• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.636-642
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• 2022

The "Hydrogen Economic Activation Road map" was announced in 2019, and hydrogen demand is expected to exceed 470,000 tons per year in 2022 and keep increasing. Under this circumstance, it has become important to understand the greenhouse gas (GHG) emissions associated with various hydrogen production pathways. In this study, the evaluation of life cycle GHG emissions regarding the hydrogen produced as by-product from coke oven gas (COG) in steel mill is conducted. To cover the possible range of operations, three literatures were reviewed and their data of inputs and outputs for the process were adopted for calculation. Life cycle inventories and emission factors were mostly referred to GaBi and Intergovernmental Panel on Climate Change (IPCC) guidelines, respectively. When there are multiple products from a single process, the energy allocation method was applied. Based on these sources and the assumptions, the life cycle emission values of COG-based hydrogen were found to be 3.8 to 4.7 kg/CO₂-eq./kg-H₂.

• 에너지공학
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• 제16권2호
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• pp.58-63
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• 2007

최근 신 고유가 시대를 맞이하여 천연가스를 이용한 합성석유 제조기술 개발의 중요성이 점차로 부각되고 있는 상황이다. GTL(Gas-to-Liquids) 공청은 현재의 고유가 상황에서 경쟁력 있는 사업 분야를 제공 할 것으로 분석되고, GTL 제품은 환경오염물질이 거의 없어 21 세기의 환경규제 강화 추세에 효과적으로 대응할 수 있는 청정연료이다. GTL 공정은 크게 천연가스의 주성분인 메탄의 리포밍 반응을 거쳐 합성가스 ($CO+H_{2}$)를 제조하는 단계, 이 합성가스로부터 FT 합성반응을 통하여 액체 합성원유를 제조하는 단계, 합성원유를 개질하는 단계 (수첨분해/수첨이성질화)로 이루어진다. 본 총설에서는 GTL 기술의 개요와 세계적인 개발 동향을 천연가스 reforming 기술과 FT 합성유 제조 기술에 중점을 두고서 소개하고자 한다.

• 한국토양비료학회지
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• 제16권2호
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• pp.179-182
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• 1983

비닐하우스내(內) 풋고추 재배단지에서 카바이트 부산소석회 시용(施用)에 의(依)한 피해실태조사와 그 원인(原因)을 구명(究明)하기 위하여 재현시험을 실시한 결과(結果) 1. 카바이트 부산소석회 시용구에서는 정식후(定植後) 새 뿌리 발생이 전연 안되었으며 엽면(葉面)에는 많은 암갈색(暗褐色) 얼룩점이 산재(散在)하였고 위조낙엽(萎凋落葉)되면서 뿌리 내림이 불량(不良)하였다. 2. 카바이트 부산소석회 시용구의 식물체는 소석회 시용구의 식물체보다 호흡량(呼吸量)이 떨어졌다. 3. 카바이트 부산소석회에는 아세틸렌가스($C_2H_2$) 발생이 많았고 이 석회를 시용(施用)한 피해(被害) 토양에서도 가스가 발생되었으며 발생량이 많을수록 고추의 피해(被害)가 심(甚)하였다.

• Nuclear Engineering and Technology
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• 제47권1호
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• pp.11-25
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• 2015

