• 제목/요약/키워드: propionic acid

검색결과 507건 처리시간 0.023초

된장 숙성중 정미성분의 변화에 관한 연구 (II) -유리당과 휘발성, 비휘발성 유기산 (Studies on the Changes of Taste Compounds during Soy Paste Fermentation(II))

  • 김미정;이혜수
    • 한국식품조리과학회지
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    • 제9권4호
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    • pp.257-260
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    • 1993
  • 조미료로서 된장의 수용도를 높일 수 있는 자료를 제공하고자 황곡균으로 개량식 된장을 제조하고 이것을 180일 간 숙성시키면서 맛성분으로 중요한 역할을 하는 유리당, 휘발성 유기산, 비휘발성 유기산을 분석하였다. 그 결과 된장의 감미원인 유리당은 glucose>xylose> arabinose순서로 많이 존재하였다. 휘발성 유기산은 ace-tic, formic, butyric, propionic acid가 검출되었고 총량은 숙성 60일가지 증가하였다. 180일 숙성 후, 휘발성유기 산의 함량은 acetic>propioniclbutyric>formic acid순서 로 많이 존재하였다. 비휘발성 유기산은 담금 직후부터 succinic>glutaric>lactir acid순서로 많았으며 숙성 45일부터 tartaric>citric>malic이 뒤를 이은 순서로 생성되었다.

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Seta-flash 밀폐식 방법에 의한 n-hexanol+n-butyric acid 계와 n-butanol+propionic acid 계의 인화점 측정 (Measurement of Flash Points for n-hexanol+n-butyric acid and n-butanol+propionic acid by Seta-flash Closed Cup Method)

  • 하동명;이성진
    • 한국안전학회지
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    • 제29권6호
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    • pp.76-80
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    • 2014
  • The flash point is one of the most important physical properties used to determine the fire hazard of flammable liquid mixture and defined as the lowest temperature at which a liquid produces sufficient vapor to form a combustible mixture with air. The main purpose of this paper is to measure and predict the flash point of binary flammable miscible mixtures. The flash points for n-hexanol+n-butyric acid and n-butanol+propionic acid, were measured by using Seta-flash closed cup method. The experimentally derived data were correlated with the binary interaction parameters of the van Laar and NRTL equations through the optimization method. The flash points estimated by these correlations were compared with those calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

배양액(培養液)의 성분(成分) 및 배양시간(培養時間)의 변화(變化)에 따른 간흡충(肝吸?)의 산소소비(酸素消費)에 미치는 영향(影響) (Effects of Electrolytes, pH, Glucose, Acetic acid and Propionic acid on Oxygen Consumption in Clonorchis Sinensis)

  • 김화웅;최형곤;윤병오;하영호
    • 대한약리학회지
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    • 제5권1호
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    • pp.17-22
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    • 1969
  • Oxygen consumption by Clonorchis sinensis (C.S.) was observed in a medium of valuable pH of KRP, lack of certain electrolytes of KRP and of glucose, acetic acid or propionic acid was added to KRP. The results were as follows. 1. In a different solutions, KRP with or without $0.4%-glucose$, $0.9%-saline$ solution, the variation of oxygen consumption by C.S. was not significant. 2. Oxygen consumption by C.S. was inhibited by the solution of KCI, $CaCl_2$, or $MgSO_4$ in a 0.9% solution of saline. 3. Under the acidity, oxygen consumption was enhanced but under the alkality, it was inhibited. 4. Oxygen consumption by C.S. was inhibited by acetic acid or propionic acid in KRP solution. 5. C.S. keeping in KRP solution for a long duration, oxygen cosumption was reduced in the course of time.

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고농도 유기산폐수의 효모에 의한 분해연구 (Characteristics of Organic Acid Degradation by Yeast)

  • 김석원;허병기;김은기
    • KSBB Journal
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    • 제14권2호
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    • pp.136-140
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    • 1999
  • Characteristics of organic acid degradation by isolated yeast strain was investigated. Optimum initial pH was 5. Increase in cell mass was proportional to the decrease in organic acid degradation. Also no accumulation of byproduct was observed during degradation. Acetic acid degraded fast, followed by butyric acid and propionic acid in order. No significant substrate inhibition was observed up to 12 g/L of acetic acid 7 g/L of propionic acid, respectively. However, inhibition of butyric acid was significant above 4 g/L. Cell mass yield was 0.2-0.4 g cell/g acids and decreased at high decreased at high organic acid concentration. 95% of organic acid (7.5 g/L), corresponding to 13,000 ppm, was degraded in 30-40 hours.

