• Journal of the Korean Wood Science and Technology
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• 제46권5호
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• pp.497-510
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• 2018

본 연구에서는 과열증기를 이용하여 열처리한 낙엽송재의 야외 내후성 시험을 통해 부후균과 해충에 대한 저항성을 평가하였다. 12개월간 진행된 야외 내후성 시험 결과, 무처리재는 흰개미에 의한 피해가 두드러지게 나타났지만 방부목재와 과열증기 열처리재에서는 육안으로 관찰되는 피해는 발견되지 않았다. 무처리재와 방부목재는 약 5%의 질량 감소를 보였으며, 과열증기 열처리재는 약 1%의 질량 감소를 보였다. 야외 내후성 시험이 진행된 후 방부목재에 남아있는 방부약제의 함량이 야외 내후성 시험 전보다 감소한 것으로 보아 야외 내후성 시험이 진행되는 동안 방부약제가 일부 용출된 것으로 보이며, 이에 따라 방부목재의 질량 감소가 무처리재와 유사한 수준으로 나타난 것으로 생각되었다. 과열증기를 이용한 열처리는 방부약제 주입과 같은 화학적인 처리 없이 친환경적으로 목재의 부후균과 해충에 대한 저항성을 개선시킬 수 있는 가능성이 확인되었으며, 이를 위하여 장기적인 관찰이 추가적으로 필요할 것이라 생각된다.

• Journal of the Korean Wood Science and Technology
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• 제23권3호
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• pp.66-72
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• 1995

The rate of fixation of the components were evaluated in CCA-Type B and CCFZ-treated radiata pine sapwood by quantitative analysis of solution expressed from the treated wood. The leaching characteristics of radiata pine blocks treated with CCA-Type B and CCFZ were also evaluated by the AWPA standard leaching test. Both fixation and leaching charactersistics of CCA-Type B were compared with CCA-Type C treated wood samples. The rate of CCA-Type B fixation was a little faster than that of CCFZ. However, significant amounts of arsenic was unfixed in the CCA-Type B treated samples and consequently leached. These significant quantities of arsenic liberated from the CCA-Type B treated wood during service may pose some environmental concerns. Arsenic was no longer detectable from CCA-Type C treated samples when fixation was complete, even though the fixation of CCA-Type C was slower in some degree than CCA-Type B. In summary, it could be said that CCFZ was much safer preservative than CCA-Type B by the criterion based on the relative hazard assessed by absolute amount of unfixed element present in the treated wood. Also the decision that CCA preservative has to move from Type B to Type C should be made sooner or later for continuous use of CCA preservative in the future.

• Journal of the Korean Wood Science and Technology
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• 제20권1호
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• pp.15-22
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• 1992

This study was performed to investigate the corrosion of metal fasteners in waterborne preservative-treated wood. Of all the metal tested, steel exhibited the greatest amount of corrosion across all preservatives and exposure conditions whereas stainless steel was totally inert. Galvanized steel corroded at a much lower rate compared to steel and the corrosion of brass was negligible. Among the preservatives, CCA-Type B was the most corrosive system tested. The sequence for the average corrosivity across all metals was: CCA-type B>CCA-Type C${\geq}$ACC${\geq}$CCA-Type A. Across all metals and retentions the salt formulations were more corrosive than the oxide and the corrosion was increased with the increse in the amount of preservative loadings. The amount of corrosion was also increased with the increase in exposure relative humidity (RH) across all metals and presevatives However, at the 60% RH exposure condition, the corrosion of metals was very negligible. Consequently, it can be concluded that across all metals oxide-type preservatives should be used to prevent the corrosion problem of metal fasteners in contact with treated wood and the use of steel nail preservative-treated wood should be avoided without distinction of end-use location, i.e., exterior or interior, and the use of stainless steel or at least brass nail in damp exterior condition was strongly recommended.

