• Title/Summary/Keyword: product rate variation

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Limitations of the Transition State Variation Model(5) Dual Reaction Channels for Solvolysis of Dansyl Chloride

  • Koo In Sun;Lee Ocg-Kyeong;Lee Ikchoon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.4
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    • pp.395-398
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    • 1992
  • Rate of solvolysis of dansyl chloride in aqueous binary mixtures of acetone, methanol and ethanol are reported. Kinetic solvent isotope effects in methanol and product selectivities in alcohol-water mixtures are also reported. Kinetic data are interpreted with the Grunwald-Winstein and Kivinen equations. The value of $k_{CH3OH}/k_{CH3OD}=1.76$ suggests that a general have catalyzed and/or an $S_AN$ pathway is operative in methanol, a less polar solvent. Rate-rate profiles for solvolysis of dansyl chloride in the aqueous binary media indicate a change in reaction channel from $S_AN$ (in less polar media) to $S_N2$ (in more polar media) mechanism.

Relationship between Plant Protection Rate and Coefficient of Variation of Microbial Products for Ginseng Cultivation (인삼재배용 미생물 제품의 식물보호율과 변이계수와의 관계)

  • Lee, Byung-Dae;Park, Hoon
    • Journal of Ginseng Research
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    • v.33 no.2
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    • pp.127-131
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    • 2009
  • The plant protection rate of the marketed microbial products for ginseng cultivation was investigated against Rhizoctoina solani and Pythium sp. in a seedling pot experiment. A significant difference was found among the mean plant protection rates (Pm) of the microbial products, including Tolclofos-methyl (Rhizolex). The best microbial product, C-ISR2, showed a 33% and 33.6% net Pm (total Pm-control Pm) in the two tests against Rhizoctonia solani. In one test with a 58.6% control plot Pm, the total pm was 91.6%, indicating that plant protection can be done only with a microbial product in a well-conditioned field. The net Pm of C-ISR2 against Pythium sp. was 26.4%. The net Pm of a microbial product against a pathogen seems to be fixed. A significant negative linear correlation was found between the Pm and the coefficient of variation (CV) of the protection rate in all the three experiments. This indicates that the protection processes of control, microbial products, and chemical pesticides are in the same system. Pm was only dependent on CV, probably due to each seedling's microenvironment. In the linear correlation equation between the Pm and the CV of the microbial products and the control plot, the intercept of the vertical axis will be the theoretical Pm when CV is zero.

Improvement of an Early Failure Rate By Using Neural Control Chart

  • Jang, K.Y.;Sung, C.J.;Lim, I.S.
    • International Journal of Reliability and Applications
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    • v.10 no.1
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    • pp.1-15
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    • 2009
  • Even though the impact of manufacturing quality to reliability is not considered much as well as that of design area, a major cause of an early failure of the product is known as manufacturing problem. This research applies two different types of neural network algorithms, the Back propagation (BP) algorithm and Learning Vector Quantization (LVQ) algorithm, to identify and classify the nonrandom variation pattern on the control chart based on knowledge-based diagnosis of dimensional variation. The performance and efficiency of both algorithms are evaluated to choose the better pattern recognition system for auto body assembly process. To analyze hundred percent of the data obtained by Optical Coordinate Measurement Machine (OCMM), this research considers an application in which individual observations rather than subsample means are used. A case study for analysis of OCMM data in underbody assembly process is presented to demonstrate the proposed knowledge-based pattern recognition system.

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A Study on the Flat Surface Generation Using Flexible Disk Grinding (유연성 디스크 정밀연삭 가공중 평면가공에 관한 연구)

  • Yoo, Song Min
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.7
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    • pp.158-166
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    • 1996
  • In this study, a flexible disk grinding process is applied in order to produce high precision product. A new model was developed considering feed motion along horizontal and vertical direction. Different types of feed speed variation was tested with respect to distinct process stages in order to achieve flat surface. It was observed that highest order polynomial form for both horizontal and vertical feed speed variation among the proposed categories produced surface close to flat one. Disk deflection trend during the process was visualized confirming the proposed scheme. Cutting force and VRR(volume removal rate) was observed as an aid to process planning.

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MICROSTRUCTURAL CHARACTERISTICS OF HOT FORGED AL 6061 ALLOY

  • Kwon Y.-N.;Lee Y.-S.;Lee J.-H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10b
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    • pp.55-58
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    • 2003
  • Many researches have been already done on the issues of high temperature deformation and the microstructural evolution. The information has been very useful for the plasticity industry, especially successful for the extrusion. However, the parts made with forging usually have a complex shape. It is difficult to control the distribution of the variables like strain, strain rate and temperature rise due to the working heat during a hot-forging process. Consequently, the microstructural variation could be occurred depending on the plastic deformation history that the forged part would get during a hot forging. In the present study, the microstructural characteristic of a hot-forged 6061 aluminum alloy has been discussed on the aspect of grain size evolution. A forging of 6061 aluminum alloy has been carried out for a complex shape with a dimensional variation. Also, finite element analysis has been done to understand how the deformation variables such as strain, strain rate give an influence on the microstructure of a hot forged aluminum product.

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Procurement Pricing Strategy for Remanufacturing System under Uncertainty in Quality of Used Product (회수 품질이 불확실한 재제조 시스템의 회수 가격 결정 모형)

  • Lee, Ji Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.691-697
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    • 2016
  • Remanufacturing refers to restoring a used product to an acceptable condition for resale in the market of remanufactured items. In this paper, we deal with the acquisition price and remanufacturing decision for remanufacturing systems in the case where the demand for the remanufactured product in a single period is known and the return quantity of the used product is determined by its acquisition price. The quality of the acquired used product is categorized into two classes, high and low, through inspection and different qualities incur different remanufacturing costs. The probability that the acquired used product is categorized as high class can be a constant or random variable. We derive the expected total cost functions, obtain the optimal solutions, and interpret the managerial meaning of the optimal solution for each case. The sensitivity of the optimal solution with respect to the variation of the inspection cost and uncertainty of the quality of the used product is investigated through numerical examples.

