• Title/Summary/Keyword: protection potential

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A Study on the Protection of the Bare and Painted Steel Plates (아연 양극에 의한 도장강판과 나강판의 방식 연구)

  • 문경만;김종신;김진경
    • Journal of Advanced Marine Engineering and Technology
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    • v.17 no.1
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    • pp.55-65
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    • 1993
  • Galvanic protection method is one the cathodic protection methods and is mostly used for corrosion prevention of heat exchangers and ship's hull. In this paper, it was investigated that how cathodic potential distribution was varied with according to the bare and painted steel plates in case of galvanic anode protection. The results obtained above were as follows. 1. Cathodic potential distribution of a painted steel plate was smoothed than that of the bare steel plate all over the cathodic surface area. 2. It was shown that polarization potential of the bare steel plate was somewhat shifted to negative potential, on the contrary that of the painted steel plate was somewhat shifted from negative potential to positive potential as time gone by beginning of galvanic anode method. 3. The applied current density in order to maintain constant protection potential(-770mv SCE) in the painted steel plate was less than that of the bare steel plate because of the high resistance polarization of the painted steel plate. 4. It was suggested that required number and life-time of anode for galvanic anode protection could be decided easily with corrosion prevention coefficient obtained by experimental data.

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The Effects of Surface Condition and Flow Rate to the Cathodic Protection Potential and Current on Steel (강의 음극방식에 미치는 표면상태와 유속의 영향)

  • Kyeong-soo, Chung;Seong- Jong, Kim;Myung-Hoon, Lee;Ki-Joon, Kim;Kyung-Man, Moon
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.6
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    • pp.972-980
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    • 2004
  • Cathodic protection is being widely used to protect steel structures in sea water environment, In order to protect steel structures completely, the flow condition of sea water surrounding with this structures and the surface condition of the structures must be considered for a desirable design of cathodic protection. In this study, the optimum protection potential and current density were investigated in terms of cathodic current density, surface condition and a flow condition of sea water. The optium protection potential of the cleaned specimen was -770 mV(SCE) and below. However in the case of the rusted specimen, its potential was -700 mV(SCE) and below, which was somewhat positive than the cleaned one irrespective of flow condition. The optimum cathodic protection current density for both the cleaned and rusted specimens was 100 mA/$\textrm{m}^2$, however, on the flow condition, 200 mA/$\textrm{m}^2$ to be supplied for cathodic protection of steel structures completely for both cleaned and rusted specimens.

The effect of cathodic protection system by means of zinc sacrificial anode on pier in Korea

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.10
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    • pp.1206-1211
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    • 2014
  • This study has been conducted to confirm the effect of sacrificial anode cathodic protection system for 90 days to protect corrosion on pier that is located in Korea. The cathodically protected structure was a slab and a pile cap. Before the construction of cathodic protection system, the macrography was carried out. As a result of the macrography, many corrosion traces were confirmed in this structure. The trace was mainly focused on joint and zones that concrete cover was eliminated. To apply the cathodic protection system, many onsite techniques have been adopted. In addition, to confirm the inner state of steel in concrete properly, a corrosion monitoring sensor (DMS-100, Conclinic Co. Ltd) has been applied. Test factors were corrosion & cathodic protection potential, 4 hour depolarization potential, resistivity and current density. After 90 days from the installation of cathodic protection system, it could confirm that proper corrosion protection effect was obtained by considering the result of tests.

Nonexistence and non-decoupling of the dissipative potential for geo-materials

  • Liu, Yuanxue;Zhang, Yu;Wu, Runze;Zhou, Jiawu;Zheng, Yingren
    • Geomechanics and Engineering
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    • v.9 no.4
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    • pp.531-545
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    • 2015
  • Two fundamental issues exist in the damage theory of geo-material based on the concept of thermodynamics: existence or nonexistence of the dissipation potential, and whether the dissipation potential could be decoupled into a damage potential and a plastic one or not. Thermodynamics theory of elastoplastic damage assumes the existence of dissipation potential, but the presence of dissipation potential is conditional. Based on the dissipation inequality in accord with the second law of thermodynamics, the sufficient and necessary conditions are given for the existence of the dissipation potential separately in total and incremental forms firstly, and proved strictly in theory. With taking advantage of the basic mechanical properties of geo-materials, the nonexistence of the dissipative potential is verified. The sufficient and necessary conditions are also given and proved for the decoupling of the dissipation potential of geo-materials in total and incremental forms. Similarly, the non-decoupling of the dissipation potential has also been proved, which indicates the dissipation potential of geo-materials in total or incremental forms could not be decoupled into a dissipative potential for plasticity and that for damage respectively. The research results for the fundamental issues in the thermodynamics theory of damage will help establish and improve the theoretic basis of elastoplastic damage constitutive model for geo-materials.

