• Title/Summary/Keyword: primary phase

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Influence of Minor Element on Microstructure and Mechanical Properties of TiFe Ultrafine Eutectic Alloys (TiFe 공정합금의 미소합금 첨가에 따른 미세구조 변화 및 기계적 물성)

  • Lee, Chan Ho;Jo, Jae Hyuk;Mun, Sang Chul;Kim, Jung Tae;Yeo, Eun Jin;Kim, Ki Buem
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.615-619
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    • 2012
  • Recently, ultrafine grained (ufg, typically 100 > d > 500 nm) Ti-Fe eutectic materials have been highlighted due to their extraordinarily high strength and good abrasion resistance compared to conventional coarse grained (cg, d > $1{\mu}m$) materials. However, these materials exhibit limited plastic strain and toughness during room temperature deformation due to highly localized shear strain. Several approaches have been extensively studied to overcome such drawbacks, such as the addition of minor elements (Sn, Nb, Co, etc.). In this paper, we have investigated the influence of the addition of Gd and Y contents (0.3-1.0 at.%) into the binary Ti-Fe eutectic alloy. Gd and Y are chosen due to their immiscibility with Ti. Microstructural investigation reveals that the Gd phase forms in the eutectic matrix and the Gd phase size increases with increasing Gd content. The improvement of the mechanical properties is possibly correlated to the precipitation hardening. On the other hand, in the case of Ti-Fe-Y alloys, with increasing Y contents, primary phases form and lamellar spacing increases compared to the case of the eutectic alloy. Investigation of the mechanical properties reveals that the plasticity of the Ti-Fe-Y alloys is gradually improved, without a reduction of strength. These results suggest that the enhancement of the mechanical properties is closely related to the formation of the primary phase.

Mechanical Properties and Castabilities of Al-12Mg-5.5Zn-xSi Alloys

  • Kim, Jeong-Min;Sung, Ki-Dug;Jun, Joong-Hwan;Kim, Ki-Tae;Jung, Woon-Jae
    • Journal of Korea Foundry Society
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    • v.24 no.6
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    • pp.340-346
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    • 2004
  • The plan for obtaining a good combination of strength and castability appeared feasible and the following observations were made. 1. In Al-12Mg-6.6Zn-xSi alloys, more primary $Mg_2Si$ phase formed with reduced $Al_3Mg_2$ phase, as Si content is necessary for an effective solution heat treatment because the solidus temperature is very low silicon contents. 2. A high tensile strength could be obtained in the heat-treated Al-12Mg-5.5Zn-5Si alloy attributed in the heat-treated Al-12Mg-5.5Zn-5Si alloy attributes to fine $MgZn_2$ particles that precipitated uniformly in the matrix. 3. Al-12Mg-5.5Zn-Si alloys showed excellent casting capabilities such as hot cracking resistance and fluidity compared to the reference commercial alloys. 4. The wear resistance of Al-12Mg-5.5Zn-5Si alloy was superior to that of A7075 alloy, and even higher resistance is expected if the morphology and size of primary $Mg_2Si$ phase is carefully controlled.

Induction of Differentiation of the Cultured Rat Mammary Epithelial Cells by Triterpene Acids

  • Paik, Kee-Joo;Jeon, Seong-Sill;Chung, Hae-Young;Lee, Kyung-Hee;Kim, Kyu-Won;Chung, Joon-Ki;Kim, Nam-Deuk
    • Archives of Pharmacal Research
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    • v.21 no.4
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    • pp.398-405
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    • 1998
  • We investigated the effects of triterpene acids (TAs), ursolic acid (UA) and oleanolic acid (OA), on the induction of proliferation and differentiation of normal rat mammary epithelial cells (RMEC) or organoids cultured in Matrigel or primary culture system. To elucidate the effects, we tested their differentiation inducing activities with intercellular communication ability, cell cycle patterns, induction of apoptosis, and morphological differentiation in the three dimensional extracellular culture system. To study the changes of RMEC subpopulation in culture, the cultured cells were isolated, immunostained with peanut lectin (PNA) and anti-Thy-1.1 antibody and then analyzed with flow cytometry. Four different subpopulations, such as PNA and Thy-1.1 negative cells (B-), PNA positive cells (PNA+), Thy-1.1 positive cells (Thy-1.1+), PNA and Thy-1.1 positive cells (B+), were obtained and the size of each subpopulation was changed in culture with time in the presence of TAs. Intercellular communication was observed in culture for 7 days in TAs-treated cells, but not in culture for 4 days with scrape-loading dye transfer technique. $G_2$/M phase cells and the number of apoptotic population were increased in TAs-treated groups in cell cycle analyses. S phase fractions were reduced and the change of $G_1$ phase cells was not observed. The colonies with distinct multicelfular structures, such as stellate, ductal, webbed, squamous, lobulo-ductal colonies, were observed in Matrigel culture and the frequencies of each colony were changed in the presence of TAs. These results suggest that UA and OA have differentiation inducing effects on rat mammary epithelial cells in primary or in Matrigel culture.