The accident at Japan's Fukushima Daiichi nuclear power plant in March 2011, caused by an earthquake and a subsequent tsunami, resulted in a failure of the power systems that are needed to cool the reactors at the plant. The accident progression in the absence of heat removal systems caused Units 1-3 to undergo fuel melting. Containment pressurization and hydrogen explosions ultimately resulted in the escape of radioactivity from reactor containments into the atmosphere and ocean. Problems in containment venting operation, leakage from primary containment boundary to the reactor building, improper functioning of standby gas treatment system (SGTS), unmitigated hydrogen accumulation in the reactor building were identified as some of the reasons those added-up in the severity of the accident. The Fukushima accident not only initiated worldwide demand for installation of adequate control and mitigation measures to minimize the potential source term to the environment but also advocated assessment of the existing mitigation systems performance behavior under a wide range of postulated accident scenarios. The uncertainty in estimating the released fraction of the radionuclides due to the Fukushima accident also underlined the need for comprehensive understanding of fission product behavior as a function of the thermal hydraulic conditions and the type of gaseous, aqueous, and solid materials available for interaction, e.g., gas components, decontamination paint, aerosols, and water pools. In the light of the Fukushima accident, additional experimental needs identified for hydrogen and fission product issues need to be investigated in an integrated and optimized way. Additionally, as more and more passive safety systems, such as passive autocatalytic recombiners and filtered containment venting systems are being retrofitted in current reactors and also planned for future reactors, identified hydrogen and fission product issues will need to be coupled with the operation of passive safety systems in phenomena oriented and coupled effects experiments. In the present paper, potential hydrogen and fission product issues raised by the Fukushima accident are discussed. The discussion focuses on hydrogen and fission product behavior inside nuclear power plant containments under severe accident conditions. The relevant experimental investigations conducted in the technical scale containment THAI (thermal hydraulics, hydrogen, aerosols, and iodine) test facility (9.2 m high, 3.2 m in diameter, and $60m^3$ volume) are discussed in the light of the Fukushima accident.

• Journal of the Korean Wood Science and Technology
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• 제14권2호
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• pp.21-28
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• 1986

목질물질(木質物質)인 톱밥, 볏짚 그리고 왕겨를 열분해(熱分解)하여 기상물질(氣相物質)을 합성(合成)하기 위해, 석영으로 설계 제작된 반응탑(反應塔)을 사용하였다. 최초의 반응온도 350$^{\circ}C$로부터 열분해(熱分解)와 gasification 반응(反應)이 완결된다고 예상되는 550$^{\circ}C$까지 가열하였다. 촉매가 반응온도에 어떤 영향을 미치는지 조사하기 위해 $K_2CO_3$와 $Na_2CO_3$를 촉매로 사용하였다. 합성(合成) gas chromatograph와 mass spectrometer에 의해 CO, $CO_2$, $CH_4$ 그리고 $CH_3CHO$등인 것으로 판명되었다. 합성(合成) gas의 수율(收率)과 조성(組成)은 반응온도(反應溫度)와 이 반응에 사용되는 촉매에 달려있지만, 톱밥을 시료(試料)로 반응온도 550$^{\circ}C$, $K_2CO_3$를 촉매로 사용한 반응(反應)에서 생성되는 gas 체적(體積)은 1,800$m{\ell}$/g 톱밥에 달한다.

• Korean Membrane Journal
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• 제5권1호
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• pp.43-53
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• 2003

The selectivity of a gas in the carbon molecular sieve membrane (CMSM) can be expressed as the ratio of the product of the diffusivity and the solubility of two different gases. The diffusivity is also expressed as the product of the entropy and the total energy (kinetic and potential energy) in the nano-sized pore of the membrane. The present study calculates the entropic-energy and selectivity of penetrant gases such as H$_2$, O$_2$, N$_2$, and CO$_2$ from the gas-in-a box theory to physically analyze the diffusivity of penetrant gas in slit-shaped pore of CMSM focusing on the restriction of gas motion based on the size difference between penetrant gas pairs. The contribution of each energy term is converted to entropic term separately. By the conjugated calculation for each entropic-energy, the entropic effects on diffusivity-selectivity for gas pairs such as H$_2$/N$_2$, CO$_2$/N$_2$, and O$_2$/N$_2$ were analyzed within active pore of CMSM. In the activated diffusion domain, the calculated value of entropic-selectivity lies between 9.25 and 111.6 for H$_2$/N$_2$, between 3.36 and 6.0 for CO$_2$/N$_2$, and between 1.25 and 16.94 for O$_2$/N$_2$, respectively. The size decrement of active pore in CMSM had the direct effect on the reduction of translational entropic-energy and the contribution of vibrational entropic-energy for N$_2$, O$_2$, and H$_2$ was almost negligible. However, the vibrational entropic term of CO$_2$ might extravagantly affect on the entropic-selectivity.

