• Transactions of the Korean hydrogen and new energy society
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• v.16 no.3
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• pp.244-252
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• 2005

It is very interesting and important in the academic point of view and in practical use the hydrogen-induced phase separation(HIPS) which appears during hydrogen heat treatment. Since hydrogen can be removed very fast by pumping it out the hydrogen-induced new lattice phase which can not be obtained without hydrogen can be preserved as meta-stable state. In this study it has been investigated whether the HIPS appear in Pd-Al, Pd-Co, Pd-Cr, Pd-Ti, Pd-V and Pd-Zr alloys and discussed thermodynamic representation of the HIPS. The Pd alloys were arc-melted under argon atmosphere and remelted 4 or 5 times for homogenization. The alloys were annealed at 600$^{\circ}C$ under vacuum for 24 hrs and then subjected to pressure-composition isotherm measurements at 100$^{\circ}C$. The hydrogen heat treatment(HHT) of samples was carried out at 600$^{\circ}C$ under hydrogen pressure of 70 bar for 6 days and PC isotherms at 100$^{\circ}C$ were measured. By comparing the PC isotherms measured before and after HHT, occurrence of phase separation was determined. The experimental results showed that the HIPS appeared only in Pd-0.05Co alloy. For Pd-Co alloys with various composition the PC isotherms were measured. By adopting Park-Flanagan model for ternary thermodynamics the Gibbs free energy change for Pd-Co-H solid solution was calculated and subsequently with this the HIPS in Pd-Co alloy was explained fairly.

• Geomechanics and Engineering
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• v.17 no.5
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• pp.413-420
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• 2019

The changes in earth pressure and ground settlement due to underground excavation near an existing retaining wall were studied experimentally according to the separation distance between the underground excavation and the retaining wall. In addition, this study attempted to experimentally prove that the arching phenomenon occurred during the construction of the underground space. A model tank having 120 cm in length, 160 cm in height, and 40 cm in width was manufactured to simulate underground excavation through the use of five separated base wall bodies. The variation of earth pressure on the retaining wall was measured according to the underground excavation phase through the use of 10 separated right wall bodies. The results showed that the earth pressure on the retaining wall was changed by the lowering of the first base bottom wall; however, the earth pressure was not changed significantly by the lowering of the third base bottom wall, since the third base wall had sufficient separation distance from the retaining wall. Lowering of the first base wall induced a decrease in the earth pressure in the lower part of the retaining wall; in contrast, lowering of the first base wall induced an increase in the earth pressure in the middle part of the retaining wall, proving the arching effect experimentally. It is necessary to consider the changes in earth pressure on the retaining wall in designing earth retaining structures for sections where the arching effect occurs.

• Macromolecular Research
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• v.11 no.1
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• pp.53-61
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• 2003

A molecular-thermodynamic model is developed for the salt-induced protein precipitation. The protein molecules interact through four intermolecular potentials. An equation of state is derived based on the statistical mechanical perturbation theory with the modified Chiew's equation for the fluid phase, Young's equation for the solid phase as the reference system and a perturbation based on the protein-protein effective two body potential. The equation of state provides an expression for the chemical potential of the protein. In a single protein system, the phase separation is represented by fluid-fluid equilibria. The precipitation behaviors are simulated with the partition coefficient at various salt concentrations and degree of pre-aggregation effect for the protein particles. In a binary protein system, we regard the system as a fluid-solid phase equilibrium. At equilibrium, we compute the reduced osmotic pressure-composition diagram in the diverse protein size difference and salt concentrations.

• Korean Chemical Engineering Research
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• v.43 no.1
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• pp.16-20
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• 2005

Porous polypropylene membranes were prepared by a thermally induced phase separation method in super-critical $CO_2$, where polypropylene and Camphene were used as raw materials. The porosity of polypropylene membranes with 10 wt% polypropylene concentration was 78, 80, 73% by using methanol, ethanol, and n-buthanol as an analytical solvent, respectively. The tensile strength increased with an increasing polypropylene concentration, where it was $0.17kg_f/mm^2$ at 10 wt% polypropylene concentration. The extraction rate for Camphene increased with time and Camphene was removed 94% in 5 min. It increased with an increasing temperature and was 99% at $45^{\circ}C$, however, decreased with an increasing temperature at higher than $45^{\circ}C$. The extraction rate increased with an increasing pressue up to 150 bar, however, decreased slightly with an increasing pressure over 150 bar. The extraction rate had a relation with the solubility of Camphene in supercritical $CO_2$.

• Journal of the Optical Society of Korea
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• v.18 no.6
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• pp.753-761
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• 2014

We propose a two-step UV irradiation procedure to fabricate polymer-dispersed liquid crystal (PDLC) films by lamination. During the first UV treatment, before lamination, the UV-curable monomers coated on one film substrate are solidified through photo-polymerization as the phase separation between the liquid crystals and the monomers. Introducing an adhesion-enhancement layer on the other plastic substrate and controlling the UV irradiation conditions ensure that UV-induced cross-linkable functional groups remain on the surfaces of the photo-polymerized layers. Thereby, the adhesion stability between the top and bottom films is much improved during a second (post-lamination) UV treatment by further UV-induced cross-linking at the interface. Because the adhesion-enhancement and PDLC layers prepared by the bar-coating process are solidified before lamination, the PDLC droplet distribution and the cell gap between the two plastic substrates remain uniform under the lamination pressure. This ensures that the voltage-controlled light transmittance is uniform across the entire sample.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3215-3220
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• 2007

Gas-liquid separator has been designed for the sake of reducing expenses associated with production operations. To date, a number of gas-liquid separators have been installed and put to use for various applications. Despite the advantages of simple and compact configuration of separator with no moving part, its efficient operation is limited in terms of total pressure losses, separation performance and flow-induced noise and vibration, which are closely associated with the very complicated flow phenomena involved. In the present study, a gas-liquid centrifugal separator with a swirl vane is investigated for the purpose of water separation from compressed moisture air. The 3D Navier-Stokes equations are numerically solved using a fully implicit finite volume scheme. Based upon the obtained solutions, tangential velocities, centrifugal forces, vortices and total pressure losses are analyzed to find out the best design parameters. From the present study, several attempts are made to improve the performance of conventional separators of centrifugal type.