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기질에 따른 미생물 전해 전지-혐기성 소화의 미생물 군집 특성 (Effect of Substrates on the Microbial Communities in a Microbial Electrolysis Cell and Anaerobic Digestion Coupled System)

  • 이채영;한선기
    • 한국수소및신에너지학회논문집
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    • 제30권3호
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    • pp.269-275
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    • 2019
  • This study was conducted to evaluate the microbial communities in coupled system of a microbial electrolysis cell and an anaerobic digestion. Glucose, butyric acid, propionic acid and acetic acid were used as substrates. The maximum methane production and methane production rate of propionic acid respectively were $327.9{\pm}6.7mL\;CH_4/g\;COD$ and $28.3{\pm}3.1mL\;CH_4/g\;COD{\cdot}d$, which were higher than others. Microbial communities' analyses indicated that acetoclastic methangens were predominant in all systems. But the proportion of hydrogenotrophic methanogens was higher in the system using propionic acid as a substrate when compared to others. In coupled system of a microbial electrolysis cell and anaerobic digestion, the methane production was higher as the distribution of hydrogen, which was generated by substrate degradation, and proportion of hydrogenotrophic methanogens was higher.

Effect of Applying Molasses and Propionic Acid on Fermentation Quality and Aerobic Stability of Total Mixed Ration Silage Prepared with Whole-plant Corn in Tibet

  • Chen, Lei;Guo, Gang;Yuan, Xianjun;Shimojo, Masataka;Yu, Chengqun;Shao, Tao
    • Asian-Australasian Journal of Animal Sciences
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    • 제27권3호
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    • pp.349-356
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    • 2014
  • The objective of this study was to evaluate the effects of molasses and propionic acid on the fermentation quality and aerobic stability of total mixed ration (TMR) silages prepared with whole-plant corn in Tibet. TMR (354 g/kg DM) was ensiled with four different treatments: no additive (control), molasses (M), propionic acid (P), and molasses+propionic acid (PM), in laboratory silos (250 mL) and fermented for 45 d. Silos were opened and silages were subjected to an aerobic stability test for 12 days, in which chemical and microbiological parameters of TMR silages were measured to determined the aerobic deterioration. After 45 d of ensiling, the four TMR silages were of good quality with low pH value and ammonia/total N (AN), and high lactic acid (LA) content and V-scores. M silage showed the highest (p<0.05) LA content and higher dry matter (DM) recovery than the control and P silages. P silage had lower (p<0.05) LA content than the control silage. During aerobic exposure, lactic acid contents decreased gradually in the control and M silages, while that of P and PM silages increased, and the peak values were observed after 9 d. M silage had similar yeast counts with the control silage (> $10^5$ cfu/g FM), however, it appeared to be more stable as indicated by a delayed pH value increase. P and PM silages showed fewer yeasts (< $10^5$ cfu/g FM) (p<0.05) and were more stable than the control and M silages during aerobic exposure. It was concluded that M application increased LA content and improved aerobic stability of TMR silage prepared with whole-plant corn in Tibet. P application inhibited lactic acid production during ensiling, and apparently preserved available sugars which stimulated large increases in lactic acid during aerobic exposure stage, which resulted in greater aerobic stability of TMR silage.

The Correlation of Lower Flash Point data with Activity Coefficient Models

  • Ha, Dong-Myeong;Lee, Sungjin
    • International Journal of Safety
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    • 제10권1호
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    • pp.5-9
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    • 2011
  • Two popular activity coefficient models, Wilson and NRTL equations have been used to correlate the published flash point data on the n-propanol + propionic acid and n-butanol + propionic acid systems through the optimization method. The results of these correlation were compared with the results calculated by Raoult's law. The optimization method were found to be better than those based on the Raoult's law. The optimization method based on the Wilson equation described the published data more effectively than was the case when the optimization method was based upon the NRTL equation.

