• Title/Summary/Keyword: proton exchange membrane fuel Cell

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A Study on the Flooding Phenomena of Cathode Flow Path with Operating Temperatures in a PEM Fuel Cell (고분자전해질형 연료전지의 작동 온도에 따른 공기극 유로 내 플러딩 현상에 관한 연구)

  • Kim Han-Sang;Ha Taehun;Min Kyoungdoug
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.326-329
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    • 2005
  • Proton exchange membrane (PEM) should be sufficiently hydrated with proper water management to maintain a good ionic conductivity and performance of a PEM fuel cell. However. cathode flooding resulting from excess water can impede the transport of reactants and hence deteriorate the fuel cell performance. For the PEM fuel cell to be commercially viable as vehicle or portable applications, the flooding on the cathode side should be minimized during the fuel cell operation. In this study, visualization technique was applied to understand the cathode flooding phenomena on the cathode side of a PEM fuel cell. To this end. a transparent PEM unit fuel cell wi th an act ive area of $25cm^2$ was designed and manufactured to allow for the visualization of cathode channel with performance characteristics. Two-phase flow resulting from the electro-chemical reaction of fuel cell was investigated experimentally. The images photographed by CCD camera with cell operating temperatures $(30\~50^{\circ}C)$ were presented. Results indicated that the flooding on the cathode side first occurs near the exit of cathode channel. As the operating temperature of fuel cell increases. it was found that liquid water droplets tend to evaporate easily and it can have an influence on lowering the flooding level. It is expected that this study can effectively contribute to the detailed researches on modeling water transport of an operating PEM fuel cell including two-phase flow phenomena.

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Studies on the Preparation and Characterization of PVA Based Cation-exchange Membranes for DMFC Application (직접 메탄올 연료전지 적용을 위한 PVA 기반 양이온교환막 제조 및 특성연구)

  • Jeon, Yi Seul;Kim, Ka young;Rhim, Ji Won
    • Membrane Journal
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    • v.25 no.2
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    • pp.144-151
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    • 2015
  • The water-soluble poly(vinyl alcohol) membranes with the addition of sulfosuccinic acid (SSA) were prepared and to assign the ion exchange capacity, poly(4-styrene sulfonic acid-co-maleic acid) (PSSA_MA) was added to PVA according to PSSA_MA contents of 70, 80 and 90 wt%. To characterize the resulting membranes, FT-IR, water contents, ion exchange capacity, proton conductivity and methanol permeability were measured. As PSSA_MA contents increased, water contents, ion exchange capacity, proton conductivity increased, but methanol permeability decreased. From these results, the best preparation component was known as PVA10/SSA9/PSSA_MA80.

Research Trend and Analysis of Altitude and Endurance for Fuel Cell Unmanned Aerial Vehicles (연료전지 무인항공기의 고도와 체공시간에 대한 특성 분석 및 최신 연구동향)

  • Cho, Seonghyun;Kim, Minjin;Son, Youngjun;Yang, Taehyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.393-404
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    • 2014
  • Unmanned aerial vehicles (UAVs) have been applied to not only military missions like surveillance and reconnaissance but also commercial missions like meteorological observation, aerial photograph, communication relay, internet network build and disaster observation. Fuel cells make UAVs eco-friendly by using hydrogen. Proton exchange membrane fuel cells (PEMFCs) show low operation temperature, high efficiency, low noise and high energy density and those characterisitcs are well fitted with UAVs. Thus Fuel cell based UAVs have been actively developed in the world. Recently, fuel cell UAVs have started to develope for high altitude UAVs because target altitude of UAVs is expanded upto stratosphere altitude. Long endurance of UAVs is essential to improve effects of the missions. Improvement of UAV endurance time could be fulfilled by developing a hydrogen fuel storage system with high energy density and reducing the weight of UAVs. In this paper, research trend and analysis of fuel cell UAVs are introduced in terms of their altitude and endurance time and then the prospect of fuel cell UAVs are shown.

A Study on Optimal Design and Operational Features of a Stand-alone 500W PEMFC System (독립형 500W PEMFC 시스템의 최적 설계 및 구동 특성에 관한 연구)

  • Park, Se-Joon;Ha, Min-Ho;Choi, Hong-Jun;Cha, In-Su;Yoon, Jeong-Phil;Lim, Jung-Yeol
    • Proceedings of the KIPE Conference
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    • 2008.06a
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    • pp.320-322
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    • 2008
  • The international oil price now has been going up every each day, about 120 USD per a gallon April 2008, so that most of countries in the world are concern of the the shortage of petroleum and the development of new and renewable energy resources. This paper presents optimal design and operational features of stand-alone 500W PEMFC(Proton Exchange Membrane Fuel Cell) system which can be a substitute instead fossil fuel. The stack of PEMFC is composed of 35 laminated graphites, and a unit cell of the stack has electrical characteristics as below; 14W, 0.9V, 15A. The other components of BOP(Balance of Plant) are composed of hydrogen and nitrogen tanks, regulators, 3way solenoid valves, mass flow meters, etc.

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Effect of Load Modeling on Low Frequency Current Ripple in Fuel Cell Generation Systems

  • Kim, Jong-Soo;Choe, Gyu-Yeong;Kang, Hyun-Soo;Lee, Byoung-Kuk
    • Journal of Electrical Engineering and Technology
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    • v.5 no.2
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    • pp.307-318
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    • 2010
  • In this work, an accurate analysis of low frequency current ripple in residential fuel cell power generation systems is performed based on the proposed residential load model and its unique operation algorithm. Rather than using a constant dc voltage source, a proton exchange membrane fuel cell (PEMFC) model is implemented in this research so that a system-level analysis considering the fuel cell stack, power conditioning system (PCS), and the actual load is possible. Using the attained results, a comparative study regarding the discrepancies of low frequency current ripple between a simple resistor load and a realistic residential load is performed. The data indicate that the low frequency current ripple of the proposed residential load model is increased by more than a factor of two when compared to the low frequency current ripple of a simple resistor load under identical conditions. Theoretical analysis, simulation data, and experimental results are provided, along with a model of the load usage pattern of low frequency current ripples.

