• Title/Summary/Keyword: properties UV

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Study of the coloration factors of tinted lenses (착색렌즈의 색비율 정량화에 관한 연구)

  • Lim, Yong-Mu;Shim, Moon-Sik;Jung, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.37-46
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    • 2001
  • In this study, We compared the properties of tinted and colored lenses with the standards m the ordinary optical properties, coloration, UV, IR and luminous transmittance, color acceptance for traffic signal, and chromaticity. The UV, lR and luminous transmittance was analysed in the range of 175 nm to 3000 nm by using a UV-Vis-IR spectrophotometer and was used in the synthesis of spectrum of various color lens. A experimental function was made from the slope obtained from the transmittance change as a function of coloration time. We could expect the ordinary optical properties and color acceptance for traffic signal of various color lenses with the requirements of US standard(ANSI Z-80.3).

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Study on the Properties of UV-curable Polyurethane acrylate with reactive diluents content (자외선 경화형 폴리우레탄 아크릴레이트 수지의 반응성 희석제 함량에 따른 물성 연구)

  • Sim, Jae Hak;Seo, Eun Sun;Lee, Won Young;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.18 no.4
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    • pp.159-165
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    • 2017
  • In this study, we synthesized UV-curable urethane acrylates with different contents of BA, reactive diluent and characterized their physical properties such as thermal, mechanical properties, adhesive strength and flexibility resistance. From a result of DSC, Tg of polyol and acrylate resin were separated as the BA content increased more than 40%. Also, tensile strength, elongation and adhesive strength decreased with increasing the BA content. The UV-curable urethane acrylate with 40% BA has shown good flexibility resistance compared to other resin due to poor hardness and Tm of acrylate resin.

A Study on Anti-Aging Properties of Recycled Leather Using Shaving Scrap by Applying Antioxidant (피혁 폐기물을 재활용한 재생가죽의 내노화특성 연구)

  • Eun Ho Seo;Sung Wook Lim;Yun Seob Lee;Won Joo Kim;Eun Young Park
    • Textile Coloration and Finishing
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    • v.35 no.3
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    • pp.151-158
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    • 2023
  • In this study, we investigated the durability properties of the recycled leather using shaving scrap with antioxidant. Recycled leather sheets were manufactured by mixing shaving scrap and NB latex as a binder. HALS(Hindered Amine Light Stabilizer) and UVA(UV absorbers) were used as antioxidant. Mechanical properties such as hardness, tensile strength, elongation, tear strength and abrasion resistance were measured. Light aging resistance was evaluated using UV lamp and the degree of discoloration of the recycled leather sheets using a gray scale. In addition, to evaluate heat aging and UV aging, the degree of discoloration of the recycled leather sheets over time was measured using colorimeter. Washing fastness was evaluated on the degree of dyeing of recycled leather sheets for six type of multi-fiber woven fabrics (Acetate, Cotton, Nylon-66, Polyester, Acryl, Wool). To determine whether hazardous substances were detected in recycled leather sheets, the contents of arylamine and Cr 6+ were evaluated. As a result, when used in combination with antioxidant, the heat aging and light aging of recycled leather were improved and hazardous substance were not detected.

Effect of Crosslinking Agent on Adhesion Properties of UV Curable 2-EHA/AA Pressure Sensitive Adhesive (UV경화형 2-EHA/AA 점착제의 점착특성에 대한 경화제의 영향)

  • Kim, Ho-Gyum;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.281-286
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    • 2015
  • UV-cured acrylic copolymer pressure sensitive adhesive (PSA) having different amounts of crosslinking agents were prepared and adhesion properties were investigated. 0.01 wt% of MMT clay was dispersed in 2-ethylhexyl acrylate (2-EHA)/acrylic acid (AA) monomer mixture containing 0, 0.05, 0.1 and 0.3 wt% 1,6-hexandiol diacrylate (HDDA) for crosslinking. It was investigated that the curing behavior and surface chemistry of PSAs were merely affected by the presence of MMT clays. On the other hand, adhesive properties were influenced by the MMT addition; a cohesive failure was restrained due to improved molecular elasticity even in uncrosslinked acrylic PSAs. However, it was also appeared that combination of 0.3 wt% crosslinking agent and MMT loading might result in the damage of adhesion properties of PSAs possibly due to the lack of chain flexibility. In our studies, it is suggested that the 2-EHA/AA PSAs incorporating 0.01 wt% of MMT and crosslinked with 0.05 wt% of HDDA exhibited the balanced adhesion properties without severe cohesive failure during strip.

Optophysical Properties of Hydrogel Ophthalmic Lenses Containing Gallate Group (Gallate group이 포함된 친수성 안의료용 렌즈의 광물리적 특성)

  • Park, Se-Young;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.56 no.6
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    • pp.725-730
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    • 2012
  • HEMA (2-hydroxyethyl methacrylate), EGDMA (ethylene glycol dimethacrylate; cross-linker), MMA (methyl methacrylate) and AA (acrylic acid) were copolymerized with ethyl gallate and propyl gallate as additives in the presence of AIBN (2,2'-azobisisobutyronitrile; initiator). The measurement of physical properties of the produced copolymers exhibited that refractive index, water content, visible transmittance, tensile strength, and contact angle were in the range of 1.433-1.435, 38.71-38.99%, 85.4-88.8%, 0.2468-0.2740 kgf and $49.77-36.29^{\circ}$, respectively. The transmittances of the copolymers were measured to be in the range of 49.0-7.4% and 71.0-43.4% for UV-B and UV-A, respectively, indicating that the copolymers have UV-blocking effect. The produced copolymers containing ethyl gallate and propyl gallate satisfied the basic physical properties required for the fabrication of hydrogel contact lenses. The copolymers showed an increase of wettability and UV-blocking effects while having no significant change in water content compared to the gallate-free copolymers.

