• Title/Summary/Keyword: primary phase

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Ion-Pair Chromatography of Organic and Inorganic Anions (유기 및 무기음이온에 대한 이온쌍크로마토그래피)

  • Sam Woo Kang
    • Journal of the Korean Chemical Society
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    • v.29 no.4
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    • pp.365-371
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    • 1985
  • A cationic dye, methylene blue $(MTB^+)$ was examined as a counter ion in the separation of organic and inorganic anions by ion-pair chromatography. Nonabsorbing anions could be indirectly detected by photometric detector with the assistance of MTB^+ in visible range (665nm). A mixture of anions was able to be separated with good base line resolution and high sensitivity. The capacity factors were also determined in various experimental conditions to study retention mechanism. The retention followed the ion-interaction model where the $MTB^+$ occupies a primary layer at the stationary phase while the analyte anion and other anions in the system compete for forming the secondary layer.

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A High Efficiency Converter for Battery Hybrid Power System of Electric Vehicles (전기자동차의 배터리 하이브리드 전원시스템용 고효율 컨버터)

  • Tran, Dai-Duong;Lee, Hyun-Hwa;Choi, Woojin
    • Proceedings of the KIPE Conference
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    • 2016.07a
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    • pp.333-334
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    • 2016
  • This paper proposes a new cascoded configuration for hybrid energy storage system (HESS) which consists of batteries and supercapacitor (SC) for Electric Vehicle applications. In this configuration,a resonant LLC converter is interfacedin series with a battery module and it converts a part of the energy from the batteries and transfer it to the dc-link bus. The LLC converter is controlled by a phase-shift angle between the primary and secondary switches to maintain a constant dc-link voltage and obtain soft-switching conditions for all the primary switches. By placing the SC moduleina cascoded concept, the rated voltage of SC can be reduced significantly compared with the conventional topologies. It helps save the cost and reduce the number of SC cells. The proposed configuration can operate with four different modes: feeding load, acceleration, regenerative braking andSC charging. A scaled-down prototype converter (2 kW, 600V output) is designed and tested to verify the advantages of the proposed topology. The maximum efficiency obtained with the proposed topology is 99%.

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Characteristics according to turn ratio of Separated Three-Phase Flux-Coupling Type Superconducting Fault Current Limiter(SFCL) (삼상 분리형 자속커플링 전류제한기의 턴 수의 따른 전류제한 특성)

  • Kim, Yong-Jin;Du, Ho-Ik;Du, Seung-Gyu;Kim, Min-Ju;Lee, Dong-Hyeok;Han, Byoung-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.344-345
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    • 2009
  • The flux-coupling type superconducting fault current limiter(SFCL) is composed of a series transformer and superconducting unit of the YBCO coated conductor. The primary and secondary coils in the transformer were wound in series each other through an iron core and the YBCO coated conductor was connected with secondary coil in parallel. In a normal condition, the flux generated from a primary coil is cancelled out by its structure and the zero resistance of the YBCO thin films. When a fault occurs, the resistance of the YBCO coated conductor was generated and the fault current was limited by the SFCL. In this paper, we investigated the fault current limiting characteristics according to turn ratio in the flux-coupling type SFCL. The experiment results that the fault current limiting characteristics was improved according to turn ratio.

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A Study on the Strength Characteristics of $L1_{2}-Ni_{3}Al$ Intermetallic Compound ($L1_{2}-Ni_{3}Al$ 금속간화합물의 강도특성에 관한 연구)

