• Bulletin of the Korean Chemical Society
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• 제20권12호
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• pp.1457-1463
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• 1999

Structure and their redox property of the vanadium oxides prepared by decomposing NH₄VO₃ at various temperatures were studied by XRD, SEM, XPS, and temperature programmed reduction/temperature programmed oxidation (TPR/TPO) experiment. All TPR profiles have two sharp peaks in the temperature range 650-750℃, and the area ratio of the two sharp peaks changed from sample to sample. There were three redox steps in TPR/TPO profiles. The oxidation proceeded in the reverse order of the reduction process, and both the reactions proceeded via quite a stable intermediates. The changes of the morphological factor $(I_{(101)}/I_{(010)})$, the ratio of $O_{1S}$ peak area (O$_{1S}$( α)/O$_{1S}$( β)) in the XPS results, and the ratio of hydrogen consumption in TPR profiles with various vanadium oxides showed the distinct relationship between the structural property and their redox property of vanadium oxides. The change of the specific yield of phthalic anhydride with various vanadium oxides showed a very similar trend to those of the peak area ratio in TPR profiles, which meant that the first reduction step related to the partial oxidation of o-xylene on the vanadium oxide catalyst.

• 전기의세계
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• 제31권12호
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• pp.817-822
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• 1982

마이크로 컴퓨터 입출력 방법을 논의한다. 세가지 입출력 방법으로 Programmed I/O와 Interrupt와 DMA에 대해서 설명하고, 각 마이크로 프로세서의 입출력의 특징을 비교한다.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1999년도 제14차 학술회의논문집
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• pp.61-64
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• 1999

In this paper, a technique to expand the Input and Output (I/O) of the programmable logic controller (PLC) using remote I/O module is presented. The controller and the remote I/O module should have the same protocol and are interfaced through RS 485. Each remote I/O module consists of 16 digital input and 16 digital output, and the maximum of 32 remote I/O module can be linked to one controller. The remote I/O is programmed for interrupt request to controller independently. Therefore, there is no affect to the scan time of the controller. Using this technique, the PLC can be efficiently applied to the several hundred meters different control points such as the ON-OFF control fur the agriculture farm, the building automation system, a multi group of machine control.

• 한국인터넷방송통신학회논문지
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• 제13권2호
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• pp.59-65
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• 2013

1970-1980년대에 개발된 8-16비트 마이크로프로세서들이 오늘날의 우수한 성능을 갖는 컴퓨터 발달의 시초가 되었으며 교육현장에서 아직도 사용되고 있는 곳이 많이 있다. 본 연구에서는 이러한 소형 8-32비트 마이크로프로세서 시스템에서 사용되는 인텔계열 마이크로프로세서의 Programmed I/O 명령 실행 싸이클에 따른 실행시간을 구하여 비교하였다. 비교 결과 마이크로프로세서 클럭 주파수 4MHz와 12MHz의 경우, 8비트용 8051이 명령 실행에 따른 많은 클럭수로 인하여 8비트 8085 및 16비트 8086 마이크로프로세서의 실행시간보다 길었으며, 실제 많이 사용하는 클럭 주파수의 경우는 8085, 8086, 8051 및 80386의 순으로 명령실행 시간이 빨라짐을 보여 주었다. 주로 국내에서 많이 사용하는 인텔계열 마이크로프로세서에 의한 I/O 프로그램 실행시간을 비교해봄으로써 마이크로프로세서의 실시간 제어를 위한 인터페이스 등에 도움이 될 수 있다.

• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1470-1474
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• 2009

Thermal and photochemistry of methyl iodide ($CH_3I)\;adsorbed\;on\;D_2O$ ice film on Cu(111) at 100 K were studied using temperature-programmed desorption (TPD) time-of-flight mass spectrometry (TOF-MS), X-ray and ultraviolet photoelectron spectroscopies. On the basis of TPD, multilayer and monolayer $CH_3I$ molecules desorb from $D_2O$ ice layer at 120 and 130 K, respectively. Photo-irradiation at 100 K exhibits dramatic changes in the TPD and I $3d_{5/2}\;XPS\;of\;CH_3I$ on ice film, due to a dramatic dissociation of $CH_3I$. The dissociation is likely activated by solvated electrons transferred from the metal substrate during photo-irradiation. No other photo-initiated reaction products were found within our instrumental detection limit. During photo-irradiation, the $CH_3I$, $CH_3$ and I could be trapped (or solvated) in ice film by rearrangement (and self-diffusion) of water molecules. A newly appeared parent molecular desorption peak at 145 K is attributed to trapped $CH_3I$. In addition, the $CH_3$ and I may diffuse through ice and chemisorb on Cu(111), indicated by TPD and I $d_{5/2}$ XPS taken with photo-irradiation time, respectively. No molecular ejection was found during photo-irradiation at 100 K. The work functions for $CH_3I/Cu(111),\;D_2O/Cu(111)\;and\;CH_3I/D_2$O/Cu(111) were all measured to be about 3.9 eV, 1.0 eV downward shift from that of clean Cu(111).

