• 제목/요약/키워드: primary phase

검색결과 1,058건 처리시간 0.034초

유기 및 무기음이온에 대한 이온쌍크로마토그래피 (Ion-Pair Chromatography of Organic and Inorganic Anions)

  • 강삼우
    • 대한화학회지
    • /
    • 제29권4호
    • /
    • pp.365-371
    • /
    • 1985
  • 이온쌍크로마토그래피에 의한 유기 및 무기음이온을 분리하는데 반대이온으로서 양이온 염료인 메틸렌 부루$(MTB^+)$를 사용하여 흡수가 되지 않는 음이온 시료를 간접적으로 분광광도 검출기로서 가시영역인 665nm에서 검출할 수 있었으며 혼합시료의 분리를 시도한 결과 좋은 분리도와 높은 감도를 보여주었다. 또한 여러 실험조건에서 분리인자를 측정하여 머무름 기구를 조사하였다. 본 연구에서 머무름 기구는 $MTB^+$가 고정상에 일차층(primary layer)을 형성하고 반면 음이온 시료 또는 이동상에 존재하는 다른 음이온들이 경쟁적으로 이차층(secondary layer)을 형성하는 ion-interaction model임을 확인하였다.

  • PDF

전기자동차의 배터리 하이브리드 전원시스템용 고효율 컨버터 (A High Efficiency Converter for Battery Hybrid Power System of Electric Vehicles)

  • 트란다이두옹;이현화;최우진
    • 전력전자학회:학술대회논문집
    • /
    • 전력전자학회 2016년도 전력전자학술대회 논문집
    • /
    • pp.333-334
    • /
    • 2016
  • This paper proposes a new cascoded configuration for hybrid energy storage system (HESS) which consists of batteries and supercapacitor (SC) for Electric Vehicle applications. In this configuration,a resonant LLC converter is interfacedin series with a battery module and it converts a part of the energy from the batteries and transfer it to the dc-link bus. The LLC converter is controlled by a phase-shift angle between the primary and secondary switches to maintain a constant dc-link voltage and obtain soft-switching conditions for all the primary switches. By placing the SC moduleina cascoded concept, the rated voltage of SC can be reduced significantly compared with the conventional topologies. It helps save the cost and reduce the number of SC cells. The proposed configuration can operate with four different modes: feeding load, acceleration, regenerative braking andSC charging. A scaled-down prototype converter (2 kW, 600V output) is designed and tested to verify the advantages of the proposed topology. The maximum efficiency obtained with the proposed topology is 99%.

  • PDF

삼상 분리형 자속커플링 전류제한기의 턴 수의 따른 전류제한 특성 (Characteristics according to turn ratio of Separated Three-Phase Flux-Coupling Type Superconducting Fault Current Limiter(SFCL))

  • 김용진;두호익;두승규;김민주;이동혁;한병성
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
    • /
    • pp.344-345
    • /
    • 2009
  • The flux-coupling type superconducting fault current limiter(SFCL) is composed of a series transformer and superconducting unit of the YBCO coated conductor. The primary and secondary coils in the transformer were wound in series each other through an iron core and the YBCO coated conductor was connected with secondary coil in parallel. In a normal condition, the flux generated from a primary coil is cancelled out by its structure and the zero resistance of the YBCO thin films. When a fault occurs, the resistance of the YBCO coated conductor was generated and the fault current was limited by the SFCL. In this paper, we investigated the fault current limiting characteristics according to turn ratio in the flux-coupling type SFCL. The experiment results that the fault current limiting characteristics was improved according to turn ratio.

  • PDF

$L1_{2}-Ni_{3}Al$ 금속간화합물의 강도특성에 관한 연구 (A Study on the Strength Characteristics of $L1_{2}-Ni_{3}Al$ Intermetallic Compound)