  • Han, Chang-Suk;Chun, Chang-Hwan;Han, Seung-Oh
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.1
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    • pp.8-15
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    • 2009
  • Structural studies have been performed on precipitation hardening found in $Ni_{3}Al$ based ordered alloys using transmission electron microscopy (TEM). Tilt experiments by the weak-beam method were made to obtain some information concerning the cross slip mechanism of the superlattice dislocation. The strength of ${\gamma}'-Ni_3$(Al,Ti) increases over the temperature range of experiment by the precipitation of fine $\gamma$ particles. The peak temperature where a maximum strength was obtained shifted to higher temperature. Over the whole temperature range, the interaction between dislocation and $\gamma$ precipitates is attractive. On the temperature range of 773 K to 973 K, the dislocations in ${\gamma}'$ matrix move on (111) primary slip plane. When the applied stress is removed, the dislocations make cross slip into (010) plane, while those in $\gamma$ precipitates remain on the (111) primary slip plane. The increase of high temperature strength in ${\gamma}'-Ni_3$(Al,Ti) containing $\gamma$ precipitates is due to the restraint of cross slip of dislocations from (111) to (010) by the dispersion of disordered $\gamma$ particles.

Primary psoas abscess confused with hip pathology (고관절 이상으로 오인된 일차성 요근 농양 1례)

  • Kim, Young Ok;Woo, Young Jong
    • Clinical and Experimental Pediatrics
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    • v.49 no.5
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    • pp.570-573
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    • 2006
  • A healthy, 14-year-old boy presented with right hip pain and consequent fever after falling out of bed while sleeping. The patient could not walk and complained of severe pain with active and passive motion, which consisted mainly in extension and internal rotation of the right hip. Laboratory analysis of the peripheral blood identified leukocytosis and increased levels of acute phase reactants. Magnetic resonance imaging of the hip, which was performed with the expectation of right hip pathology, revealed cellulitis and abscess in the right psoas muscle and associated inflammatory changes in the adjacent presacral fat plane but showed no abnormal lesions in the adjacent pelvic bone and spine. Staphylococcus hominis was cultured from the blood. With empirical antibiotic therapy, the patient recovered fully. We report a case of primary psoas abscess confused with hip pathology in an immunocompetent child without underlying disease.

Isolation of a Novel Neuropeptide with Contractile Activity on the Smooth Muscle from the Snakehead Channa argus (가물치(Channa argus)로부터 평활근 수축활성 펩타이드의 정제)

  • Go, Hye-Jin;Park, Nam-Gyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.45 no.2
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    • pp.114-121
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    • 2012
  • A novel neuropeptide was isolated from the skin of the snakehead Channa argus using the dorsal retractor muscle (DRM) of a starfish Asterina pectinifera as a bioassay system. The amino acid sequence of the purified peptide was analyzed using automated sequencing and MALDI-TOF mass spectrophotometry. The primary structure of the purified peptide was determined to be Pro-Ala-Leu-Ala-Leu. To investigate the complete primary structure of this peptide, Pro- Ala-Leu-Ala-Leu-OH and Pro-Ala-Leu-Ala-Leu-NH2 were synthesized. The chemical and pharmacological properties of the synthetic peptides were compared with those of the native peptide. Both the native peptide and synthetic Pro-Ala- Leu-Ala-Leu-OH had identical behaviors on the reverse-phase and cation-exchange HPLC chromatograms. Synthetic Pro-Ala-Leu-Ala-Leu-OH showed contractile activity on the DRM, and the threshold concentration of this peptide was approximately $10^{-8}$ M. The maximal contractile effect ($E_{max}$) of this peptide was $294{\pm}45.4$% at $10^{-5}$ M.

Variable Charger of Vehicle using Relay (릴레이를 이용한 차량용 배터리의 가변 충전기)

  • Song, Sung-Geun;Chung, Seung-Tae;Kang, Sung-Gu;Lee, Sang-Hun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.9
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    • pp.47-56
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    • 2012
  • This research is to develop satiable battery charger with a variety of capacity and voltage specifications of battery. For this, voltage or current were controlled through buck converter which is DC voltage that already received three-phase at primary side and passed bridge rectifier diode. And, it was comprised of full-bridge converter and HFTR for insulation and a square wave AC. The transformer primary side was comprised in series to divide certain charging current and the secondly side was comprised of 6 fixed transformers so that they can generate certain amount of power and various output voltage through relay parallel compound 6 DC Link outputs. To confirm such structure's verification and validity, simulation with PSIM was conducted, and validity of proposed variable charger system was verified through 3kW stack production.