A Study on Corrosive Wear Characteristics and the Mechanism of Austempered Low-Alloy Ductile Iron (오스템퍼링 한 저합금구상흑연주철의 부식마멸특성 및 그 기구에 관한 연구)

  • 박흥식;진동규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1404-1411
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    • 1993
  • This study was undertaken to investigate the corrosive wear charateristics upon various transformation condition of austempered low-alloy ductile cast iron in corrosive environments against mating specimen made of the hardened SM45C. The corrosive wear test was carried out by rubbing the annular surface of two test pieces in distilled water and aqueous solution at constant sliding speed of 0.5m/s. In severe wear region, the corrosive wear rate Wc increased hastily with NaCl concentration owing to intermetallic adhesion but Wc went down slowly in mild wear region due to lubricating effect of the corrosion product. The critical sliding distance decreased with increasing NaCl concentration due to increased generation rate of the corrosion product and the specific corrosive wear rate has maximum in 1% NaCl aqueous solution at mild wear region. With the variation of matrix, the corrosive wear resistance of the fine acicular bainite was higher than that of coarse upper bainite because of reducing the local cell reaction by carbides. A growth in volume fraction of retained austenite in matrix increased the Wc due to soften surface, but has a declining tendency of Wc in mild wear region.

Developing Optimal Demand Forecasting Models for a Very Short Shelf-Life Item: A Case of Perishable Products in Online's Retail Business

  • Wiwat Premrudikul;Songwut Ahmornahnukul;Akkaranan Pongsathornwiwat
    • Journal of Information Technology Applications and Management
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    • v.30 no.3
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    • pp.1-13
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    • 2023
  • Demand forecasting is a crucial task for an online retail where has to manage daily fresh foods effectively. Failing in forecasting results loss of profitability because of incompetent inventory management. This study investigated the optimal performance of different forecasting models for a very short shelf-life product. Demand data of 13 perishable items with aging of 210 days were used for analysis. Our comparison results of four methods: Trivial Identity, Seasonal Naïve, Feed-Forward and Autoregressive Recurrent Neural Networks (DeepAR) reveals that DeepAR outperforms with the lowest MAPE. This study also suggests the managerial implications by employing coefficient of variation (CV) as demand variation indicators. Three classes: Low, Medium and High variation are introduced for classify 13 products into groups. Our analysis found that DeepAR is suitable for medium and high variations, while the low group can use any methods. With this approach, the case can gain benefit of better fill-rate performance.

An Improved, Reliable and Practical Kinetic Assay for the Detection of Prekallikrein Activator in Blood Products

  • Shin, In-Soo;Shim, Yun-Bo;Hong, Choong-Man;Koh, Hyun-Chul;Lee, Seok-Ho;Hong, Seung-Hwa
    • Archives of Pharmacal Research
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    • v.25 no.4
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    • pp.505-510
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    • 2002
  • An improved kinetic assay for prekallikrein activator (PKA), a potential vasodilator, has been developed to be used as an indicator for quality control during production of human albumin preparations. It consists of two reaction stages. In the first stage, PKA and prekallikrein are incubated at $37^{\circ}C$ for 45 min to allow the transformation into kallikrein. Kallikrein, a serine protease, catalyzes the splitting of p-nitroaniline (pNA) from its substrate H-D-Pro-Phe-Arg-pNA(S-2302). The rate at which pNA is released was measured spectrophotometrically at 405 nm. Prekallikrein, a substrate of PKA was purified by DEAE ion-exchange chromatography and the major potential variations in the assay were optimized; pH 8.0 and 150 mM sodium chloride were chosen to give a proper ionic strength. Reaction times in the range of 10 to 360 min provided linear dose-response curves. The concentration of prekallikrein was adjusted to fall between 1:1 and 1:3 dilutions to generate a linear standard calibration curve. Under the optimized conditions, reproducibility was checked. In a precision test, the coefficient of variation (CV) stayed within ${\pm}4%$ and the dose-response curve showed a good correlation (${r^2}=0.999$). An accuracy test with an international standard of PKA afforded a mean recovery of 97.5%.

The study on mechanical properties of PC panel with steam curing condition (증기양생 조건에 따른 터널 PC 패널의 물리적 특성에 관한 연구)

  • Ma, Sang-Joon;Jang, Pil-Sung;Shiin, Jin-Yong;Nam, Kwan-Woo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.10 no.1
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    • pp.17-24
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    • 2008
  • Many problems exist in the current cast in place concrete lining used in domestic tunnel construction. Especially, the crack of tunnel lining brings about a social and economic problem. It has a lot of influence on stability of structure and the fine finish of lining. So enormous repair-work and reinforcement of tunnel lining could occur an running out of government's budget. In our country, there are domestic production enterprises which produce a special pre-cast concrete product, but the technical level of them is still far behind compared to developed countries. Also, optimum steam coring method is important for the production of high quality product. But there is no regulation of steam curing method in our country. This study is to investigate the properties of PC panel according to the variation of steam curing conditions such as presteaming time and rate of temperature rise. The result shows that the optimum presteaming time of steam curing method in PC panel is more than 1 hour and the desirable rate of temperature in curing chamber is about $20^{\circ}C/hr$.

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