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Cause Analysis and Development of Root Cause Analysis Map using Data of Chemical Laboratory Accidents (화학실험실 사고 Data를 이용한 근본원인분석 Map 개발 및 원인 분석)

  • Lee, Su-Kyung;Yoon, Yeo-Song;Eom, Seok Hwa
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.86-94
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    • 2014
  • To develop a Root Cause Analysis Map which determines the cause of the accident in chemical laboratory, The Root Cause Analysis(RCA) Map for the laboratory areas was sketched from Phase 1 of the accident element to Phase 3 of the accident element, based on the RCA Map which is applied in the petrochemical industry. On the basis of laboratory RCA Map which was classified by using such method. The root causes of the 211 accident cases in laboratories were classified from Phase 4 to Phase 5 by the Cause Factor Charting technique and The cause of the accident data were inputted to EXCEL program. After that, The causes of the accident data were sorted and classified by type and each step. So 'Approximate Primary RCA Map Draft' was written. In addition, it was reaffirmed whether the root causes of 211 accidents of laboratory were appropriate to 'Primary RCA Map Draft'. By complementing the cause which was expected to cause future accidents, the RCA Map for chemical laboratories was developed. Based on 'RCA Map' proposed in this study, the causes of accidents were analysed management systems 35%, monitoring 12.2%, Human Factor Eng. 15.1% and education training 12.1% by the size of the frequency from Phase 1 to Phase 5.

Numerical Study on the Inlet Head Configuration of Multi-Phase Separator for Modularization (다상유동 분리기 모듈화를 위한 유입구 형상 설계에 관한 수치해석적 연구)

  • Hong, Chang-Ki;Kim, Youn-Jea
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.9
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    • pp.571-577
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    • 2017
  • In this numerical study, the separation efficiency of three-phase separator in an oil-sand plant was studied with various inlet head configurations. The free water knockout (FWKO) vessel was designed with a flow rate of $15.89m^3/day$ (100 bbl/day) and the SOR(stream-to-oil ratio)=3.5 was derived using Stokes' law. For modularization, optimization of the design of the inlet head configuration was performed with parallel-connected dual FWKO vessels. The feed condition of bitumen emulsion was API=17, $T_{in}=150^{\circ}C$ and $P_{in}=50bar$. A mean residence time was determined the time when 95% of the oil and water in FWKO vessel was separated. The combination between the volume of fluid (VOF) and the discrete phase model (DPM) was used to simulate the phase separation phenomenon in a multi-phase separator. Furthermore, in order to calculate multi-phase flow the pseudo-transient method was adopted.

Performance Analysis of Opportunistic Spectrum Access Protocol for Multi-Channel Cognitive Radio Networks

  • Kim, Kyung Jae;Kwak, Kyung Sup;Choi, Bong Dae
    • Journal of Communications and Networks
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    • v.15 no.1
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    • pp.77-86
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    • 2013
  • Cognitive radio (CR) has emerged as one of effective methods to enhance the utilization of existing radio spectrum. Main principle of CR is that secondary users (SUs) are allowed to use the spectrum unused by primary users (PUs) without interfering PU's transmissions. In this paper, PUs operate on a slot-by-slot basis and SUs try to exploit the slots unused by PUs. We propose OSA protocols in the single channel and we propose an opportunistic spectrum access (OSA) protocols in the multi-channel cognitive radio networks with one control channel and several licensed channels where a slot is divided into contention phase and transmission phase. A slot is divided into reporting phase, contention phase and transmission phase. The reporting phase plays a role of finding idle channels unused by PUs and the contention phase plays a role of selecting a SU who will send packets in the data transmission phase. One SU is selected by carrier sense multiple access / collision avoidance (CSMA/CA) with request to send / clear to send (RTS/CTS) mechanism on control channel and the SU is allowed to occupy all remaining part of all idle channels during the current slot. For mathematical analysis, first we deal with the single-channel case and we model the proposed OSA media access control (MAC) protocol by three-dimensional discrete time Markov chain (DTMC) whose one-step transition probability matrix has a special structure so as to apply the censored Markov chain method to obtain the steady state distribution.We obtain the throughput and the distribution of access delay. Next we deal with the multi-channel case and obtain the throughput and the distribution of access delay by using results of single-channel case. In numerical results, our mathematical analysis is verified by simulations and we give numerical results on throughput and access delay of the proposed MAC protocol. Finally, we find the maximum allowable number of SUs satisfying the requirements on throughput and access delay.