• Bulletin of the Korean Chemical Society
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• 제28권4호
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• pp.529-532
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• 2007

Combined temperature programmed reaction (TPR) and infrared (IR) spectroscopic studies for Fischer- Tropsch reaction have been performed over Ru/SiO2 and Ru-Ag/SiO2 supported catalysts. Reaction of linearly absorbed CO with hydrogen starts at 375 K over Ru/SiO2 catalyst and reaches maximum at 420 K accompanied with an intensity decrease of linear CO absorption. The reaction with bridged absorbed CO peaks around 510-535 K. Addition of Ag yields mixed Ru-Ag bimetallic sites while it suppresses the formation of bridged bonded CO. Formation of methane on this modified surface occurs at 390 K and reaches maximum at 444 K. Suppression of hydrogen on the Ag-doped surface also occurs resulting in the formation of unsaturated hydrocarbons and of CHx intermediates not observed with Ru/SiO2 catalyst. Such intermediates are believed to be the building blocks of higher hydrocarbons during the Fischer-Tropsch synthesis. Linearly absorbed CO is found to be more reactive as compared to bridged CO. The Ag-modified surface also produces CO2 and carbon. On this surface, hydrogenation of CO begins at 390 K and reaches maximum at 494 K. The high temperature for hydrogenation of absorbed CO and C over Ru-Ag/SiO2 catalyst as compared to Ru/SiO2 catalyst is due to the formation of Ru-Ag bimetallic surfaces impeding hydrogen adsorption.

• 대한화학회지
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• 제33권1호
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• pp.135-142
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• 1989

HZSM-5를 觸媒로 하여 메탄올과 이소부틸렌으로부터 Methyl tertiary butyl ether(MTBE)의 氣相合成實驗을 하였으며, zeolite 觸媒의 SiO$_2/Al_2O_3$ 比 및 反應條件의 영향을 硏究하였다. 각 觸媒들은 pyridine을 吸着시켜 temperature programmed desorption(TPD) 및 IR法으로 酸點의 세기와 特性을 조사하였으며, 승온탈착실험을 통하여 각 反應物 및 生成物의 吸着特性을 검토하였다. HZSM-5의 SiO$_2/Al_2O_3$比가 증가할수록 强한 酸點의 수는 감소하여 메탄올의 脫水反應은 억제되고 MTBE에 대한 선택도가 증가하였다. MTBE에 대한 전환율과 선택도는 $i-C_4H_8$의 細孔內 확산저항에 의하여 큰 영향을 받음을 알 수 있었다. MTBE合成反應은 發熱的이어서, 전반적으로 80$^{\circ}$C의 반응온도가 合成에 적합하였다. 한편 각 觸媒上에 生成된 coke의 特性을 TG, DTA 및 IR spectrum으로 측정하였다. 침착된 coke의 量은 HY > H-Mordenite > HZSM-5順이었으며, H-Mordenite에 있어서는 누적된 coke의 양이 HZSM-5보다 현저하지는 않았으나, 細孔의 配向이 1方向性이므로 반응시간이 길어짐에 따라 심한 活性減退가 일어났다. HY는 큰 細孔을 가지고 있어 M$i-C_4H_8$의 重合이 쉽게 일어났으며, HZSM-5에 비하여 많은 coke의 참착과 빠른 活性減退를 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제19권12호
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• pp.1363-1368
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• 1998

Mo/γ-Al2O3 catalysts were prepared by impregnation method in various conditions to identify the states of surface Mo species. TPR (Temperature-Programmed Reduction) and Raman spectroscopy were applied to analyze the surface Mo species. TPR analysis revealed that MoO3 was reduced to Mo through MoO2, the intermediate state and the increase of Mo loading enhanced the reducibility of Mo oxide till the formation of monolayer coverage. High temperature calcination induced oxygen defects in MoO3 giving their unstable states for easier reduction. Raman spectroscopy analysis showed that the increase of Mo loading induced the polymeric Mo oxide.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2006년도 추계학술대회논문집
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• pp.844-847
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• 2006

In this paper, the forced vibration of damped composite beam with I-type section was analyzed. The damping material was assumed to have complex Young's modulus. Damped composite beam structure could be modeled using equivalent beam elements with less D.O.F. rather than solid elements. Finite element method for 6 D.O.F. equivalent beam element was formulated and programmed using complex values. The results of frequency responses revealed good agreement with those of NASTRAN in both Euler beam model and Timoshenko beam model.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2005년도 ICCAS
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• pp.575-579
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• 2005

In this paper, the development of an IMM(Injection Molding Machine) controller is discussed. Presently, the Mold Close and Open Control Method of a toggle-type IMM is open-loop control. Through the development, a PC based control system was built instead of an existing controller and a closed-loop control replaced the previous control method by using PC based PLC. To control the nonlinear system of toggle type clamping unit, a fuzzy PI control algorithm was selected and it was programmed by an IL(Instruction List) and a LD(Ladder Diagram) on a PC based PLC. The application of fuzzy algorithm as the control method was also considered to change a control object like a mold replacement or an additional apparatus. For the development of an IMM controller, PC based PLC of PCI card type, distributed I/O modules with CANopen and Industrial PC and HMI (Human Machine Interface) software were used.