• 제목/요약/키워드: proton exchange membrane fuel cells (PEMFC)

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고분자 연료전지용 세공충진막의 제조 및 연료전지 특성 (Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances)

  • 최영우;박진수;이미순;박석희;양태현;김창수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.278-281
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    • 2009
  • Proton exchange membrane is the key material for proton exchange membrane fuel cells (PEMFC). Currently widely-used perfluorosulfonic acid membranes have some disadvantages, such as low thermal stability, easy swelling, excessive crossover of methanol and high price etc. Other membranes, including sulfonated polymer, radiation grafted membranes, organic-inorganic hybrids and acid-base blends, do not satisfy the criteria for PEMFC, which set a barrier to the development and commercialization of PEMFC. Pore-filling type proton exchange membrane is a new proton exchange membrane, which is formed by filling porous substrate with electrolytes. Compared with traditional perfluorosulfonic acid membranes, pore-filling type proton exchange membranes have many advantages, such as non- swelling, low methanol permeation, high proton conductivity, low cost and a wide range of materials to choose. In this research, preparation methodology of pore-filling membranes by particularly using all hydrocarbon polymers and fuel cell performances with the membranes are evaluated.

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고온형 고분자전해질연료전지용 MEA 개발 및 응용 (Development and Application of High Temperature Proton Exchange Membrane Fuel Cells)

  • 임태훈;김형준
    • 한국수소및신에너지학회논문집
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    • 제18권4호
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    • pp.439-445
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    • 2007
  • Proton exchange membrane Fuel Cells(PEMFCs) have been spotlighted because of their broad potential application for potable electrical devices, automobiles and residential usages. However, their utilization is limited to low temperature operation due to the electrolyte dehydration at high temperature. High temperature PEMFC operation offers high CO tolerance and easy water management. This review presents development of high temperature($120{\sim}200^{\circ}C$) PEMFC. Especially, PEMFC which is based on acid-doped PBI membrane is discussed.

sPEEK 막으로 제조한 고분자전해질 연료전지(PEMFC) 막전극합체(MEA)의 특성 (Characteristics of Proton Exchange Membrane Fuel Cells(PEMFC) Membrane and Electrode Assembly(MEA) Using Sulfonated Poly(ether ether ketone) Membrane)

  • 이혜리;이세훈;황병찬;나일채;이정훈;오성준;박권필
    • Korean Chemical Engineering Research
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    • 제54권2호
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    • pp.181-186
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    • 2016
  • 최근에 저가의 고분자 전해질 연료전지(Proton Exchange Membrane Fuel Cells, PEMFC)용 비불소계 전해질 막 연구개발이 활발히 진행되고 있다. 본 연구에서는 sulfonated Poly(ether ether ketone)(sPEEK)막의 특성을 술폰화도, 상대습도, 단위 전지 온도에 따라 PEMFC 운전 조건에서 비교하였다. I-V 분극곡선, 수소투과도, 전기화학적 표면적, 막 저항 및 부하 전달 저항 등을 측정 분석했다. 술폰화도와 온도, 상대습도가 높을수록 성능이 높았으며, 특히 낮은 슬폰화도와 낮은 상대습도에서 이온 전도도 감소 때문에 성능이 큰 폭으로 감소함을 확인하였다.

고분자 전해질 연료전지용 바이폴라 플레이트의 디자인에 관한 고찰 (A Study on the design of bipolar plate for proton exchange membrane fuel cell)

  • 윤정필;최장균;차인수;임중열
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.39-42
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    • 2007
  • Hydrogen fuel cell is clean and efficient technology along with high energy densities. While there are many different types of fuel cells, the proton exchange membrane fuel cell stands out as one of the most promising for transportation and small stationary applications. This paper focuses on design of bipolar plate for proton exchange membrane fuel cell. The bipolar plate model is realistically and accurately simulated velocity distribution, current density distribution and its effect on the PEMFC system using CFD tool FLUENT.

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PEMFC 연료전지의 과도현상 특성 (Dynamic Transient Phenomena of a Proton Exchange Membrane Fuel Cells)

  • 이영;최용성;장우새;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.203-203
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    • 2010
  • The proton exchange membrane fuel cell (PEMFC) is different from the normal power supply, and it is a nonlinear, multi-input, strong coupling, the complex dynamic system with large time delay. At present, many studies on the content of the fuel cell fuel cells focus on a static process, this paper analyzed in subsequent sections of the process of fuel cell dynamic response time of transition, and then it found the method to reduce the response time during the process of load change to ensure that the stability of output power.

