• Title/Summary/Keyword: pseudo-science

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Heavy Metal Removal of Acrylic Acid-grafted Bacterial Cellulose in Aqueous Solution (아크릴산으로 그라프트된 미생물셀룰로오스의 수용액 내 중금속 흡착거동)

  • Ahn, Yeong-Hee;Choi, Yong-Jin
    • Journal of Environmental Science International
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    • v.23 no.8
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    • pp.1419-1428
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    • 2014
  • Electron beam-induced grafting polymerization was employed to prepare Acrylic acid-grafted bacterial cellulose (BC-g-AAc). BC-g-AAc as an adsorbent was applied to remove heavy metals (e.g., As, Pb, and Cd). This study examined followings; morphological change of surface, adsorptive behavior of BC-g-AAc, and interpretation of adsorptive kinetics. Specific surface areas of BC and BC-g-AAc were $0.9527m^2g^{-1}$ for BC and $0.2272m^2g^{-1}$ for BC-g-AAc, respectively as measured by BET nitrogen adsorption, revealing the morphological change of the surface of BC-g-AAc. Batch adsorption test was performed to investigate adsorptive behavior of BC-g-AAc in aqueous solution. The amounts of Pb and Cd adsorbed on BC-g-AAc were $69mg\;g^{-1}$ and $56mg\;g^{-1}$, respectively. However, As was not adsorbed on BC-g-AAc due to its neutral nature. Both the Benaissa model and the Kurniawan model were applied in the study to interpret adsorptive kinetics. From the value of correction coefficient ($R^2$), adsorptive kinetics of Pb and Cd were subjected to Kurniawan model referred to pseudo-second-order. Taken together, the results of this study show that BC-g-AAc has potential as a heavy metal (eg., Pb, Cd)-adsorbent made of an environmentally friendly material.

A Paleomagnetic Study of Cretaceous Rocks from the Euiseong Area (의성지역에 분포하는 백악기 지층에 대한 고지자기 연구)

  • Doh, Seong-Jae;Kim, Kwang-Ho
    • Economic and Environmental Geology
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    • v.27 no.3
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    • pp.263-279
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    • 1994
  • Paleomagnetic and rock-magnetic data of Cretaceous sedimentary and volcanic rocks from the Euiseong area indicate that the stable components of remanence are carried by single and pseudo-single domain magnetite, with the exception of the Shinyangdong Formation which has been remagnetized. The Hayang Group, except for the remagnetized Shinyangdong Formation, yields the mean characteristic direction of $D/I=22.5^{\circ}/57.2^{\circ}$ (${\alpha}_{95}=4.6^{\circ}$, N=14 sites) and the pole position is $72.0^{\circ}N$, $206.4^{\circ}E$ ($dp/dm=4.9^{\circ}/6.7^{\circ}$). The Yucheon Group shows two polarities and the mean characteristic direction of $D/I=351.2^{\circ}/60.5^{\circ}$ (${\alpha}_{95}=11.2^{\circ}$, N= 19 sites) and the pole position is $81.3^{\circ}N$, $79.0^{\circ}E$ ($dp/dm=13.0^{\circ}/17.0^{\circ}$). The mean directions of both the Hayang and the Yucheon Groups are supported by the McElhinny's fold test at the 99% confidence level and that of the Yucheon Group by a reversal test at the 95% confidence level. A magnetostratigraphic correlation between polarities of the study formations and the Geomagnetic Time Scale indicates that the Hayang Group can be correlated to the Cretaceous Long Normal Superchron (CLNS), and the Yucheon Group to the boundary between the CLNS and the Polarity Chron 33R or later boundaries between normal and reverse polarities. Comparison of the paleopoles from this study with those from the surrounding areas both within the Gyeongsang basin and in the northeastern Asia indicates that the study area was not undergone significant tectonic rotations with respect to the other parts of the Gyeongsang basin and that the Korean Peninsula was the part of the single terrane of the northeastern Asia at least since the CLNS. The Yucheon Group can be divided into four sub-groups based on the paleomagnetic data, suggesting that there were at least four times of volcanic activities in the study area.

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Visual Evaluations of Clothing./ng Color Images for Cool Skin Color (찬피부색에 대한 의복색 이미지의 시각적 평가)

  • 박화순
    • Archives of design research
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    • v.15 no.4
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    • pp.327-336
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    • 2002
  • This paper is intended to help cool-skin-colored people to choose suitable clothing colors confidently and look well-dressed and to make positive self-images. A pseudo-experimental method has made it possible to analyze the visual evaluations of clothing color images for cool-skin-colored people and obtain the following results. 1. Reddish colors of vivid tone for doffing give positive images and those of dull and dark tone, negative ones. 2. Yellowish colors of vivid and bright tone for doffing show positive images and those of dull and dark tone, negative ones. Cool yellow of light tone proves to contribute to a well-looking image. 3. Warm green of vivid and deep tone, and cool green of vivid tone for clothing present positive images. 4. Warm blue of vivid and deep tone, and cool blue of vivid and bright lone make positive images. Either blue with dull tone gives a negative image. 5. Purple colors whose tone is vivid, deep and light contribute to positive images, and those of dull tone, negative ones.

