Hyo
    • 한국미생물·생명공학회지
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    • 제17권5호
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    • pp.475-480
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    • 1989
  • Pseudomonas delafieldii이 배양액으로부터 분리한 다당류 용액의 물성을 검토하였다. 본 다당류는 매우 점도가 높은 의가소성 물질로 1% 용액의 겉보기 점도는 42sec$^{-1}$에서 1769mpaㆍs이었다. 이 용액은 pH에 대한 안정성은 있으나 열 안정성은 보이지 않았다. 이 용액의 유동 활성에너지는 4.44kacl/mole 이고, 농도의존성은 double 1logarithm으로 포현되었다.

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Rheological Properties of Mycelial Broth in Submerged Culture of Aspergillus niger No. PFST-38

  • Oh, Sung-Hoon;O, Pyong-Su
    • Journal of Microbiology and Biotechnology
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    • 제3권3호
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    • pp.209-213
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    • 1993
  • The flow behavior of the mycelial broth of glucoamylase hyperproducer Asp. niger No. PFST-38 for the production of glucoamylase were studied. The mycelial broth followed Bingham-pseudoplastic flow model described by Herschel-Bulkley equation. The yield stress increased with the increase in mycelial concentration. The dependency of the consistency index and the flow behavior index on the mycelial concentration could be expressed by a linear relationship. The consistency index increased proportionally with the mycelial concentration while the flow behavior index decreased with the increase in mycelial concentration. The flow property of the broth was related to the morphological data obtain in the previous study. The changes in apparent viscosity of the broth could be expressed as a function of the hyphal thickness as shown below.

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졸-겔법을 이용한 Al2O3가 분산된 TZP 단섬유의 제조 (Fabrication of Discontinuous Al2O3-Dispersed TZP Fibers by a Sol-Gel Method)

  • 심수만
    • 한국세라믹학회지
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    • 제52권1호
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    • pp.56-60
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    • 2015
  • Discontinuous, polycrystalline $Al_2O_3$-dispersed TZP fibers were prepared by the centrifugal spinning of a colloidal $ZrO_2$ sol containing Y and Al nitrates and poly(vinyl alcohol). Factors affecting the rheological properties of the sols, such as sol concentrations, aging, and the amounts and types of additives, were investigated by measuring the shear viscosities. The flow characteristics of the sols were studied in relation to the spinnability by measuring the viscosity with respect to the shear rate. The spinnability was obtained through the addition of a polymer which increases the viscosity to a range of optimum viscosity values for spinning. Aging the sols containing the additives did not noticeably change the sol viscosities at room temperature up to 30 days. The flow behavior of the spinnable sols progressively changed from nearly Newtonian to pseudoplastic with an increase in the sol concentration.

연속섬유강화 플라스틱 복합재의 압축성형에 있어서 확대/축소 점도비를 고려한 유동해석 (Flow Analysis with Ratio of Expansional /Contractional Viscosity during Compression Molding of Continuous Fiber-Reinforced Polymeric Composites)

  • 김형철;채경철;조선형;김이곤
    • 대한기계학회논문집A
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    • 제24권3호
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    • pp.581-592
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    • 2000
  • To obtain an excellent product and decide on optimum molding conditions, it is important to establish the relationship between molding conditions and viscosity. The composites is treated as a pseudoplastic fluid, and the expansional/contractional viscosity of the fiber-reinforced polymeric composites is measured using the parallel plastometer, and the model for flow state has been simulated with the viscosity. The effects of expansional slip parameter $\alpha_{e}$, and expansional/contractional viscosity ratio ${\mu}_{\gamma}$, on the mold filling parameters are also discussed.