• 한국가구학회지
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• 제19권5호
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• pp.358-364
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• 2008

Wood-inorganic material composite (WIC) was prepared by impregnating wood with copper sulfate ($CuSO_4\;5H_2O$) solution and by immersed wood in sodium carbonate($Na_2CO_3$) solution in order to introduce insoluble copper compounds {copper carbonate hydroxide, $CuCO_3\;Cu(OH)_2$} into the wood to give fungicidal effects in treated-wood. The weight percent gains (WPGs) of treated wood reached maximum value by impregnation of 20% copper sulfate solution and immersion in about 15% sodium carbonate solution for 24 hrs. Inorganic substances were present mainly in the lumina and cross-field pitting of tracheides. These substances were proved to be the insoluble copper carbonate hydroxide against water by the energy dispersive X-ray analyzer in conjunction with a scanning electron microscope (SEM-EDXA). The treated specimens showed high preservative effectiveness because the weight losses were hardly occurred by the fungi degradation test.

• Journal of the Korean Wood Science and Technology
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• 제25권4호
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• pp.92-98
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• 1997

To make good use of chitosan forming complex with heavy metals in wood preservative treatment, woods impregnated with chitosan and copper sulfate were prepared. Amounts of leached copper, decay resistance, anti-mold efficacy, iron corrosion rates, moisture regain rates and degradation pattern in chitosan pre-treated and untreated wood were compared. After leaching test, amounts of leached copper from chitosan pre-treated wood had a much smaller than chitosan untreated wood, and good decay resistance was retained even after leaching test. From these results, it was proved that chitosan-copper complex formed in wood played and important role for decay durability. In chitosan pre-treated wood, damage values by test molds became remarkably smaller, but the growth of test molds was not perfectly inhibited. Distinct differences in iron corrosion rates between chitosan pre-treated and untreated woods was not recognized but chitosan pre-treated wood showed the lower moisture regain rates than chitosan untreated wood because of water insoluble chitosan membrane formed in wood. After leaching test, the tracheid walls in the wood treated with 2.0% copper sulfate only were eroded by the fungal attacks, but those in the wood pre-treated with chitosan remained almost intact.

• Journal of the Korean Wood Science and Technology
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• 제39권6호
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• pp.521-530
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• 2011

구조용 집성재의 시장 수요가 확대되고 다양화되면서 교량이나 파고라와 같이 외기에 노출되는 조건에서 사용하기 위한 고 내구성 구조용 집성재에 대한 시장 요구가 증가할 것으로 예견된다. 따라서 본 연구는 국산 침엽수재로 제조되는 구조용 집성재에 적합한 방부처리 기술 및 기준을 개발하기 위한 목적으로 진행되었다. 본 연구에서는 방부처리된 국산 리기다소나무 제재목을 이용하여 구조용 집성재를 제조하고 제조 단계별 생산수율과 KS 품질기준 충족여부를 평가하였다. 방부집성재의 제조수율은 일반 집성재와 큰 차이를 나타내지 않았으며, 목재자원의 효율적인 활용을 위해서는 집성재 제조수율 향상방안과 함께 부산물에 대한 효율적 활용방안도 함께 검토되어야 한다. 리기다소나무 방부처리재의 경우 불균일한 방부약제 흡수량으로 인하여 구조용 집성재 제조용으로 적합하지 않은 것으로 확인되었으며, 집성재 제조 후에 유용성 방부제를 처리하는 방안에 대한 추가적인 검토가 요구되었다.

• Journal of the Korean Wood Science and Technology
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• 제43권5호
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• pp.641-651
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• 2015

The aim of this study was to estimate the service life of alkaline copper quaternary (ACQ)-treated wood. The service life of preservative-treated wood was estimated by comparing a residual quantity of ACQ in wood with toxic threshold to fungi. Indoor and outdoor leaching tests were carried out in order to predict residual ACQ quantity within wood. As a result, the leaching ratio of ACQ from treated wood above ground via precipitation was 18.1% for 50 years. When the H4 treated wood, which is traditionally used in contact with the ground and fresh water, is used above-ground, the leaching ratio of ACQ for 50 years is 18.1% and the residual quantity of ACQ is $4.2kg/m^3$, which is higher than the toxic threshold of ACQ. Thus, the H4 treated wood used above-ground will be resistant to biodeterioration for at least 50 years.

