• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.1029-1036
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• 2012

Push-pull-type copolymers - low-band-gap copolymers of electron-rich fused-ring units (such as cyclopentadithiophene; CPDT) and electron-deficient units (such as benzothiadiazole; BT) - are promising donor materials for organic solar cells. Following a design principles proposed in our previous study, we investigate the electronic structure of a series of new CPDTBT derivatives with various electron-withdrawing groups using the time-dependent density functional theory and predict their power conversion efficiency from a newlydeveloped protocol using the Scharber diagram. Significantly improved efficiencies are expected for derivatives with carbonyl [C=O], carbonothioyl [C=S], dicyano [$C(CN)_2$] and dicyanomethylene [C=$C(CN)_2$] groups, but these polymers with no long alkyl side chain attached to them are likely to be insoluble in most organic solvents and inapplicable to low-cost solution processes. We thus devise several approaches to attach alkyl side chains to these polymers while keeping their high efficiencies.

• Journal of the Korean Chemical Society
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• v.58 no.2
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• pp.193-197
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• 2014

Dibenzo-18-crown-6, dibenzo-21-crown-7 and dihydroxy dibenzo-18-crown-6 were synthesized by Bayer-Villiger oxidation strategy. Dibenzo-18-crown-6 and dibenzo-21-crown-7 could be synthesized through a three-step protocol starting from salicylaldehyde. Salicylaldehyde was reacted with bis-(2-chloroethyl)ether using $K_2CO_3$ in acetonitrile to link the two phenolic groups with the oxyethylene bridge followed by conversion of the formyl group to the hydroxy group via a Baeyer-Villiger reaction and finally linking the two phenolic group with appropriate oxyethylene bridge. The two target crown ethers were obtained in overall yield, 24% and 30%, respectively. This method has a great potential for synthesis of symmetrical as well as unsymmetrical dibenzo crowns with varying oxyethylene bridges. Baeyer-Villiger oxidation could be used to prepare dihydroxy derivative of dibenzo-18-crown-6 through acetylation of dibenzo-18-crown-6 followed by Baeyer-Villiger oxidation. The Baeyer-Villiger oxidation could be substantially accelerated using trifluoroacetic acid.

• Proceedings of the Korea Inteligent Information System Society Conference
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• 2001.01a
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• pp.278-282
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• 2001

The discovery of tacit knowledge from domain experts is one of the most exciting challenges in today\`s knowledge management. The nature of decision knowledge in determining the quality a firm\`s short-term liquidity is full of abstraction, ambiguity, and incompleteness, and presents a typical tacit knowledge extraction problem. In dealing with knowledge discovery of this nature, we propose a scheme that integrates both knowledge elicitation and knowledge discovery in the knowledge engineering processes. The knowledge elicitation component applies the Verbal Protocol Analysis to establish industrial cases as the basic knowledge data set. The knowledge discovery component then applies fuzzy clustering to the data set to build a fuzzy knowledge based system, which consists of a set of fuzzy rules representing the decision knowledge, and membership functions of each decision factor for verifying linguistic expression in the rules. The experimental results confirm that the proposed scheme can effectively discover the expert\`s tacit knowledge, and works as a feedback mechanism for human experts to fine-tune the conversion processes of converting tacit knowledge into implicit knowledge.

• Journal of Plant Biotechnology
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• v.8 no.1
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• pp.15-19
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• 2006

An efficient protocol for in vitro multiple shoot bud induction and plant regeneration from mature green cotyledon derived callus tissues of Acacia sinuata has been developed. Callus formation occurs at all the concentrations of thidiazuron (TDZ) in Murashige and Skoog's (MS) medium, but 0.6 ${\mu}M$ proved to be the best with maximum callus formation frequency. Supplementation of TDZ in combination with indole-acetic acid (IAA) in MS media accelerates shoot bud organogenesis in differentiating callus tissues with 60-70% conversion of shoot buds into shoot Most efficient shoot organogenesis was recorded when TDZ induced calli were subcultured at different concentrations of 6-benzyla-denine (BA). Optimum shoot bud induction and plant regeneration from callus was achieved when 0.6 ${\mu}M$ (TDZ) induced calli were subcultured at 3.0 ${\mu}M$ (BA) where $16.6{\pm}0.74$ shoots/unit callus on obtained. Rooting in in vitro differentiated shoots was achieved when transferred to medium containing different concentration of indole-3-butyric acid (IBA) in full & half strength MS medium. The well rooted plantlets were hardened and transferred to net house with 90% survival rate.