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Effects of Nutrient Property Changes on Summer Phytoplankton Community Structure of Jangmok Bay (장목만에서 여름철 영양염 특성 변화가 식물플랑크톤 군집구조에 미치는 영향)

  • Jang, Pung-Guk;Jang, Min-Chul;Lee, Woo-Jin;Shin, Kyoung-Soon
    • Ocean and Polar Research
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    • v.32 no.2
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    • pp.97-111
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    • 2010
  • Phytoplankton production is affected by various physico-chemical factors of environment. However, one of the most critical factors generally accepted as controlling primary production of phytoplankton is nutrients. It has recently been found that the succession of phytoplankton groups and species are closely related to the chemical properties of ambient water including nutrient limitation and their ratios. In Jangmok Bay, silicate and nitrate are primarily supplied by rainfall, while phosphate and ammonia are supplied by wind stress. Typhoons are associated with rainfall and strong wind stress, and when typhoons pass through the South Sea, such events may induce phytoplankton blooms. When nutrients were supplied by heavy rainfalls during the rainy season and by summer typhoons in Jangmok Bay, the dominant taxa among the phytoplankton groups were found to change successively with time. The dominant taxon was changed from diatoms to flagellates immediately after the episodic seasonal events, but returned to diatoms within 3~10 days. Pseudo-nitzschia spp. were dominant mainly in the presence of low phosphate levels during the first of the survey which included the rainy season, while Skeletonema costatum was dominant when phosphate concentrations were high due to the strong wind stress during the latter half of the survey as a result of the typhoon. The competition between S. costatum and Chaetoceros spp. appeared to be regulated by the silicate concentration. S. costatum preferred high silicate and phosphate concentrations; however, Chaetoceros spp. were able to endure low silicate concentrations. These results implied that, in coastal ecosystems, the input patterns of each nutrient supplied by rainfall and/or wind stress appeared to contribute to the summer succession of phytoplankton groups and species.

Effect of Operating Parameters on Methyl Orange Removal in Catalytic Ozonation (촉매 오존화 공정에서 메틸오렌지 제거에 미치는 운전변수의 영향)

  • Lee, Myoung-Eun;Kim, Ji-Eun;Chung, Jae Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.7
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    • pp.412-417
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    • 2017
  • Removal characteristics of methyl orange and their dependence on operating parameters in a catalytic ozonation were investigated through a series of batch experiments. Activated carbon enhanced the self-decomposition of ozone, generating $OH{\cdot}$, thus promoting methyl orange degradation. As the carbon dose increases, the pseudo-first order rate constants of methyl orange degradation increased, resulting in the fast removal of methyl orange. The increase of gaseous ozone concentration enhanced the mass transfer to the aqueous solution, therefore, promoted the methyl orange removal. The methyl orange degradation was not significantly affected by the change of pH in the range of 5~12, and TOC removal was negligibly affected by the variation of pH over 7. The results indicate that the catalytic ozonation can be considered as an effective dye treatment technology.

A Study on the Leaf Persisting Periods and Leaf Color Characteristics of Woody Landscape Plants (낙엽조경수목의 대기정화 기간 연장과 미적 이용을 위한 잎 지속기간 및 엽색 특성)

  • 서병기
    • Asian Journal of Turfgrass Science
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    • v.12 no.3
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    • pp.195-214
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    • 1998
  • The leaf persisting and seasonal leaf color characteristics of deciduous woody landscape plants were investigated through the field survey in Suwon region. The leaf period was about 270 days from March 20, 1992 when Prunus padus was leaf spreading to December 17, 1992 when Lonicera sempervirens was leaf falling. The plants of leaf period over 240 days were Elaegagnus umbellata var. coreana, Salix pseudo-lasiogyn, Ligustrum obtusi-folium, Rosa multiflora, Lonicera sempervirens and Clematis viticella. The woody landscape plants bearing the red leaf by KBS standard color number before fall foliage coloring were Prunus salicina, Berberis thunbergii 'Atropurpurea', Acer platanoides 'Red King', Acer palmatum var. Pendula 'Crimson Queen', Parthenocissus tricuspidata, Nyssa sylvatica, Acer palmatum var. sanguineum, and the yellow leaf, Berberis thunbergii Variegata 'Aurea', Physocarpus opulifolius 'Luteus', and Forsythia koreana 'Seoul Cold', Ligustrum X vicaryi which is variegation. The fall foliage color period was about 100 days from September 6, 1992 when Euonymus alatus was fall foliage coloring, to December 17, 1992 when Lonicera sempervirens was leaf falling. (Table 24) And in terms of color based on KBS standard color number, 60.7% of fall foliage were yellow, 37.4%, red, respectively.

