• Corrosion Science and Technology
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• v.11 no.4
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• pp.141-150
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• 2012

Stress corrosion cracks in Alloy 600 compact tension specimens tested at $325^{\circ}C$ in a simulated primary water environment of pressurized water reactor were analyzed by analytical transmission electron microscopy and secondary ion mass spectroscopy (SIMS). From a fine-probe chemical analysis, oxygen was found on the grain boundary just ahead of the crack tip, and chromium oxides were precipitated on the crack tip and the grain boundary attacked by the oxygen diffusion, leaving a Cr/Fe depletion (or Ni enrichment) zone. The oxide layer inside the crack was revealed to consist of a double (inner and outer) layer. Chromium oxides existed in the inner layer, with NiO and (Ni,Cr) spinels in the outer layer. From the nano-SIMS analysis, oxygen was detected at the locations of intergranular chromium carbides ahead of the crack tip, which means that oxygen diffused into the grain boundary and oxidized the surfaces of the chromium carbides. The intergranular chromium carbide blunted the crack tip, thereby suppressing the crack propagation.

• Corrosion Science and Technology
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• v.19 no.3
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• pp.138-145
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• 2020

Immersion tests of Alloy 600 were conducted in simulated primary water environments of a pressurized water reactor at 325 ℃ for 10, 100, and 1000 h to obtain insight into effects of surface deformation on internal and intergranular (IG) oxidation behavior through precise characterization using various microscopic equipment. Oxidized samples after immersion tests were covered with polyhedral and filamentous oxides. It was found that oxides were abundant in mechanically ground (MG) samples the most. The number density of surface oxides increased with time irrespective of the method of surface finish. IG oxidation occurred in mechanically polished (MP) and chemically polished (CP) samples with thin internal oxidation layers. However, IG oxidation was suppressed with relatively thick internal oxidation layers in MG samples compared to MP and CP samples, suggesting that MG treatment could increase resistance to primary water stress corrosion cracking (PWSCC) from the standpoint of IG oxidation. As a result, appropriate surface treatment for Alloy 600 could prevent oxygen diffusion into grain boundaries, inhibit IG oxidation, and finally induce its high PWSCC resistance.

• Nuclear Engineering and Technology
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• v.49 no.4
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• pp.668-674
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• 2017

Experimental verification of boron species in fuel CRUD (Chalk River Unidentified Deposit) would provide essential and important information about the root cause of CRUD-induced power shifts (CIPS). To date, only bonaccordite and elemental boron were reported to exist in fuel CRUD in CIPS-troubled pressurized water reactor (PWR) cores and lithium tetraborate to exist in simulated PWR fuel CRUD from some autoclave tests. We have reevaluated previous analysis of similar threadlike crystals along with examining some similar threadlike crystals from CRUD samples collected from a PWR cycle that had no indications of CIPS. These threadlike crystals have a typical [Ni]/[Fe] atomic ratio of ~2 and similar crystal morphology as the one (bonaccordite) reported previously. In addition to electron diffraction study, we have applied electron energy loss spectroscopy to determine boron content in such a crystal and found a good agreement with that of bonaccordite. Surprisingly, such crystals seem to appear also on corroded surfaces of Alloy 600 that was exposed to simulated PWR primary water with a dissolved hydrogen level of $5mL\;H_2/kg\;H_2O$, but absent when exposed under $75mL\;H_2/kg\;H_2O$ condition. It remains to be verified as to what extent and in which chemical environment this phase would be formed in PWR primary systems.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.203-203
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• 2023

총일차생산량(GPP, Gross Primary Productivity)은 생태계의 유기물 생산량을 나타내는 지표로써 생태계 생산성과 안정성을 파악할 수 있는 중요한 지표로 알려져 있다. GPP를 산출하는 대표적인 방법에는 다중 센서를 탑재한 원격 탐사 자료를 활용하는 방법과 플럭스타워를 통해 관측한 에디공분산을 분석하는 방법이 있다. 본 연구에서는 Landsat과 MODIS와 같이 시공간 해상도가 다른 원격 탐사 자료들을 기반으로 초고해상도 GPP 자료를 산출하기 위한 공간자료 융합 연구를 수행하였다. 이를 위해 GAN(Generative Adversarial Networks)과 같은 머신러닝 알고리즘을 활용하였으며 최종적으로 산정된 GPP 정보는 설마천과 청미천 등에 설치된 플럭스타워로부터 획득한 자료와의 비교·검증을 통해 평가되었다. 본 연구의 성과는 향후 증발산 자료, 생태계 호흡량 자료 등과의 조합을 통해 얻을 수 있는 물이용효율(WUE, Water Use Efficiency), 탄소이용효율(CUE, Carbon Uptake Efficiency)과 같은 지표 산정 시 적극 활용될 수 있을 것으로 기대된다.