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N-아실-α-아미노숙신이미드와 N-아실-α-아미노글루탈이미드의 합성 (Synthesis of N-acyl-α-aminosuccinimides and N-acyl-α-aminoglutarimides)

  • 정대일;김문주;송현애;김윤영;이용균;박유미;최순규;한정태;박민수
    • 생명과학회지
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    • 제14권1호
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    • pp.91-97
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    • 2004
  • 앞선 연구의 구조적 특성을 근거로 하여, 한 분자내에 MES 유발경련에 작용하는 cyclicimide의 구조를 포함하면, 그들의 구조가 경련 유발 수용체들에 상호 보완적으로 작용, MES및 PTZ유발 경련에 모두 작용할 수 있는 적용 범위가 넓은 항경련성 화합물이 될 수 있을 것으로 생각하여 N-acyl-$\alpha$-aminosuccinimide 1과 N-acyl-$\alpha$-aminoglutar- imide 2 유도체를 합성하였다. 먼저 (R)-2-benzyloxy carbonylamino-succinic acid 3을 출발 물질로 하여 N-acyl-a-aminosuccinimide 1 유도체인 (R)-Benzoic acid 4-benzyloxycarbonyl-amino-2-oxo-pyrrolidin-l-yl ester 6a, (R)4-nitro-benzoic acid 4-benzyloxycarbon-ylamino-2-oxo-pyrrolidin-1-yl ester 6b, (R)-4-nitro-benzoic acid 4-benzyloxycarbonylamino-2-oxo-pyrrolidin-1-yl ester 6c, 그리고 (R)-propionic acid 4-benzyloxycarbonylamino-2-oxo-pyrrolidin-1-yl ester 64를 합성하였다 또한 (R)-3-car-bobenzyloxy-aminoglutarrnic acid 7를 출발물질로 하여 N-acyl-$\alpha$-aminoglutarimide 2유도체인 (R)-(3-Benzyloxycarbonyl-amino-2,6-dioxo-piperidin-1-yloxy)-acetic acid methyl ester 10a, (R)-(3-benzyloxyarbonylamino-2,6-dioxo-piperidin-1-yloxy)-acetic acid ethyl ester l0b, 그리고 (R)-2-(3-benzylox-ycarbonylanino-2,6-dioxo-piperidin-1-yloxy)-propionic acid methyl ester l0c를 합성하였다. 합성된 화합물 6a, 6b, 6c, 6d, 10a, lOb, l0c에 대한 활성평가는 각 단계별 MES test와 PTZ test의 항경련 활성 시험 방법을 가지고 실험할 예정이다.

Effects of VFAs and Glucose Infusions on Ruminating Behavior of the Fasted-Goats

  • Oshiro, S.;Kawamura, T.;Hirayama, T.;Hirakawa, M.;Higoshi, H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제11권2호
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    • pp.171-175
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    • 1998
  • To test their roles in rumination behavior, metabolites (acetic acid, propionic acid, butyric acid and glucose) were intravenously infused into the jugular vein of goats during fasting. The heads of four female goats tested were locked in a stanchion of cages in an experimental room. Ruminating behaviors with regard to number of ruminations, ruminating time, number of remastications and remasticating time were significantly decreased by acetic acid infusion (p < 0.05), and tended to be depressed more on values in butyric acid infusion or glucose infusion than those in pre-infusions, but propionic acid infusion decreased a little. Those data suggest that rumination receptors sensitive to VFAs and glucose are more likely to be situated in the area, where they would respond too blood levels.

클리브랜드 개방식 장치를 이용한 2성분계의 인화점 (Flash Points of the Binary Solutions Using Cleveland Open Cup Tester)

  • 하동명;이성진
    • 한국화재소방학회논문지
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    • 제25권1호
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    • pp.57-62
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    • 2011
  • 인화점은 공정안전을 평가할 때 산업공정에서 가연성 액체의 중요한 연소 특성 가운데 하나이다. 본 연구에서는 클리브랜드 개방식 장치를 사용하여 n-propanol + formic acid계와 acetic acid + propionic acid계의 인화점을 측정하였다. 실험값은 Raoult의 법칙과 최적화 기법에 의해 추산된 값과 비교하였다. 그 결과, 최적화 기법에 의한 추산값이 Raoult의 법칙에 의한 추산값 보다 실험값에 더욱 근접하였다.