High-efficiency fuel-cell power inverter with soft-switching resonant technique (Soft-switching resonant technique을 적용한 고효율 PEMFC inverter)

  • Han, K.H.;Cho, Y.R.;Baek, S.H.
    • Proceedings of the KIEE Conference
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    • 2005.10c
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    • pp.326-328
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    • 2005
  • In order to reduce the capital and overall operating cost of a fuel-cell system, a high-efficiency fuel-cell power inverter with a simple framework is required. The high-order two-inductance two-capacitance (LLCC) resonant technique is adopted in this study to implement a low-frequency 60-Hz sine wave voltage inverter utilized in the proton exchange membrane fuel-cell (PEMFC) system. The methodology for inverting dc voltage into low-frequency ac boltage is usually generated by the pulse-width-modulation (PWM) technique. However, the PWM-type inverter output has high-frequency harmonic components. Although an adequately designed filter could be utilized to overcome this problem, there are still some undesirable effects introduced by the high-frequency switching loss, electromagnetic-interference, harmonic current, and load variation. A novel power inverter via the LLCC resonant technique is designed for inverting dc voltage into 60-Hz ac sine wave voltage in the PEMFC system. This circuit scheme has the merits of low harmonic components, soft switching, high efficiency, and simplified implementation. The effectiveness of the proposed resonant inverter used for the PEMFC system is verified by numerical simulations and experimental results.

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The development of complex electrode for fuel cell using CNT (CNT를 이용한 PEMFC 연료전지용 복합전극 개발)

  • Ok, Jinhee;Altalsukh, Dorjgotov;Rhee, Junki;Park, Sangsun;Shul, Yonggun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.135.2-135.2
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    • 2010
  • Carbon nanotube(CNT) has been spotlighted as a promising candidate for catalyst support material for PEMFC (proton exchange membrane fuel cell). The considerable properties of CNT include high surface area, outstanding thermal, electrical conductivity and mechanical stability. In this study, to fully utilize the properties of CNTs, we prepared directly oriented CNT on carbon paper as a catalyst support in the cathode electrode. The CNT layer was prepared by a chemical vapor deposition(CVD) process. And the Pt particles were deposited on the CNT oriented carbon paper by impregnation and eletro-deposition method. The potential advantages of directly oriented CNT on carbon paper can include improved thermal and charge transfer through direct contact between the electrolyte and the electrode and enhanced exposure of Pt catalyst sites during the reaction.

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PSCAD/EMTDC Model of PEMFC for Power System Analysis (전력계통 해석을 위한 PEMFC의 PSCAD/EMTDC 모델)

  • Lee, Jong-Su;Kim, Hak-Man;Lee, Byoung-Kuk;Shin, Myong-Chul
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.1
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    • pp.9-14
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    • 2009
  • The modelling of PEMFC(Proton Exchange Membrane Fuel Cell) has been studied in many kinds of methods. But there are some limitations in application of the developed models to analyze transient phenomena of power systems. The PSCAD/EMTDC is very popular simulation tool in power system areas. To analyze power systems interconnected to PEMFCs, the PSCAD/EMTDC model of the PEMFCs is needed. In this paper, we developed a PSCAD/EMTDC model of PEMFC based on electro-chemical characteristic equations of PEMFC. Also, we performed simulations using the developed model in the PSCAD/EMTDC program and tested appropriateness of the proposed models. The simulations showed good results.

A Study on the BOS control of a small PEM fuel cell stack (소형 PEM 연료전지 스택의 BOS 제어에 관한 연구)

  • Kim, Tae-Hoon;Choi, Woo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.274-277
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    • 2009
  • 본 논문에서는 소형 PEM(Proton Exchange Membrane) 연료전지 스택의 BOS(Balance of Stack) 제어에 관하여 논의한다. 별도의 가습 장치가 필요치 않고 BOS의 구성이 비교적 간단한 소형 PEM 연료전지 시스템에서는 팬과 퍼지밸브만의 제어를 통해 스택 내부 수분의 조절과 열 관리가 수행된다. 따라서 본 논문에서는 부하에 따른 최적의 공기유량을 계산하고 요구되는 유량의 공급을 위해 팬을 제어하는 알고리즘을 통해 소형 연료전지 시스템의 과도응답 특성과 안정성을 향상시키는 방법에 관하여 제안한다. 150W급 소형 연료전지 시스템을 꾸미고, 마이크로컨트롤러를 이용한 제어회로를 구현하여 실험함으로써 제안된 알고리즘의 유용함을 검증하였다.

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Structural and Flow Analysis for Designing Air Plate of a Fuel Cell (구조 해석과 유동 해석을 통한 연료전지 공기판 설계)

  • Park, Jung-Sun;Yang, Ji-Hae;Lee, Won-Yong
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.585-590
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    • 2003
  • The distributions of mass flow rate and pressure are major factors to deside the performance of a proton exchange membrane fuel cell (PEMFC). These factors are affected by channel configuration of air plate. In this paper. structural analysis is performed to investigate deformation of porous media. Two kind of models are suggest for flow analyses. Deformed porous media and undeformed porous media are considered for air plate model. The Numerical flow analysis results with deformed porous media and undeformed porous media had some discrepancy in pressure distribution. The pressure and velocity in a working condition are numerically calculated to predict the performance of the air plates. Distributions of the parameters in the PEMFC are analyzed numerically under steady-state conditions.

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