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고분자전해질 연료전지용 Poly(arylene ether sulfone) 막의 특성 (Characteristics of Poly(arylene ether sulfone) Membrane for Proton Exchange Membrane Fuel Cells)

  • 정재진;신용철;이무석;이동훈;나일채;이호;박권필
    • Korean Chemical Engineering Research
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    • 제51권5호
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    • pp.556-560
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    • 2013
  • 최근에 저가의 고분자전해질 연료전지(Proton Exchange Membrane Fuel Cells, PEMFC)용 비불소계 전해질 막 연구개발이 활발히 진행되고 있다. 본 연구에서는 PEMFC 운전 조건에서 Poly(arylene ether sulfone)(PAES) 막과 불소계막의 특성을 비교하였다. I-V 분극곡선, 수소투과도, 전기화학적 표면적, 막저항 및 부하 전달 저항 등을 측정 분석했다. PAES 막은 상대습도 100%에서는 불소계 막과 비슷한 성능을 보였으나 낮은 상대습도에서 이온전도도가 낮아 성능감소가 컸다.

PEMFC 시스템용 바이폴라 플레이트의 디자인에 관한 연구 (A Study on a Design of Bipolar Plate for PEMFC System)

  • 윤형상;차인수;이정일;윤정필
    • 신재생에너지
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    • 제4권1호
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    • pp.5-10
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    • 2008
  • Hydrogen fuel cell is clean and efficient technology along with high energy densities. While there are many different types of fuel cells, the proton exchange membrane fuel cell stands out as one of the most promising for transportation and small stationary applications. This paper focuses on design of bipolar plate for proton exchange membrane fuel cell. The bipolar plate model is realistically and accurately simulated velocity distribution, current density distribution and its effect on the PEMFC system using CFD tool FLUENT.

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Nano Catalysts for Proton Exchange Membrane Fuel Cells

  • 김수길;황승준;임지은;유성종;이승철;임태훈
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.71.1-71.1
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    • 2012
  • Proton Exchange Membrane Fuel Cells (PEMFCs) have been of great interest particularly in the automobile industries because of their high energy density and low pollutant emission. However, some of the issues such as, the necessarily high contents of Pt catalysts and their slow kinetics of cathode oxygen reduction reaction remain as obstacles in the commercialization of the PEMFC. In this presentation, after brief explanation on basic principles of PEMFC and its application to FC vehicles, recent researches to improve the activity and durability of Pt-based nano catalysts toward oxygen reduction will be introduced. It covers size and shape control of Pt nano particle, binary and ternary Pt-M alloys, novel core-shell nano structures of Pt, and a little bit about non-Pt catalysts. Strategies and methodologies for design and synthesis of novel catalysts will also be included.

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Analysis of the Operating Point and Fault Current Contribution of a PEMFC as Distributed Generation (DG)

  • Moon, Dae-Seong;Kang, Gi-Hyeok;Chung, Il-Yop;Won, Dong-Jun
    • Journal of Electrical Engineering and Technology
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    • 제4권3호
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    • pp.382-388
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    • 2009
  • Recently, hydrogen energy has been anticipated to change the paradigm of conventional power systems because it can expand sustainable energy utilization and conceptually provide remarkable flexibility to power system operation. Since hydrogen energy can be converted to electric energy through fuel cells, fuel cells are expected to play an important role in the future hydrogen economy. In this paper, a Proton Exchange Membrane Fuel Cell (PEMFC) is modeled as an equivalent circuit and its steady-state characteristics investigated using the model. PEMFCs can be connected to power systems through power conditioning systems, which consist of power electronic circuits, and which are operated as distributed generators. This paper analyzes the effects of the characteristics of the PEMFC internal voltages and investigated the dynamic responses of the PEMFC under fault conditions. The results show that the fault current contribution of the PEMFC is different from those of conventional generators and is closely related to its operating point.

고온 연료전지용 새로운 형태의 고분자 전해질막의 합성과 특성연구 (Synthesis and Properties of New Type of Proton Conducting Polymer Membrane for High Temperature Fuel Cells)

  • 이중희;삼부 바드라;김남훈;이홍기;김홍건
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.166-169
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    • 2009
  • Poly(benzimidazole-co-aniline) (PBIANI), a self-crosslinked, net-structured, proton conducting polymer has been synthesized for the membrane of high temperature proton exchange membrane fuel cells (HT-PEMFC) with improved proton conductivity and mechanical strength. The stress at break (26$\pm$3MPa)and proton conductivity (167 mS cm-1)of the phosphoric acid doped PBIANI (DPBIANI)membrane is much higher than those of other doped polybenzimidazole(PBI) type membranes.

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