• Journal of the Korean Society of Propulsion Engineers
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• v.2 no.2
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• pp.83-87
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• 1998

To reduce the supersonic jet noise from the liquid rocket engine, water injetion silencers were designed and tested. Test variables were the mass flow rate of water jet, the length of primary pipe and the diameter of expansion pipe. Followings are the results of this study. 1. From the same mass flow rate of water, longer primary pipe was more effective to reduce the noise. 2. Noise level was significantly reduced with increasingly water flow rate. 3. The optimum water flow rate was 10～12 times of the propellant flow rate. 4. By installing expansion pipe, noise level was reduced approximately 30㏈ compared to without expansion pipe

• Korean Journal of Environmental Biology
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• v.24 no.3
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• pp.213-220
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• 2006

Present study aims to investigate the effect of muddy water on various tissues and plasma proteins of Hemiculter eigenmanni in Imha reservoir. The gills in muddy water were shown to have clubbing in secondary lamellae and edema in primary lamellae, respectively. The size of glomerula in kidney was smaller than that of control. Scanning electron micrographs of gills revealed muddy debris and parasites attached between primary and secondary lamellae, suggesting that muddy water possibly involves to decrease in respiratory rate. By using SDS-PAGE, plasma protein bands displayed both quantitative and qualitative changes and ferritin activities were shown more stronger and Fe-3 ferritin band appeared to be specific to plasma of muddy water.

• Resources Recycling
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• v.28 no.4
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• pp.51-58
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• 2019

Dismantlement of lithium primary batteries without explosion is required to recycle the lithium primary batteries which could be exploded by heating too much or crushing. In the present study, the optimum discharging condition was investigated to dismantle the batteries without explosion. When the batteries were discharged with $0.5kmol{\cdot}m^{-3}$ sulfuric acid, the reactivity of the batteries decreased after 4 days at $35^{\circ}C$ and after 1 day at $50^{\circ}C$, respectively. This result shows that higher temperature removed the high reactivity of the batteries. Because loss of metals recycled increases when the batteries are discharged only with the sulfuric acid, discharging process using acid solution and water was newly proposed. When the batteries were discharged with water during 24 hours after discharging with $0.5kmol{\cdot}m^{-3}$ sulfuric acid during 6 hours, the batteries discharged were dismantled without explosion. Because decrease in loss of metals was accomplished by new process, the recycling process of the batteries could become economic by the 2-step discharging process.

• Journal of the Korean Society of Safety
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• v.20 no.3 s.71
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• pp.105-111
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• 2005

An experimental study is performed for extinguishing of n-heptane pool fire by water mist containing potassium acetate as a fire suppression additive. Water mist was generated by a single pressure nozzle in a small-scale chamber. The drop size distribution of water mist was measured using laser diffraction(Malvern particle sizer). The flame temperature, oxygen concentration and carbon monoxide concentration were measured. In case of using additives, the fire extinguishing time was shorter than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing additives was increased. And also dissociated metal atoms, potassium, were reacted as a scavenger of the major radical species OH, H which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

• Korean Journal of Environmental Biology
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• v.26 no.2
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• pp.76-86
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• 2008

The seasonal variations of primary production were investigated by phyto-PAM chlorophyll fluorometry as well as classical methods (standing crops of phytoplanktons and chlorophyll ${\alpha}$) in the Beopsu Marsh, Haman-gun, Gyeongsangnam-do. The amounts of turbidity, SS, T-N, T-P, BOD, COD, Ca$^{2+}$ and Cl$^-$ were the highest at the station 3, where located in flowout site of wastewater treated by the filtration plants. The water quality was the third level by the standard of BOD and COD. The amount of chlorophyll a (268.8 mg L$^{-1}$) was the highest at the station 2 in April because the cell density (2,677 cells mL$^{-1}$) of Micractinium pusillum increased suddenly from February (180 cells mL$^{-1}$). The patterns of primary production of phytoplankton by phyto-PAM chlorophyll fluorometry were fallen in with those of standing crops and chlorophyll a of phyto-planktons. The primary production was varied according to stations and seasons. The water environments of the Beopsu Marsh as a natural mounument should be under the control of a regular examination in order to preserve the ecosystem.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.18 no.2
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• pp.65-69
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• 2013

In situ measurement of a primary production in East Sea, a marginal sea with a fair accessibility, is nonetheless an arduous task because of dynamic variability. In this study, we estimated the mean value of background (gross) primary production over the warm region of the East Sea based on a biogeochemical hypothesis. We propose an immiscible-shoaling hypothesis for the estimation of primary production, which assumes that primary production in the warm region occurred only by the nutrient supply through the Korea Strait. Annual primary production thus estimated is $209\;gC\;m^{-2}\;y^{-1}$, which is comparable to the satellite-based estimates of net primary production in the region. However, since this hypothesis assumes that primary production is based on only the new nutrients supplied to the system, primary production would increase by 40% if we release the assumption, and assume f = 0.6. This suggests that nutrient influx through the Korea Strait alone is more than enough to support primary production previously reported. Primary production may increase as much as two times if we considered other external perturbations excluded intentionally to estimate the background level of primary production, such as coastal upwelling, submerged ground water discharge, aeolian input, ocean dumping, and mixing by typhoons as well as the contribution of cyanobacteria that has not been quantified in the region. This implies the primary production in the warm region of the East Sea would be comparable to that of the Peru upwelling region with f = 0.6.