  • 한창석;천창환;한승오
    • 열처리공학회지
    • /
    • 제22권1호
    • /
    • pp.8-15
    • /
    • 2009
  • Structural studies have been performed on precipitation hardening found in $Ni_{3}Al$ based ordered alloys using transmission electron microscopy (TEM). Tilt experiments by the weak-beam method were made to obtain some information concerning the cross slip mechanism of the superlattice dislocation. The strength of ${\gamma}'-Ni_3$(Al,Ti) increases over the temperature range of experiment by the precipitation of fine $\gamma$ particles. The peak temperature where a maximum strength was obtained shifted to higher temperature. Over the whole temperature range, the interaction between dislocation and $\gamma$ precipitates is attractive. On the temperature range of 773 K to 973 K, the dislocations in ${\gamma}'$ matrix move on (111) primary slip plane. When the applied stress is removed, the dislocations make cross slip into (010) plane, while those in $\gamma$ precipitates remain on the (111) primary slip plane. The increase of high temperature strength in ${\gamma}'-Ni_3$(Al,Ti) containing $\gamma$ precipitates is due to the restraint of cross slip of dislocations from (111) to (010) by the dispersion of disordered $\gamma$ particles.

고관절 이상으로 오인된 일차성 요근 농양 1례 (Primary psoas abscess confused with hip pathology)

  • 김영옥;우영종
    • Clinical and Experimental Pediatrics
    • /
    • 제49권5호
    • /
    • pp.570-573
    • /
    • 2006
  • 대요근은 12번 흉추의 외연면에서 5번 요추까지의 외연면에 걸쳐 기시하여 대퇴골의 소전자에 부착되는 근육으로 고관절의 굴곡에 관여한다. 이는 후복막 기관으로 여러 혈관에서 풍부한 혈류 공급을 받으며, S자 결장, 공장, 충수 돌기, 요관, 대동맥, 신장, 췌장, 척추, 림프선 등 여러 장기와 인접하고 있어 감염의 호발 부위가 된다. 그러나, 요근 농양 발생시, 그 증상이 비특이적이고 건강한 소아에서 드물게 발병하는 이유로 고관절 질환으로 혼돈되기도 하여, 진단과 치료가 지연되는 예가 많다. 저자들은 평소 건강하던 14세 남아가 침대에서 떨어져 경한 우측 둔부 좌상을 입은 이후, 우측 둔부 통증과 발열 및 보행 불능을 호소하여 고관절 이상을 의심해 시행한 자기 공명 영상에서 우연히 우측 요근내 농양을 발견해 항생제 치료를 시행하였던 증례를 경험하였기에 보고하는 바이다.

가물치(Channa argus)로부터 평활근 수축활성 펩타이드의 정제 (Isolation of a Novel Neuropeptide with Contractile Activity on the Smooth Muscle from the Snakehead Channa argus)

  • 고혜진;박남규
    • 한국수산과학회지
    • /
    • 제45권2호
    • /
    • pp.114-121
    • /
    • 2012
  • A novel neuropeptide was isolated from the skin of the snakehead Channa argus using the dorsal retractor muscle (DRM) of a starfish Asterina pectinifera as a bioassay system. The amino acid sequence of the purified peptide was analyzed using automated sequencing and MALDI-TOF mass spectrophotometry. The primary structure of the purified peptide was determined to be Pro-Ala-Leu-Ala-Leu. To investigate the complete primary structure of this peptide, Pro- Ala-Leu-Ala-Leu-OH and Pro-Ala-Leu-Ala-Leu-NH2 were synthesized. The chemical and pharmacological properties of the synthetic peptides were compared with those of the native peptide. Both the native peptide and synthetic Pro-Ala- Leu-Ala-Leu-OH had identical behaviors on the reverse-phase and cation-exchange HPLC chromatograms. Synthetic Pro-Ala-Leu-Ala-Leu-OH showed contractile activity on the DRM, and the threshold concentration of this peptide was approximately $10^{-8}$ M. The maximal contractile effect ($E_{max}$) of this peptide was $294{\pm}45.4$% at $10^{-5}$ M.

릴레이를 이용한 차량용 배터리의 가변 충전기 (Variable Charger of Vehicle using Relay)

  • 송성근;정승태;강성구;이상훈
    • 조명전기설비학회논문지
    • /
    • 제26권9호
    • /
    • pp.47-56
    • /
    • 2012
  • This research is to develop satiable battery charger with a variety of capacity and voltage specifications of battery. For this, voltage or current were controlled through buck converter which is DC voltage that already received three-phase at primary side and passed bridge rectifier diode. And, it was comprised of full-bridge converter and HFTR for insulation and a square wave AC. The transformer primary side was comprised in series to divide certain charging current and the secondly side was comprised of 6 fixed transformers so that they can generate certain amount of power and various output voltage through relay parallel compound 6 DC Link outputs. To confirm such structure's verification and validity, simulation with PSIM was conducted, and validity of proposed variable charger system was verified through 3kW stack production.

