• Clean Technology
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• v.10 no.1
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• pp.9-17
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• 2004

Direct methanol fuel cell(DMFC) with proton exchange membrane (PEM) has advantages over the conventional power source (e.g. vehicle). DMFC, however, has a problem to be solved such as methanol crossover, high anodic overpotential and limiting current density, etc. The physicochemical phenomena in DMFC can be described by coupled PDEs (partial differential equations), which can be solved by a PDE solver. In this paper, we utilized a commercial software FEMLAB to solve the PDEs. The FEMLAB is one of the software programs available which are developed as a solver for building physics problems based on PDEs and is designed to simulate systems of coupled PDEs which may be 1D, 2D, 3D, non-liner and time dependent. We performed simulation using the Tafel equation as an electrochemical reaction model to analyze methanol concentration profile in DMFC system. We confirm that the rapid decrease of methanol concentration at anodic catalyst layer with the increase of the current density is a main reason of the low performance in DMFC through simulation results.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.3
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• pp.22-29
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• 2004

Deformation of the porous media has influence on performance of a proton exchange membrane fuel cell (PEMFC). The stress distributions and deformation of the porous media are major factors for safe and efficient operation in the PEMFC. In this paper, nonlinear contact analysis of air plate and porous media is performed under a working condition to predict the performance characteristics of the air plates. Two kinds of models are suggested for this study. The first porous media model has nonlinear material properties. The second model has nonlinear material properties with contact condition between porous media and air plate. The numerical analysis results of the two models are somewhat different. It is shown that the nonlinear contact analysis is required for the design study of the PEMFC.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.239-242
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• 2005

고분자 전해질형 연료전지에서는 수소이온의 이온전도성 저하를 방지하기 위하여 외부에서 가습하여 주는 방식이 일반적이지만, 가습에 소요되는 부품을 일부라도 제거할 경우 연료전지의 효율은 높이고 제작단가도 경감할 수 있다. 이를 위하여 저가습 및 무가습 실험을 수행하였으며, 정확한 data의 수집과 시험장비의 자동제어를 위하여 National Instrument사의 compact field point (cFP)를 사용하였다. 무가습 실험 중 stack의 안정성 측면을 고려하기 위하여 수소연료가 부족하거나 갑작스런 voltage drop이 발생할 경우 LabVIEW logic에 의한 stack 보호용 자동차단 시스템을 구현하였다. Humidifier와 heater의 온도를 조절하여 공급유체의 상대습도 및 온도를 각각 조절하였으며, 이에 필요한 이론적 온도는 Antoine equation을 사용하여 산정하였다. Anode와 cathode 양측 $100\%$ 가습 경우를 기준으로 가습량을 조절하면서 실험을 수행하였으며 성능 차이를 그래프로 도시하여 양측의 변화에 대한 영향을 볼 수 있도록 하였다. Stack의 온도가 $70^{\circ}C$이고 양측 무가습일 경우에 성능 측정이 불가능하여 stack의 온도를 저온에서부터 변화시키면서 무가습 성능을 실시간으로 측정하여 보았다 일반적으로 hydronium ion은 anode측에서 cathode측으로 계속 이동하여야 전기를 생성할 수 있으므로 cathode측 무가습이 anode측 무가습보다 성능이 더 잘 나오는 것으로 예측하였으나 이와 반대되는 경향의 실험 결과를 얻었다. Anode측 무가습과 cathode측 무가습의 standard deviation은 anode 무가습일 경우가 크게 발생하였고 양측 무가습일 경우는 stack의 온도가 높을수록 크게 관찰되었다. 이와 같은 현상은 공기중의 상대습도와 back diffusion등에 영향을 받을 수 있으므로 각종 변수들의 영향을 분리하여 관찰할 수 있는 실험을 수행중에 있다.

• Korean Chemical Engineering Research
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• v.54 no.6
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• pp.847-853
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• 2016

Here has been examined a 3-dimensional computational fluid dynamics (CFD) modeling in order to investigate the performance analysis of proton exchange membrane (PEM) fuel cells with serpentine flow fields. The present CFD model considers the isothermal transport phenomena in a fuel cell involving mass, momentum transport, electrode kinetics, and potential fields. Co-current flow patterns for a PEMFC are considered for various geometries in the single straight cell. Current density distribution from the calculated distribution of oxygen and hydrogen mass fractions has been determined, where the activation overpotential has been also calculated within anode and cathode. CFD results showed that profiles differ from those simulations subjected to each the calculated activation overpotential. It is interesting that the present serpentine flow field shows the specific distribution of current density with respect to the aspect ratio of depth to width and the ratio of reaction area for various serpentine geometries. Simulation results were considered reasonable with the other CFD results reported in literature and global comparisons of the PEMFC model.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.5
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• pp.41-49
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• 2004

The porous media of a proton exchange membrane fuel cell (PEMFC) is made of deformable materials. The shape of cross sectional area in air plate channels has been changed by structural deformation of the porous media. The uniform mass flow rate and pressure are major factors for safe and efficient operation in the PEMFC. Two kinds of models are provided for the flow analyses. Deformable and undeformable porous media are considered for numerical analysis and experiment of the air plate model. The numerical flow analysis results with deformable and undeformable porous media has some discrepancy in pressure distribution. The pressure differences are measured in order to compare with numerical analysis results. Pressures are measured between inlet and outlet of the air plate. The numerical analysis and experimental results show similar pressure distribution. It is shown that the pressure drops in the two approaches are well matched each other. It is proven that the consideration of structural deformation is required in the numerical analysis/experiment for the PEMFC design.