• International Journal of Fluid Machinery and Systems
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• v.1 no.1
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• pp.33-37
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• 2008

EquiMar (Equitable Testing and Evaluation of Marine Energy Extraction Devices in terms of Performance, Cost and Environmental Impact) is one of the first round of energy projects under the European Commissions 7th Framework Programme (FP7). The three year EquiMar project aims to deliver a suite of protocols for the evaluation of both wave and tidal converters, harmonizing testing and evaluation procedures across the wide range of available devices, accelerating adoption through technology matching and improving the understanding of both environmental and economic impacts associated with the deployment of devices. The EquiMar protocols will cover site selection, initial design, scaling up of designs, the deployment of arrays and environmental impact assessment as well as economic issues. EquiMar will build on existing protocols, e.g. UK DTI Marine Renewables Development Fund (MRDF) protocols for wave and tidal energy, and engage with international standards setting activities, e.g. IEC TC114.

• Journal of IKEEE
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• v.17 no.3
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• pp.301-308
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• 2013

In this paper, we propose the hybrid lighting control system on multiple sensor. The proposed hybrid lighting control system was designed for management and control of street lightings by configured as the data display part of integration-interworking part, the data conversion-processing part of integrated management part, and the communication part of gateway system. The data are implemented to designing the DB to enable to storage in real-time by enable to monitoring by wireless remote control and schedule set. As a result of the efficiency verification of the proposed hybrid lighting control system, the hybrid lighting control system be to the real-time monitoring and remote lighting control was possible, because to peristalsis with smart devices and portable PC etc., and it could be obtained the effect of energy and electricity, communication cost reduction.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.1
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• pp.57-63
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• 2015

Recently, Korea's municipal wastewater treatment plants generated amount of wastewater sludge per day. However, ocean dumping of sewage sludge has been prohibited since 2012 by the London dumping convention and protocol and thus removal or treatment of wastewater sludge from field sites is an important issue on the ground site. The hydrothermal carbonization is one of attractive thermo-chemical method to upgrade sewage sludge to produce solid fuel with benefit method from the use of no chemical catalytic. Hydrothermal carbonization improved that the upgrading fuel properties and increased materials and energy recovery, which is conducted at temperatures ranging from 200 to $350^{\circ}C$ with a reaction time of 30 min. Hydrothermal carbonization increased the heating value though the increase of the carbon and fixed carbon content of solid fuel due to dehydration and decarboxylation reaction. Therefore, after the hydrothermal carbonization, the H/C and O/C ratios decreased because of the chemical conversion. Energy retention efficiency suggest that the optimum temperature of hydrothermal carbonization to produce more energy-rich solid fuel is approximately $200^{\circ}C$.

• Journal of the Korea Institute of Military Science and Technology
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• v.12 no.1
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• pp.88-96
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• 2009

Interoperation between heterogeneous simulators employs definition of standard protocols for data exchange and time synchronization among simulators. The High Level Architecture(HLA) is a specification of common services for such interoperation, which is approved as IEEE standard 1516. This paper presents the design and implementation of an interoperable adaptor which supports development of interoperable simulators under the IEEE 1516 HLA/RTI environment. The adaptor, KHLAAdaptor1516, is implemented as a library form which is linked to HLA-compliant simulators. Design of the adaptor employs a protocol conversion method, the model of which is finite state machine. KHLAAdaptor1516 allows developers to separate interoperable adaptors from stand-alone simulators. The interoperable adaptor manages mapping between HLA services and simulation messages for simulator, This separation increases robustness of a federation and reusability of simulators as well as alleviates much effort and time for maintenance.

• ETRI Journal
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• v.34 no.3
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• pp.352-360
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• 2012

This paper proposes a low-cost, low-power, and high-capacity optical-electrical-optical-type reach extender that can provide 3R frame regeneration and remote management to increase the reach and split ratio with no change to a legacy time division multiple access passive optical network. To provide remote management, the extender gathers information regarding optical transceivers and link status per port and then transmits to a service provider using a simple network management protocol agent. The extender can also apply to an Ethernet passive optical network (E-PON) or a gigabit-capable PON (G-PON) by remote control. In a G-PON, in particular, it can provide burst mode signal retiming and burst-to-continuous mode conversion at the upstream path through a G-PON transmission convergence frame adaptor. Our proposed reach extender is based on the quad-port architecture for cost-effective design and can accommodate both the physical reach of 60 km and the 512 split ratios in a G-PON and the physical reach of 80 km and the 256 split ratios in an E-PON.

• The Journal of the Korea institute of electronic communication sciences
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• v.5 no.3
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• pp.332-338
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• 2010

In this paper, Zigbee/PLC gateway system is designed for Ubiquitous health care. A protocol conversion algorithm for smooth information exchange between Zigbee and PLC communication has been implemented on the gatway. If a moving object is detected by wireless sensor, the data is transmitted to gateway. Zigbee/PLC gateway analyzes received data and transmits to Power Line Communication for real-time monitoring. Implemented system is can support elder who lives alone activity analysis, crime prevention system, Home network service.