플라스마 아크 紛體肉盛法에 의한 Al 合金의 硬化厚膜 合金化層의 形成 (Formation of Thicker hard Alloy Layer on Aluminum Alloy by PTA Overlaying with Metal Powders)

  • 박성두;이영호
    • Journal of Welding and Joining
    • /
    • 제11권2호
    • /
    • pp.74-85
    • /
    • 1993
  • Effect of Si metal powders addition with the plasma transferred arc(PTA) overlaying process on characteristics of the alloyed layer in aluminum alloy(A5083) has been investigated. The overlaying conditions were 175-250A in plasma arc current, 500mm/min in travel speed, the 5-20g/min in powder feeding rate. Main results obtained are summarized as follows. 1)Sufficient size of molten pool on surface of base metal was required for forming an alloyed layer; in a fixed travel, the formation of alloyed layer with clear and beautiful surface depend upon the plasma arc current and powder feeding rate; the greater plasma arc current and the smaller powder feeding rate were, the better bead was formed. Optimum alloyed conditions by which an excellent alloyed bead obtained was 225A in plasma arc current. PTA process made it possible to form an alloyed layer with up to 67wt% Si. 2)Microstructure in the alloyed layer was in accord with prediction from the Al-Si phase diagram 3)The hardness of the alloyed layer increased in proportion to Si content. 4)As volume fraction of primary Si increased, the specific wearness of the alloyed layer was significantly improved. However, no further improvement was found when the volume fraction was greater than about 30%. 5)Utilizing the PTA process, a crack free alloyed layer with maximum hardness of about Hv 310 could be obtained.

  • PDF

Fe-Cr-Ni강 용접금속부의 미세편석에 관한 해석 (Analysis of Microsegregation in Fe-Cr-Ni Weld Metal)

  • 박준민;박종민;안상곤;이창희;윤의박
    • Journal of Welding and Joining
    • /
    • 제16권5호
    • /
    • pp.56-66
    • /
    • 1998
  • During solidification or welding of alloys, the solute redistribution brings out microsegregation. The microsegregation causes the formation of non-equilibrium second phases, shrinkage and porosity degrading mechanical/chemical properties Therefore, it has been required to predict microsegregation quantitatively. To predict the degree of microsegregation, more exact and appropriate computer simulation technique has been actively used during last two decades. To predict the degree of microsegregation in weld metal, an advanced two dimensional model was suggested. In the new model, both primary and secondary arm regions were defined for the analysis region. The growth in the primary arm regina was assumed to be a planar for effective calculation. Especially, for the growth of a secondary arm, a simple and effective mathematical function was established to show the growing pattern, the solute diffusion in the solid phase was calculated by finite difference method (FDM). The solid-liquid interface movement was considered to be in local equilibrium state. The experiments for welding of 310S stainless steel were carried out in order to examined the reasonability and feasibility of this model. The concentration profiles of the solute predicted by this model were compared with those obtained from experimental works.

  • PDF

Transmission Electron Microscopy Characterization of Early Pre-Transition Oxides Formed on ZIRLOTM

  • Bae, Hoyeon;Kim, Taeho;Kim, Ji Hyun;Bahn, Chi Bum
    • Corrosion Science and Technology
    • /
    • 제14권6호
    • /
    • pp.301-312
    • /
    • 2015
  • Corrosion of zirconium fuel cladding is known to limit the lifetime and reloading cycles of fuel in nuclear reactors. Oxide layers formed on ZIRLO4^{TM}$ cladding samples, after immersion for 300-hour and 50-day in a simulated primary water chemistry condition ($360^{\circ}C$ and 20 MPa), were analyzed by using the scanning transmission electron microscopy (STEM), in-situ transmission electron microscopy (in-situ TEM) with the focused ion beam (FIB) technique, and X-ray diffraction (XRD). Both samples (immersion for 300 hours and 50 days) revealed the presence of the ZrO sub-oxide phase at the metal/oxide interface and columnar grains developed perpendicularly to the metal/oxide interface. Voids and micro-cracks were also detected near the water/oxide interface, while relatively large lateral cracks were found just above the less advanced metal/oxide interface. Equiaxed grains were mainly observed near the water/oxide interface.