Nonexistence and non-decoupling of the dissipative potential for geo-materials

  • Liu, Yuanxue;Zhang, Yu;Wu, Runze;Zhou, Jiawu;Zheng, Yingren
    • Geomechanics and Engineering
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    • v.9 no.5
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    • pp.569-583
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    • 2015
  • Two fundamental issues exist in the damage theory of geo-material based on the concept of thermodynamics: existence or nonexistence of the dissipation potential, and whether the dissipation potential could be decoupled into a damage potential and a plastic one or not. Thermodynamics theory of elastoplastic damage assumes the existence of dissipation potential, but the presence of dissipation potential is conditional. Based on the dissipation inequality in accord with the second law of thermodynamics, the sufficient and necessary conditions are given for the existence of the dissipation potential separately in total and incremental forms firstly, and proved strictly in theory. With taking advantage of the basic mechanical properties of geo-materials, the nonexistence of the dissipative potential is verified. The sufficient and necessary conditions are also given and proved for the decoupling of the dissipation potential of geo-materials in total and incremental forms. Similarly, the non-decoupling of the dissipation potential has also been proved, which indicates the dissipation potential of geo-materials in total or incremental forms could not be decoupled into a dissipative potential for plasticity and that for damage respectively. The research results for the fundamental issues in the thermodynamics theory of damage will help establish and improve the theoretic basis of elastoplastic damage constitutive model for geo-materials.

The effect of temperature and relative humidity on concrete slab specimens with impressed current cathodic protection system

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.3
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    • pp.260-265
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    • 2013
  • Impressed current cathodic protection (ICCP) system is one of the most promising corrosion protection methods. The Effect of ICCP system can be changed at diverse conditions. Particularly, temperature and relative humidity plays a crucial role in CP (Cathodic Protection) effect. Thus, in this study, the influence of temperature and relative humidity on concrete specimens was investigated. Specimens were concrete slab type with a base of $400mm{\times}400mm$ and height of 70mm. To enhance the effect of CP system, seawater was used as an electrolyte. Used anode for ICCP system was mixed metal oxide (MMO) titanium. Test factors were natural potential, CP potential, CP current, and 4-hour depolarization potential. From this study, it could be confirm that CP potential and current were highly influenced by temperature and relative humidity.

Cathodic Protection Behavior of Coastal Bridge Structure with Sacrificial Anode Cathodic Protection System (희생양극식 음극방식이 적용된 해안 교량 구조물의 방식거동)

  • Ha, Ji-Myung;Jin, Chung-Kuk;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.242-246
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    • 2012
  • This measurement represents the effectiveness of sacrificial anode cathodic protection (SACP) system in a coastal bridge structure. To verify the cathodic protection (CP) effect, the monitoring sensor (DMS-100) that could measure potential, corrosion rate, current, concrete resistivity, and temperature was embedded. The measurement conducted for three years after CP system was installed. Specifically, due to the fact that fresh water and sea water was repeated in the bridge structure, this bridge structure presented special CP behavior. Measurement factors were CP potential, CP current, concrete resistivity, and depolarization potential. In addition, visual inspection was also carried out. As a result of current and depolarization measurement, CP system was well activated in most piers.

Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Determination of optimum protection potential for cathodic protection of offshore wind-turbine-tower steel substructure by using potentiostatic method (정전위법에 의한 해상풍력 타워 구조물용 강재의 음극방식을 위한 최적방식전위 결정)

  • Lee, Jung-Hyung;Jung, Kwang-hu;Park, Jae-Cheul;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.230-237
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    • 2017
  • In this study, electrochemical methods were used to determine the optimum protection potential of S355ML steel for the cathodic protection of offshore wind-turbine-tower substructures. The results of potentiodynamic polarization experiments indicated that the anodic polarization curve did not represent a passivation behavior, while under the cathodic polarization concentration, polarization was observed due to the reduction of dissolved oxygen, followed by activation polarization by hydrogen evolution as the potential shifted towards the active direction. The concentration polarization region was found to be located between approximately -0.72 V and -1.0 V, and this potential range is considered to be the potential range for cathodic protection using the impressed current cathodic protection method. The results of the potentiostatic experiments at various potentials revealed that varying current density tended to become stable with time. Surface characterization after the potentiostatic experiment for 1200 s, by using a scanning electron microscope and a 3D analysis microscope confirmed that corrosion damage occurred as a result of anodic dissolution under an anodic polarization potential range of 0 to -0.50 V, which corresponds to anodic polarization. Under potentials corresponding to cathodic polarization, however, a relatively intact surface was observed with the formation of calcareous deposits. As a result, the potential range between -0.8 V and -1.0 V, which corresponds to the concentration polarization region, was determined to be the optimum potential region for impressed current cathodic protection of S355ML steel.

Effect for Steel Corrosion Protection in Concrete applying Surface Coating Anode and Solar Battery (표면(表面) 코팅 양극(陽極)과 태양전기(太陽電氣)를 이용한 콘크리트 중의 철근(鐵筋) 부식(腐食) 방지(防止)를 위한 효과)

  • Kim, Jong-Pil;Park, Kwang-Pil;Kim, Seong-Soo;Jung, Ho-Seop;Lee, Seung-Tae
    • Resources Recycling
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    • v.18 no.4
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    • pp.44-51
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    • 2009
  • In order to verify the effect of Surface Coating Anode and Solar Battery anode system, accelerated tests in the presence or absence of some chloride content and cracks were carried out. The potential-decay, protection potential and corrosion current density of reinforcing steel in concrete specimen were measured to evaluate the effectiveness of the system. From the test results, the application of the system led to the satisfaction on NACE's criterion in all mixtures of concrete. Additionally it was found that protection potential and corrosion current density were satisfied due to the application of Surface Coating Anode and Solar Battery anode system.