Formation of Thicker hard Alloy Layer on Aluminum Alloy by PTA Overlaying with Metal Powders (플라스마 아크 紛體肉盛法에 의한 Al 合金의 硬化厚膜 合金化層의 形成)

  • ;;中田一博;松田福久
    • Journal of Welding and Joining
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    • v.11 no.2
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    • pp.74-85
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    • 1993
  • Effect of Si metal powders addition with the plasma transferred arc(PTA) overlaying process on characteristics of the alloyed layer in aluminum alloy(A5083) has been investigated. The overlaying conditions were 175-250A in plasma arc current, 500mm/min in travel speed, the 5-20g/min in powder feeding rate. Main results obtained are summarized as follows. 1)Sufficient size of molten pool on surface of base metal was required for forming an alloyed layer; in a fixed travel, the formation of alloyed layer with clear and beautiful surface depend upon the plasma arc current and powder feeding rate; the greater plasma arc current and the smaller powder feeding rate were, the better bead was formed. Optimum alloyed conditions by which an excellent alloyed bead obtained was 225A in plasma arc current. PTA process made it possible to form an alloyed layer with up to 67wt% Si. 2)Microstructure in the alloyed layer was in accord with prediction from the Al-Si phase diagram 3)The hardness of the alloyed layer increased in proportion to Si content. 4)As volume fraction of primary Si increased, the specific wearness of the alloyed layer was significantly improved. However, no further improvement was found when the volume fraction was greater than about 30%. 5)Utilizing the PTA process, a crack free alloyed layer with maximum hardness of about Hv 310 could be obtained.

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Analysis of Microsegregation in Fe-Cr-Ni Weld Metal (Fe-Cr-Ni강 용접금속부의 미세편석에 관한 해석)

  • 박준민;박종민;안상곤;이창희;윤의박
    • Journal of Welding and Joining
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    • v.16 no.5
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    • pp.56-66
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    • 1998
  • During solidification or welding of alloys, the solute redistribution brings out microsegregation. The microsegregation causes the formation of non-equilibrium second phases, shrinkage and porosity degrading mechanical/chemical properties Therefore, it has been required to predict microsegregation quantitatively. To predict the degree of microsegregation, more exact and appropriate computer simulation technique has been actively used during last two decades. To predict the degree of microsegregation in weld metal, an advanced two dimensional model was suggested. In the new model, both primary and secondary arm regions were defined for the analysis region. The growth in the primary arm regina was assumed to be a planar for effective calculation. Especially, for the growth of a secondary arm, a simple and effective mathematical function was established to show the growing pattern, the solute diffusion in the solid phase was calculated by finite difference method (FDM). The solid-liquid interface movement was considered to be in local equilibrium state. The experiments for welding of 310S stainless steel were carried out in order to examined the reasonability and feasibility of this model. The concentration profiles of the solute predicted by this model were compared with those obtained from experimental works.

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Transmission Electron Microscopy Characterization of Early Pre-Transition Oxides Formed on ZIRLOTM

  • Bae, Hoyeon;Kim, Taeho;Kim, Ji Hyun;Bahn, Chi Bum
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.301-312
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    • 2015
  • Corrosion of zirconium fuel cladding is known to limit the lifetime and reloading cycles of fuel in nuclear reactors. Oxide layers formed on ZIRLO4^{TM}$ cladding samples, after immersion for 300-hour and 50-day in a simulated primary water chemistry condition ($360^{\circ}C$ and 20 MPa), were analyzed by using the scanning transmission electron microscopy (STEM), in-situ transmission electron microscopy (in-situ TEM) with the focused ion beam (FIB) technique, and X-ray diffraction (XRD). Both samples (immersion for 300 hours and 50 days) revealed the presence of the ZrO sub-oxide phase at the metal/oxide interface and columnar grains developed perpendicularly to the metal/oxide interface. Voids and micro-cracks were also detected near the water/oxide interface, while relatively large lateral cracks were found just above the less advanced metal/oxide interface. Equiaxed grains were mainly observed near the water/oxide interface.