• Title/Summary/Keyword: properties UV

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Fabrication and characteristics of photofunctional polymer waveguide-type UV sensor (광기능성 폴리머 도파로형 자외선 센서의 제작 및 특성)

  • Kim, Kyu-Jin;Jang, Su-Won;Kang, Byoung-Ho;Kim, Do-Eok;Kwon, Dae-Hyuk;Kim, Sung-Hoon;Lee, Yong-Hyun;Kang, Shin-Won
    • Journal of Sensor Science and Technology
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    • v.15 no.4
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    • pp.231-236
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    • 2006
  • Single-mode planar waveguide type UV sensor was fabricated using SU-8 and photochromic dye. Polymer waveguide was fabricated $10{\mu}m$ width and $2{\mu}m$ thickness for single-mode operation. The UV sensor had an absorbance with $0.0396{\sim}0.114$ absorbance/mW respectively when the 5 mm sensing area was irradiated with UV for 3 sec. And sensor had a linear properties by sensing area variation. Proposed single-mode sensor had more excellent properties of UV sensitivity than other UV sensors.

Photocrosslinking of Polyester by UV irradiation (자외선 조사에 의한 폴리에스터의 광가교)

  • Yun, Deuk-Won;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.7-7
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    • 2011
  • Poly(ethylene terephthalate)(PET) is one of the most widely used materials in textile industry. It can have a low cost, silk-like handle, and excellent mechanical properties. Low thermal stability of PET had been a common problem limiting its high temperature application. The polyester have been known to have the disadvantage of degradation under ionized irradiation compared to crosslikable polymers such as polyethylene, polypropylene and polystylene. To improve thermal stability of PET, the PET films were photocrosslinked by UV irradiation. A hydrogen-abstractable photoinitiator was used to photocrosslink of PET by continuous UV irradiation. Photoinitiator addition increased the gel fraction. The photocrosslinking was attributed to the recombination of PET radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of the PET polymer chains by the added photoinitiator. Also the crosslinked PET showed higher thermal stability and mechanical strength with increasing UV energy. Polyester type films such as poly(ethylene naphthalate)(PEN) and poly(butylene terephthalte)(PBT) were also increased the gel fraction and improved thermal stability and mechanical properties by UV irradiation.

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NO2 gas sensing properties of UV activated ZnS nanowires at room temperature (상온에서 UV 활성화된 ZnS 나노와이어의 NO2 가스 검출 특성)

  • Kang, Wooseung
    • Journal of the Korean institute of surface engineering
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    • v.47 no.6
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    • pp.297-302
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    • 2014
  • ZnS nanowires were synthesized in order to investigate $NO_2$ gas sensing properties. They were grown on the sapphire substrate using ZnS powders. SEM (scanning electron microscopy) showed the diameter and length of the ZnS nanowires were approximately in the range of 50 - 100 nm and a few $10s\;{\mu}m$, respectively. They were also found to be composed of Wurtzite- structured single crystals from TEM (transmission electron microscopy) analysis. $NO_2$ gas sensing performance of the ZnS nanowire was measured with electrical resistance changes caused by $NO_2$ gas with a concentration of 1-5ppm. The sensor was UV treated with an intensity of $1.2mW/cm^2$ to facilitate charge carrier transfer. The responses of the ZnS nanowires to the $NO_2$ gas at room temperature, treated with UV of two different wavelengths of 365 nm and 254 nm, are measured to be 124.53 - 206.87 % and 233.97 - 554.83%, respectively. In the current work, the effect of UV treatment on the gas sensing performance of the ZnS nanowires was studied. And the underlying mechanism for the electrical resistance changes of the ZnS nanowires by $NO_2$ gas was also discussed.

Comparison of Durability for PUA Type Resin using Wear and Nano-indentation Test (마모 및 나노 압입 시험을 이용한 PUA계 레진의 내구성 비교)

  • Choi, Hyun Min;Kwon, Sin;Jung, Yoon-Gyo;Cho, Young Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.5
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    • pp.8-15
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    • 2018
  • Films with special properties (e.g., water-repellent films, optical films, anti-reflection films, and flexible films) are referred to as functional films. Recently, there has been interest in fine patterning methods for film fabrication. In particular there have been many studies that use a UV nanoimprint process involving a UV curing method. In this paper, a polymer film was fabricated by the UV nanoimprint process with a micro-pattern, and its durability was evaluated by a wear test and a nano-indentation test. The film mechanical properties (such as coefficient of friction, hardness, and modulus of elasticity) were measured. Moreover, the choice of PUA type resin used in the UV nanoimprint process was confirmed to impact the durability of the thin film. Despite making the polymer film samples using the same method and PUA type resin, different coefficient of friction, hardness, and modulus of elasticity values were obtained. PUA 4 resin had the most favorable coefficient of friction, hardness, and modulus of elasticity. This material is predicted to produce a high durability functional film.