• Ocean Systems Engineering
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• v.2 no.1
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• pp.17-31
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• 2012

This study investigated the behavior of a non-isothermal $CO_2$ bubble formed through a leak process from a high-pressure source in a deep sea. Isenthalpic interpretation was employed to predict the state of the bubble just after the leak. Three modes of mass loss from the rising bubble were demonstrated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. A graphical interpretation of the last mode was provided in the pressure-enthalpy diagram. A threshold pressure (17.12 bar) was identified below which the last mode was no longer present. The second mode was as effective as the first for a bubble formed in deep water, leading to faster mass loss. To the contrary, only the first mode was active for a bubble formed in a shallow region. The third mode was insignificant for all cases.

• Advances in materials Research
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• v.13 no.3
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• pp.243-251
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• 2024

The asymmetric polylactic acid (PLA) membrane was prepared via phase inversion method using non-solvent induced separation (NIPS) technique. This study aims to synthesized as well as to characterize the PLA membrane and evaluating the membrane performance on water flux and permeability. In addition, this research also studied the removal performance of methylene blue dye. The polymer solution has been prepared using 12 wt.% of PLA and dissolved in 88 wt.% of Dimethylacetamide (DMAc) as a solvent. Then, the cast film was immersed in different ratio of coagulant bath medium (distilled water: methanol: ethanol) ranging from 100:0:0, 75:25:0, 75:0:25 and 75:12.5:12.5, respectively). Several characterizations were performed which include, membrane contact angle and membrane porosity. Performance PLA membranes were determined in terms of water flux and permeability at 1 bar transmembrane pressure using dead-end permeation cell. Finally, methylene blue (MB) removal efficiency was tested at the same transmembrane pressure. The findings revealed that the increase of alcohol concentration in coagulant bath resulted in higher porosity and lower contact angle. In short, MB dye rejection efficiency is also closely related to the amount of alcohol ratio used in coagulant baths. Increases in concentration of methanol and ethanol in coagulant bath medium increases the membrane porosity thus increased in efficiency of methylene blue rejection.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.407-408
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• 2011

Natural boron consists of two stable isotopes 10B and 11B with natural abundance of 18.8 atom percent of 10B and 81.2 atom percent of 11B. The thermal neutron absorption cross-section for 10B and 11B are 3837 barn and 0.005 barn respectively. 10B enriched specific compounds are used for control rods and as a reactor coolant additives. In this work 2 methods for boron enrichment were analysed: 1) Gas irradiation in static conditions. Dissociation occurs due to multiphoton absorption by specific isotopes in appropriately tuned laser field. IR shifted laser pulses are usually used in combination with increasing the laser intensity also improves selectivity up to some degree. In order to prevent recombination of dissociated molecules BCl3 is mixed with H2S 2) SILARC method. Advantages of this method: a) Gas cooling is helpful to split and shrink boron isotopes absorption bands. In order to achieve better selectivity BCl3 gas has to be substantially rarefied (~0.01%-5%) in mixture with carrier gas. b) Laser intensity is lower than in the first method. Some preliminary calculations of dissociation and recombination with carrier gas molecules energetics for both methods will be demonstrated Boron separation in SILARC method can be represented as multistage process: 1) Mixture of BCl3 with carrier gas is putted in reservoir 2) Gas overcooling due to expansion through Laval nozzle 3) IR multiphoton absorption by gas irradiated by specifically tuned laser field with subsequent gradual gas condensation in outlet chamber It is planned to develop software which includes these stages. This software will rely on the following available software based on quantum molecular dynamics in external quantized field: 1) WavePacket: Each particle is treated semiclassicaly based on Wigner transform method 2) Turbomole: It is based on local density methods like density of functional methods (DFT) and its improvement- coupled clusters approach (CC) to take into account quantum correlation. These models will be used to extract information concerning kinetic coefficients, and their dependence on applied external field. Information on radiative corrections to equation of state induced by laser field which take into account possible phase transition (or crossover?) can be also revealed. This mixed phase equation of state with quantum corrections will be further used in hydrodynamical simulations. Moreover results of these hydrodynamical simulations can be compared with results of CFD calculations. The first reasonable question to ask before starting the CFD simulations is whether turbulent effects are significant or not, and how to model turbulence? The questions of laser beam parameters and outlet chamber geometry which are most optimal to make all gas volume irradiated is also discussed. Relationship between enrichment factor and stagnation pressure and temperature based on experimental data is also reported.

• Ocean Systems Engineering
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• v.2 no.1
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• pp.33-47
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• 2012

This study revealed the behavior of droplets formed through leak process in deep water. There was a threshold depth named the universal attraction depth (UAD). Droplets rose upward in the zone below the UAD called the rising zone, and settled down in the zone above the UAD called the settling zone. Three mass loss modes were identified and formulated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. The first two were active for the settling zone, and all the three were effective for the rising zone. In consequence, the life time of the droplets in the rising zone was far shorter than that of the droplets in the settling zone.