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Control Gain Optimization for Mobile Robots Using Neural Networks and Genetic Algorithms (신경회로망과 유전알고리즘에 기초한 이동로봇의 제어 이득 최적화)

  • Choi, Young-kiu;Park, Jin-hyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.4
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    • pp.698-706
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    • 2016
  • In order to move mobile robots to desired locations in a minimum time, optimal control problems have to be solved; however, their analytic solutions are almost impossible to obtain due to robot nonlinear equations. This paper presents a method to get optimal control gains of mobile robots using genetic algorithms. Since the optimal control gains of mobile robots depend on the initial conditions, the initial condition range is discretized to form some grid points, and genetic algorithms are applied to provide the optimal control gains for the corresponding grid points. The optimal control gains for general initial conditions may be obtained by use of neural networks. So the optimal control gains and the corresponding grid points are used to train neural networks. The trained neural networks can supply pseudo-optimal control gains. Finally simulation studies have been conducted to verify the effectiveness of the method presented in this paper.

The Plant Community Structure of Pinus densiflorain Forest in Chuwangsan National Park (주왕산국립공원의 소나무림 군집구조)

  • Jo, Jae-Chang;Cho, Woo;Han, Bong-Ho
    • Korean Journal of Environment and Ecology
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    • v.8 no.2
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    • pp.121-134
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    • 1995
  • To investigate the plant community structure in Pinus densiflora forest of Chuwangsan National Park, twenty five plots were set up and surveryed. The classification by TWINSPAN and DCA ordination techniques were applied to the study area. The plant community were divided into five groups in twenty five plots by DCA and the dividing groups were Pinus densiflora-Quercus variabilis community(I), P. densiflora-Q. serrata community(II), P. densiflora-Fraxinus sieboldiana community(III), P. densiflora-F. sieboldiana-Q. spp. community(IV) and P. densiflora-mixed deciduous forest community(V). The successional trends of tree species by DCA ordination techniques and DBH class distribution analysis seems to be from P. densiflora through Q. mongolica, Q. serrata to Carpinus laxiflora in the canopy layer group. And in the subtree and shrub layer, it was expected that Lespedeza maximowiczii, L. cytobotrya, Rhododendron mucronulatumlongrightarrowStyrax obassia, Stephandra insisa, Zanthoxylum schinifolimlongrightarrowAcer pseudo-sieboldianum, Lindera obtusiloba. There was no difference between the stand scores of DCA and soil pH, and soil moisture.

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Crystal Structure of cis-(Malonato)[(4R,5R)-4,5-bis(Aminomethyl)-2-Isopropyl-1,3-Dioxolane]Platinum(II), A Potent Anticancer Agent

  • Cho, Sang-Woo;Yongkee Cho;Kim, Dai-Kee;Wanchul Shin
    • Korean Journal of Crystallography
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    • v.11 no.1
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    • pp.22-27
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    • 2000
  • The structure of cis-(malonato)[(4R,5R)-4,5-bis(aminomethyl)-2-isopropyl-1,3-dioxolane]platinum(II) with a potent anticancer activity has been determined by the X-ray crystallographic method. Crystal data are as follows: Pt(C/sub 11/H/sub 20/N₂O/sub 6/), M/sub 4/=471.38, monoclinic, P2₁, a=7.112(1), b=33.615(3), c=7.135(1)Å, β=116.80(1)°, V=1522.6(3)Å, and Z=4. The two independent molecules with very similar structures are approximately related by pseudo two-fold screw axis symmetry, which makes the monolinic cell look like the orthorhombic cell with one molecule in the asymmetric unit and space group C222₁. The crystal packing mode is similar to that of the analogue with the dimethyl substituents instead of the isopropyl group. The Pt atom is coordinate to two O and two N atoms in a square planar structure. The six-membered chelate ring in the leaving ligand assumes a conformation intermediate between the half chair and the boat forms. The seven-membered ring in the carrier ligand assumes a twist-chair conformation and the oxolane ring assumes an envelope conformation. Crystal packing consists of the extensive hydrogen-bonding network in the two-dimensional molecular layers and weak van der Waals interactions between these layers.

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Comparison Study on the Removal of Cationic Dyes from Aqueous Suspension of Maghnia Montmorillonite (Maghnia 산 Montmorillonite 수용액으로부터 양이온 염료의 제거 비교연구)

  • Elaziouti, A.;Laouedj, N.
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.300-309
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    • 2010
  • The ability of sodium-exchanged clay particles as an adsorbent for the removal of commercial dyes, Methylene blue (MB) and Malachite green oxalate (MG) from aqueous solutions has been investigated under various experimental conditions. The effect of the experimental parameters, such as pH solution, agitation time, adsorbate concentration and adsorbent dose were examined. Maximum adsorption of dyes, i.e. >90% has been achieved in aqueous solutions using 0.03 g of clay at a pH of 7 and 298 K for both dyes. The adsorption process was a fast and the equilibrium was obtained within the first 5 min. For the adsorption of both MB and MG dyes, the pseudo-second-order reaction kinetics provides the best correlation of the experimental data. The adsorption equilibrium results follow Langmuir and Dubini-Radushkevich (D-R) isotherms with high regression coefficients $R^2$ > 0.98. The mean free energies $E_a$ of adsorption from D-R model were 3.779 and 2.564 kj/mol for MB and MG respectively, which corresponds to a physisorption process.