Behavior of Organic Matter, Chlorine Residual and Disinfection By-Products (DBPs) Formation during UV Treatment of Wastewater Treatment Plant Effluents (하수처리장 방류수의 UV 처리시 유기물질, 잔류염소 및 소독부산물 생성 거동)

  • Han, Jihee;Sohn, Jinsik
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.61-72
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    • 2014
  • Study on effluent organic matter (EfOM) characteristic and removal efficiency is required, because EfOM is important in regard to the stability of effluents reuse, quality issues of artificial recharge and water conservation of aqueous system. UV technology is widely used in wastewater treatment. Many reports have been conducted on microbial disinfection and micro pollutant reduction with UV treatment. However, the study on EfOM with UV has limited because low/medium pressure UV lamp is not sufficient to affect refractory organics. The high intensity of pulsed UV would mineralize EfOM itself as well as change the characteristics of EfOM. Chlorine demand and DBPs formation is affected on the changed amounts and properties of EfOM. The objective of this study is to investigate the effect on EfOM, chlorine residual, and chlorinated DBPs formation with low pressure and pulsed UV treatment. The removal of organic matter through low pressure UV treatment is insignificant effect. Pulsed UV treatment effectively removes/transforms EfOM. As a result, the chlorine consumption is changed and chlorine DBPs formation is decreased. However, excessive UV treatment caused problems of increasing chlorine consumption and generating unknown by-products.

The Dyeing Properties of Korean Knotweed Extract(Ⅱ) - The UV-visible Spectrophotometric Characteristics of Korean Knotweed Extracts - (호장근 추출액에 의한 염색성(Ⅱ) - 호장근 추출액의 자외 · 가시부 분광 특성 -)

  • Kim, Mi Suk;Choe, Seok Cheol
    • Textile Coloration and Finishing
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    • v.13 no.5
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    • pp.10-10
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    • 2001
  • The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it′s extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of n-π/sup */ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their peaks disappeared after 5 hours exposure.

The Dyeing Properties of Korean Knotweed Extract( II ) - The UV-visible Spectrophotometric Characteristics of Korean Knotweed Extracts - (호장근 추출액에 의한 염색성(II) -호장근 추출액의 자외 . 가시부 분광 특성 -)

  • 김미숙;최석철
    • Textile Coloration and Finishing
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    • v.13 no.5
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    • pp.298-305
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    • 2001
  • The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it's extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of $n->\pi^*$ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their Peaks disappeared after 5 hours exposure.

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Properties and UV-cut effects of cotton fabric treated with $TiO_2$/PEG ($TiO_2$/PEG처리 면직물의 물성과 자외선 차단성능)

  • 김정진;장정대
    • Textile Coloration and Finishing
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    • v.14 no.4
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    • pp.223-228
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    • 2002
  • Cotton fabric was treated with $TiO_2$-PEG600 dispersion colloid by pad-dry-cure and wet-fixation process to improve the performance properties as well as UV-cut effect. As the concentration of $TiO_2$/PEG increased tensile strength, crease resistance, stiffness of treated cotton fabric increased. Application of wet-fixation method provided a further improvement in tensile strength, crease resistance, stiffness of treated cotton fabric. Cotton fabric treated with $TiO_2$/PEG was more efficient in UV-cut property than untreated cotton.

Synthesis and Properties of Photocurable Dimethylol Propionic Acid modified Hyperbranched Acrylates (광경화형 Dimethylol Propionic Acid 변성 하이퍼브랜치 아크릴레이트의 합성과 물성)

  • Kim, Dong Kook;Lim, Jin Kyu;Kim, Woo Geun
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.342-347
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    • 2005
  • Photocurable hyperbranched acrylates were prepared from acrylic acid and hyperbranched polyol (HBP-16, 32, 64). Physical properties of three kinds of photocurable hyperbranched acrylated were investigated. Thermal stability of UV cured film measured by TGA shifted to higher temperature with increasing of functionality. Hardness, abrasion resistance, and tensile strength of UV cured film also increased with increasing functionality of acrylate. Weathering test for UV cured film showed the value of yellow index increased with increasing functionality of acrylate.

Physical Properties of UV curable coating on plastic (플라스틱용 자외선경화형 도료의 물성연구)

  • 김일재;문명준
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.61-80
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    • 1998
  • To investigate in influence of photosensitizer used with benzophenone(BP) in the curing rate and physical properties of UV curable hard coating on plastic, we prepared UV curable clear and pigmented coatings with DEA, DMA, NPM and TEA as photosensitizer, respectively. The curing rate calculated from the decrease of the absorbance of acrylic double bond measured by FT-IR spectroscopy increased s follows; DEA>DMA>NPM>TEA. this order could be explained by the reactivity of diethylamino group of DEA and the ease of formation of activated complex between BP and photosensitizer during the curing process. In UV curable pigmented coatings, the order of curing rate increased as follows; DEA>DMA>TEA>NPM. It was found that the curing rate of the pigmented coating can be increased by light scattering of TiO$_2$. The hardness of coating film cured by photosensitization of DEA and DMA is higher than other photosensitizers due to the crosslinking reaction of DEA and DMA radical bound to polymer backbone.

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