• 연구논문집
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• 통권29호
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• pp.5-15
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• 1999

Present study deals with performance analysis of an inert gas generator (IGG) which is to be used as an effective mean to suppress the fire. The IGG uses a turbo jet cycle gas turbine engine to generate inert gas for fire extinguishing. It is generally known that a lesser degree of oxygen content in the product of combustion will increase the effectiveness of fire suppressing. An inert gas generator system with water injection will bring advantages of suffocating and cooling effects which are considered as vital factors for fire extinguishing. As the inert gas is injected to the burning site, it lowers the oxygen content of the air surrounding the flame as well as reduces the temperature around the fire as the vapour in the inert gas evaporates during the time of spreading. Some important aspects of influencing parameters, such as, air excess coefficient. $\alpha$, compressor pressure ratio, $ pi_c$, air temperature before combustion chamber, $T_2$, gas temperature after combustion chamber, $T_3$, mass flow rate of water injection, $M_w$, etc., on the performance of IGG system are investigated. Calculations of total amount of water needed to reduce the turbine exit temperature to pre-set nozzle exit temperature employing a heat exchanger were made to compare the economics of the system. A heat exchanger with two step cooling by water and steam is considered to be better than water cooling only. Computer programs were developed to perform the cycle analysis of the IGG system and heat exchanger considered in the present study.

• 한국가스학회지
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• 제9권2호
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• pp.38-42
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• 2005

본 연구는 LP가스 용기용 밸브의 개발에 관한 것으로 안전밸브의 개념을 도입했다. LP가스 용기는 사용의 편리성 때문에 많이 이용되고 있지만 많은 사고가 발생되고 있다. 특히 자해나 남을 해할 목적으로 이용되기도 하며 때때로 시위도구로 사용되기도 한다. 정부에서는 이와같은 사고를 줄이기 위하여 과류밸브를 사용하도록 의무화하고 있지만 제품개발이 뒤따르지 못하고 있는 실정이다. 본 연구에서는 과류밸브보다 근원적 안전개념을 도입한 안전밸브의 개념을 소개한다. 이것은 기존의 밸브에 모듈을 삽입하는 방법으로 개발되었으며 밸브에 호스나 조정기가 연결되지 않은 상태에서는 가스의 흐름이 억제된다. 또한 정상 사용중이더라도 호스가 절단되거나 과류가 발생되면 즉시 가스의 흐름은 차단된다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 추계학술대회 논문집
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• pp.370-373
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• 2008

Small size gas turbine disk requires good mechanical strength and creep properties at high temperature. In this study, Waspaloy was used as a superalloy to satisfy these specifications. The control of microstructure was needed to satisfy material properties at high temperature. In order to do this, we studied forging conditions and material analysis. Therefore die and preform design conducted so that hot forged gas turbine disk could have a good microstructure. The die and preform shapes are designed with consideration of the predefined hydraulic press capacity and the microstructure of forging product. Also we carried out the hot compression test for Waspaloy in various test conditions. From these results, we obtained the forging conditions as material temperature, die velocity etc. To verify these forging conditions, we conducted FE simulations by means of the DEFORM 2D-HT. In this study, the hot closed die and preform designs were completed to offer high temperature material properties of a small size gas turbine.

• 한국정보전자통신기술학회논문지
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• 제6권3호
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• pp.156-161
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• 2013

가스 밸브 제어기는 사용자의 취급부주의에 의해 폭발, 화재 및 질식 등의 사고를 미연에 방지하고자 사용 시간을 설정하여 가스를 사용할 수 있는 시스템이다. 가스 밸브는 각 수용가에서 한 번 설치를 하면 특별한 사안이 없는 한 교체하지 않는 품목 중의 하나로서, 설치 이전에 충분한 시험이 필요한 장치이다. 본 연구에서는 가스 밸브 제어기를 사용 횟수를 설정하여 시험할 수 있는 시스템을 개발하였다.