• Journal of the Korean Solar Energy Society
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• v.31 no.4
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• pp.128-135
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• 2011

일반적으로 PEM 연료전지에서는 수분 균형이 시스템의 효율에 결정적으로 영향을 미치기 때문에, 이에 대한 균형(balance)을 잡는 것이 매우 중요하다. 특히, 촉매 층에서 물이 넘치는 익수현상(flooding)이나 건조현상(drying)이 발생하게 되면 연료전지의 효율이 급격하게 저하하므로, 항상 수분의 균형이 잡히도록 시스템을 제어하는 것이 일반적이다. 이 때,수분의 익수현상이나 건조현상은 PEM 연료전지의 용량과 주위의 환경, 즉 온도와 습도에 많은 영향을 받게 된다. 금번 논문에서는 가정용 규모인 3kW급에서 10kW급까지의 PEM 연료전지를 설치하였을 때, 주위의 환경(온도와 습도)이 수분 이동에 어떠한 영향을 미치는 지를 시간에 따라서 시뮬레이션(simulation)한 결과를 보여주고 있다. 결과에서 유입공기의 온도가 $50^{\circ}C$ 이하일 경우, 고정부하가 5kW급 이하이면 대부분이 건조현상이 발생하였으나, 고정부하가 6kW급 이상이 되면 익수현상이 운전시간이 20분 이내에서 발생하였다. 또한 고정부하를 최고 10kW급까지 올린 경우, 유입공기의 온도가 $50^{\circ}C$까지는 익수현상이 발생하였으나 $60^{\circ}C$ 이상인 경우에는 거의 건조현상이 발생함을 알 수 있었다.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.478-482
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• 2017

Humidity control of proton exchange membrane fuel cell(PEMFC) is very important control condition during driving. In terms of water management, low humidification conditions are advantageous, and high humidification is advantageous in terms of drainage utilization and energy efficiency. In this study, the characteristics of outlet water in low humidification and high humidification process were studied in terms of utilization of discharged water. Since the impurities in the effluent are generated during the degradation of the membrane and the electrode assembly(MEA), degradation of the MEA under low humidification and high humidification conditions was also studied. The rate of radical generation was high at low humidification condition of the anode RH 0%, which showed that it was the main cause of the degradation of the polymer membrane. Analysis of effluent showed low concentration of fluoride ion concentration of about 20 ppb at high humidification (both electrodes RH 100%) and 0.6 V, which was enough to be used as the feed water for electrolysis. Very low concentration of platinum below 0.2 ppb was detected in the condensate discharged from the high humidification condition.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.720-726
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• 2014

PEM fuel cell vehicles have been getting much attraction due to a sort of highly clean and effective transportation. The onboard fuel processor, however, is inevitably required to supply the hydrogen by conversion from some fuels since there are not enough available hydrogen stations nearby. A lot of studies have been focused on analyses of ATR reactor under the assumption of thermo-neutral condition and those of the optimized process for the minimization of energy consumption using thermal efficiency as an objective function, which doesn't guarantee the maximum hydrogen production. In this study, the analysis of optimization for 100 kW PEMFC onboard fuel processor was conducted targeting various fuels such as gasoline, LPG, diesel using newly defined hydrogen efficiency and keeping simply synthesized heat exchanger network regardless of external utilities leading to compactness and integration. Optimal result of gasoline case shows 9.43% reduction compared to previous study, which shows the newly defined objective function leads to better performance than thermal efficiency in terms of hydrogen production. The sensitivity analysis was also done for hydrogen efficiency, heat recovery of each heat exchanger, and the cost of each fuel. Finally, LPG was estimated as the most economical fuel in Korean market.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.627-631
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• 2012

Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for portable proton exchange membrane fuel cells (PEMFCs). The durability of Co-P-B/Cu catalyst for sodium borohydride hydrolysis reaction was studied. The effect of reaction temperature, $NaBH_4$ concentration, NaOH concentration and calcination temperature of catalyst on the durability of Co-P-B/Cu catalyst were measured. The gel formed during hydrolysis reaction affected the durability of catalyst (loss of catalyst). Formation of gel increased the loss of the catalyst. When $NaBH_4$ concentration was high and reaction temperature was higher than $60^{\circ}C$, loss of catalyst was low because gel was not formed. But under the temperature of $40^{\circ}C$, loss of catalyst increased due to gel formation When $NaBH_4$ concentration was 40 weight % and the reaction temperature was $40^{\circ}C$, the loss of catalyst increased as the NaOH concentration increased. As the calcination temperature of catalyst decreased, the loss of catalyst decreased and the activity of catalyst decreased. Calcination of the catalyst at high temperature enhanced the durability of catalyst but diminished the activity of catalyst.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.516-520
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• 2011

Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for portable proton exchange membrane fuel cells (PEMFCs). The hydrogen yield of sodium borohydride hydrolysis reaction was studied. The effect of temperature, $NaBH_4$ concentration, NaOH concentration and catalyst type on the hydrogen yield from $NaBH_4$ hydrolysis reaction were measured. The catalysts of Co-P/Cu, Co-B/Cu and Co-P-B/Cu were used in this study and there was no different effect of these catalysts on the hydrogen yield from $NaBH_4$. Under the temperature of $60^{\circ}C$, the hydrogen yield decreased as $NaBH_4$ concentration increased due to formation of gel with by-products and reactants. The gel formed during $NaBH_4$ hydrolysis reaction diminished the hydrogen evolution rate and total volume of hydrogen. Addition of NaOH stabilizer enhanced the formation of gel and then decreased the hydrogen yield.