Improvement of Hard Coating Characteristics by UV-curable Organic/Inorganic Hybrids (자외선 경화형 유기/무기 하이브리드에 의한 하드코팅 특성 향상)

  • Han, Ji-Ho;Kim, Hyung-Il
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.626-631
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    • 2017
  • Transparent plastic substrates require an improvement in properties such as surface hardness and thermal stability for optical applications. In this study, UV-curable organic/inorganic hybrids were synthesized to improve those properties. In order to make the optimum dispersion of inorganic component into the organic matrix, an in situ synthetic method was applied based on sol-gel reaction. Dispersion of the inorganic component in the organic urethane acrylate matrix was improved by using a proper combination of sol-gel reaction and fast UV-curing resulting in the formation of the transparent coating layer. Various alkoxy silanes were employed to vary both the degree of curing and coating properties of UV-curable organic/inorganic hybrids. UV-cured organic/inorganic hybrid coatings showed an improved surface hardness and thermal resistance depending on the content of inorganic component.

A Study on the Properties Changes of Wool Fabrics Dyed with Safflower under Ultraviolet(UV)-Light (홍화 염색 모직물의 자외선에 의한 성능 변화 연구)

  • Shin, Youn-Sook;Choi, Seung-Youn
    • Fashion & Textile Research Journal
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    • v.10 no.2
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    • pp.249-253
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    • 2008
  • The purpose of this study was to investigate the properties changes of wool fabrics dyed with safflower red and yellow colorants under Ultraviolet(UV)-light. For this purpose, the wool fabrics dyed with safflower red and yellow colorants were compared with each other after uv-light exposure in terms of K/S value, color changes(${\Delta}E$), morphology, and strength retention. K/S value rapidly decreased with increasing exposure time, but K/S value of the samples dyed with safflower yellow colorants decreased less than that of the samples dyed with safflower red colorants. In color changes, as increasing exposure time, $L^*$ and $b^*$ increased, $a^*$ decreased, and thereby ${\Delta}E$ increased in the samples dyed with safflower red colorants, $L^*$ increased, $a^*$ and $b^*$ decreased, and so ${\Delta}E$ increased in the samples dyed with safflower yellow colorants, indicating fading away by uv-light and changes of hue, value and chroma value. But the color change of samples dyed with safflower yellow colorants was less than that of samples dyed with safflower red colorants. SEM pictures showed a severe degradation by uv exposure, regardless of colorants type. Tensile strength slowly decreased until 14 days, and rapidly decreased until 21 days and slowly decreased. Strength retention of the samples dyed with safflower yellow colorants was higher than that of the samples dyed with safflower red colorants.

Analysis of Mechanical Curing Properties Based on Vacuum Pressure of UV-Cured Composites (UV 경화형 복합재료의 진공압에 따른 기계적 경화 특성 분석)

  • Jang, Yong-Soo;Kim, Jeong-Keun;Go, Sun-Ho;Kim, Hong-Gun;Kwac, Lee-Ku
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.12
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    • pp.87-97
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    • 2020
  • In this study, a UV-cured GFRP molding is made using a combination of hand lay-up and resin transfer molding, and its properties are analyzed. The molded plates produced using various vacuum pressures (0 mmHg, -450 mmHg, and -760 mmHg) are examined via a comparison of hand lay-up molding and resin transfer molding. Tests are conducted by processing tensile specimens (ASTM D-5083), flexural test specimens (ASTM D-790), and ILSS test specimens (ASTM D-2344) according to each ASTM standard with a molded plate. Similarly, the UV-cured GFRP molding is compared against GFRP using epoxy. It was confirmed that the mechanical strengths of all the specimens increased when the vacuum pressure was increased and when UV curing was applied. This is believed to be because as the vacuum pressure increases, the pores of the cured specimen are removed, thereby reducing defects, and the bonding force between the glass fiber and the resin is stronger than that of the epoxy resin. It is expected that if resin transfer molding methods and UV-cured resins are used for molding GFRP composites in industry, products with better mechanical properties and faster curing time will be produced.

A new evaluation method of UV curing process by using electrical properties (I) (전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법(I))

  • Lee, Mun-Hag;Kim, Sung-Bin;Lee, Tae-Hoon;Park, Seong-Soo;Son, Se-Mo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.21 no.2
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    • pp.55-65
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    • 2003
  • A novel evaluation method is investigated for UV curing process in printing system. The method is based on the measurement of conducivity change by the photopolymerization of UV curable inks and paints. It is found that the decrease of conductivity is caused by photopolymerization of epoxy monomer during UV curing process of ink film and the by the rate of UV curing. It is possible to make the dynamical evaluation the curing rate of UV curable ink in curing process by this method.

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The morphology and Phtoelectrochemical properties of $TiO_2$ electrode with UV Treatment and Oxygen Injection (산소와 UV 조사된 $TiO_2$ 광전극의 표면형상과 전기화학적 특성)

  • Zhao, Xingguan;Jin, En Mei;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.240-240
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    • 2010
  • In this paper, in these case of photoelectrode using UV treatment after oxygen solar conversion efficiency is increased. According to oxygen injection UV treatment will removal residual organics and increase the TiO2 surface area but also UV treatment can affect the same chemical action of ozone treatment. More porous networks and larger porosities were obtained in the TiO2 films prepared UV treatment after oxygen injection.

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