Modeling the Catalytic Activity and Kinetics of Lipase(Glycerol-Ester Hydrolase)

  • Demirer, Goksel N.;Duran, Metin;Tanner, Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.1 no.1
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    • pp.46-50
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    • 1996
  • In order to design industrial scale reactors and proceises for multi-phase biocatalytic reactions, it is essential to understand the mechanisms by which such systems operate. To il-lustrate how such mechanisms can be modeled, the hydrolysis of the primary ester groups of triglycerides to produce fatty acids and monoglycerides by lipased (glycerol-ester hydrolase) catalysis has been selected as an example of multiphase biocatalysis. Lipase is specific in its behavior such that it can act only on the hydrolyzed (or emulsified) part of the substrate. This follows because the active center of the enzyme is catalytically active only when the substrate contacts it in its hydrolyzed form. In other words, lipase acts only when it can shuttleback and forth between the emulsion phase and the water phase, presumably within an interphase or boundary layer between these two phases. In industrial applications lipase is employed as a fat splitting enzyme to remove fat stains from fabrics, in making cheese, to flavor milk products, and to degrade fats in waste products. Effective use of lipase in these processes requires a fundamental understanding of its kinetic behavior and interactions with substrates under various environmental conditions. Therefore, this study focuses on modeling and simulating the enzymatic activity of the lipase as a step towards the basic understanding of multi-phase biocatalysis processes.

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ZVS Operating Range Extension Method for High-Efficient High Frequency Linked ZVS-PWM DC-DC Power Converter

  • Sato S.;Moisseev S.;Nakaoka M.
    • Proceedings of the KIPE Conference
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    • 2003.07a
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    • pp.227-230
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    • 2003
  • In this paper, a full bridge edge-resonant zero voltage mode based soft-switching PWM DC-DC power converter with a high frequency center tapped transformer link stage is presented from a practical point of view. The power MOSFETS operating as synchronous rectifier devices are implemented in the rectifier center tapped stage to reduce conduction power losses and also to extend the transformer primary side power MOSFETS ZVS commutation area from the rated to zero-load without a requirement of a magnetizing current. The steady-state operation of this phase-shift PWM controlled power converter is described in comparison with a conventional ZVS phase-shift PWM DC-DC converter using the diodes rectifier. Moreover, the experimental results of the switching power losses analysis are evaluated and discussed in this paper. The practical effectiveness of the ZVS phase-shift PWM DC-DC power converter treated here is actually proved by using 2.5kW-32kHz breadboard circuit. An actual efficiency of this converter is estimated in experiment and is achieved as 97$\%$ at maximum.

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Diagnosis of Fault and Abnormal Conditions in a Single-Phase Transformer Using S-parameter Measurement (S파라미터를 이용한 단상 변압기의 이상 상태 진단에 대한 연구)

  • Kim, Jeongeun;Kim, Kwangho;Nah, Wansoo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.10
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    • pp.1344-1352
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    • 2018
  • In this paper, we propose a two-port S-parameter data to diagnose the fault conditions of a single-phase transformer. Using the S-parameters we can measure the reflection and transmission characteristics of signal power at the port of a transformer, which can also be converted into ABCD parameters and Z parameters through a well-known conversion formulas. Transformer fault diagnoses can be performed based on the intuitive and qualitative/quantitative characteristics of the these parameters. In addition, we can obtain wide frequency characteristics at the primary and secondary sides of the transformer, which can be used to get time domain responses using the inverse Fourier transformation with some specific input waveform. In order to verify the effectiveness of the proposed method, the fault conditions were analyzed in simulation and experiment for 3 kVA single phase transformer with 15: 5 turns ratio, and the validity of the proposed method was verified.

Series Active Power Filters to Compensate Harmonics and Reactive Power with the Direct Compensating Voltage Extraction Method in Three-Phase Four-Wire Systems

  • Kim, Jin-Sun;Kim, Young-Seok
    • Journal of Power Electronics
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    • v.9 no.5
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    • pp.691-699
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    • 2009
  • This paper presents the analysis of series active power filter for reactive power compensation, load balancing, harmonic elimination, and neutral current eradication in three-phase four-wire power systems. Generally, the three-phase four-wire system is widely employed in distributing electric energy to several office building and manufacturing plants. In such systems, the third harmonic and its 3rd harmonics are termed as triple and zero sequence components that do not cancel each other in the system neutral. Consequently, the triple harmonics add together creating a primary source of excessive neutral current. Regarding this concern, this paper presents a new control algorithm for a series hybrid active system, whereas the control approach it adopts directly influence its compensation characteristics. Hence, the advantage of this control algorithm is the direct extraction of compensation voltage reference without phase transformations and multiplying harmonic current value by gain and the required rating of the series active filter is much smaller than that of a conventional shunt active power filter. In order to show the effectiveness of the proposed control algorithm, experiments have been carried out.