• Journal of the Korean Wood Science and Technology
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• 제32권6호
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• pp.7-13
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• 2004

In this study, the Korean pine wood (Pinus densiflora Sieb. et Zucc) and Italian poplar wood (Populus euramericana Guinier) was treated with a mixture of monoammonium phosphate (MAP) and boric acid. Their usability as fire retardant and as decay-resistant construction and interior materials were evaluated by testing of chemicals, corrosion rate and absorption rate, weight loss and chemical contents. An experiment was performed to compare treated pine wood and Italian poplar wood. According to the results, Italian poplar wood had higher specific gravity and retention of chemicals than pine wood, and treated wood showed higher decay-resistance than untreated one. Weight loss was less in treated wood than untreated one because the degree of decay was lower in the former than the latter. Corrosion rate and absorption rate met the KS standard for wood preservative performance. The chemical contents analysis was carried out to determine the degree of decay and it was found that the preservative effect of chemical treatment was lower in Italian poplar wood than in pine wood.

• Journal of the Korean Wood Science and Technology
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• 제46권3호
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• pp.253-259
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• 2018

ACQ 처리 목재에서 약제의 침투깊이를 확인하기 위하여 지금까지는 Cu 성분만을 대상으로 침윤도를 측정해 왔다. 본 연구에서는 Cu 이외에 ACQ의 유효성분 중에 하나인 DDAC의 침투깊이를 조사할 수 있는 DDAC 발색처리 방법을 개발하고 다음과 같은 결론을 얻었다. DDAC 성분은 2',7'-dichlorofluorescein 발색 지시약과 반응하여 진한 주황색으로 발색한다. 이와 같은 발색 반응은 DDAC 용액에서 뿐만 아니라 ACQ 처리 목재에서도 진행되어 DDAC가 침투되어 있는 목재 조직에서는 동일하게 주황색으로 발색한다. 본 연구를 통하여 개발된 DDAC 발색기술에 의하여 방부제 난주입성 수종인 가문비나무에서 Cu에 비하여 DDAC의 목재 침투성이 우수한 사실을 육안으로 확인할 수 있었으며, 다른 난주입성 수종에 대해서도 Cu와 DDAC의 침투성 차이를 조사할 필요가 있다.

• Journal of the Korean Wood Science and Technology
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• 제45권1호
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• pp.107-115
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• 2017

본 연구에서는 국산 낙엽송 방부원주목을 대상으로 물리적 처리(인사이징, 배할, 열기건조)에 따른 표면할렬 방지효과와 장기 사용연한 확보 가능성을 실험적으로 검토하였다. 표면할렬이 목재 내 외부의 급격한 수분경사로 인해 발생하기 때문에 본 연구에서는 국내 최저 평형함수율 조건[온도($2^{\circ}C$), 습도(44.6%)]에서 시험편이 평형함수율(8.6%)에 도달할 때까지 실험을 진행하였다. 물리적 처리에 따른 표면할렬 방지효과를 검토한 결과, 무처리 시험편(Type C)의 경우, 모든 시험편에서 약제 침투 깊이보다 깊은 할렬이 발생하여 장기 내부후성을 확보할 수 없는 것으로 나타났다. 한편, 약제침투도 개선을 위해 사용하는 인사이징 처리만으로도 시험편의 80%에서 약제침투깊이보다 깊은 표면할렬을 방지하는 효과가 있었다. 그러나 국내에서 할렬을 방지하고자 사용하는 배할 처리는 인사이징 처리에 비하여 약제 침투깊이보다 깊은 표면할렬을 야기하였다.