• Title/Summary/Keyword: precise reproducibility

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Fabrication of NiS Thin Films as Counter Electrodes for Dye-Sensitized Solar Cells using Atomic Layer Deposition

  • Jeong, Jin-Won;Kim, Eun-Taek;Park, Su-Yong;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.276.2-276.2
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    • 2016
  • Dye-sensitized solar cells (DSCs) are promising candidates for light-to-energy conversion devices due to their low-cost, easy fabrication and relative high conversion efficiency. An important component of DSCs is counter electrode (CE) collect electrons from external circuit and reduct I3- to I-. The conventional CEs are thermally decomposed Pt on fluorine-doped tin oxide (FTO) glass substrates, which have shown excellent performance and stability. However, Pt is not suitable in terms of cost effect. In this report, we demonstrated that nickel sulfide thin films by atomic layer deposition (ALD)-using Nickel(1-dimethylamino-2-methyl-2-butanolate)2 and hydrogen sulfide at low temperatures of $90-200^{\circ}C$-could be good CEs in DSCs. Notably, ALD allows the thin films to grow with good reproducibility, precise thickness control and excellent conformality at the angstrom or monolayer level. The nickel sulfide films were characterized using X-ray photoelectron spectroscopy, scanning electron microscopy, X-ray diffraction, hall measurements and cyclic voltammetry. The ALD grown nickel sulfide thin films showed high catalytic activity for the reduction of I3- to I- in DSC. The DSCs with the ALD-grown nickel sulfide thin films as CEs showed the solar cell efficiency of 7.12% which is comparable to that of the DSC with conventional Pt coated counter electrode (7.63%).

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Sensitivity and accuracy for rheological simulation of cement-based materials

  • Kim, Jae Hong;Jang, Hye Rim;Yim, Hong Jae
    • Computers and Concrete
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    • v.15 no.6
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    • pp.903-919
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    • 2015
  • The flow of freshly mixed cement-based material shows thixotropy, which implies some difficulties on robust measurement of its rheological properties: The flow curve of thixotropic materials depends on the used protocol. For examples, higher viscosity is obtained when the rate of shear strain is more quickly increased. Even though precise measurement and modelling of the concrete rheology needs to consider the thixotropic effect, engineers in the concrete field prefer considering as a non-thixotropic Herschel-Bulkley fluid, even more simply Bingham fluid. That is due to robustness of the measurement and application in casting process. In the aspect of simplification, this papers attempts to mimic the thixoropic flow by the non-thixotropic Herschel-Bulkley model. Disregarding the thixotropy of cement based materials allows us to adopt the rheological concept in the field. An optimized protocol to measure the Bingham parameters was finally found based on the accuracy and reproducibility test of cement paste samples, which minimizes the error of simulation stemming from the assumption of non-thixotropy.

Prediction of Amount of Mandibular Set Back with 3 Plain Radiographs in Mandibular Sagittal Split Ramus Osteotomy (하악상행지 시상분할골절단술 시 하악후퇴량의 방사선학적 예측)

  • Noh, Lyang-Seok;Kim, Jin-Wook;Kwon, Tae-Geon;Lee, Sang-Han
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.33 no.4
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    • pp.323-330
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    • 2011
  • Purpose: The present study examined the reproducibility of an operation plan by comparing the jaw position of STO with the postoperative mandibular set back measurement in sagittal split ramus osteotomy. Methods: Thirty patients with class III dental and skeletal malocclusion and who were treated with BSSRO were reviewed. Three plain radiographs such as the panoramic view, the lateral cephalogram and the submentovertex view were taken before and after operation. Also, paper surgery for STO and model surgery were used to evaluate the amount of mandibular set back. Results: On the panoramic view, the amount of mandibular set back in STO was similar to the postoperative results of model surgery, but the amount of mandibular set back on the lateral cephalogram was smaller than the postoperative result of model surgery and then the amount of set back on submentovertex view was similar to the postoperative result of model surgery. Conclusion: Precise tracing and paper surgery should be performed for a combined expected STO in order to predict the exact amount of preoperative mandibular set back.

Radiation Quality Analysis of Diagnostic X-ray Equipment (진단용 X선 기기의 선질 분석)

  • Kim, Tae-Gon;Kim, Young-Pyo;Cheon, Min-Woo;Park, Yong-Pil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2010.10a
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    • pp.771-772
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    • 2010
  • X-ray equipment used to diagnose a patient has a big defect of a patient's exposure to radiation caused in irradiating X-ray to the human body, ICRP restricts the permissible exposure dose of the human body. A number of studies has been proceeded to reduce these exposures. In this study the high voltage generator with inverter system, which is possible to increase the generation efficiency of X-ray and to control the precise output power was produced. Also, to minimize the ripple which is possible to occur in the direct voltage that is applied to X-ray tube the propagation rectification method was applied and the radiation reproducibility and properties were evaluated to use this for the diagnosis of patient.

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Evaluation of Dose Distribution Using a Radiophotoluminescence Glass Dosimeter in Biobeam8000 Gamma Irradiation Device (유리선량계를 이용한 Biobeam8000 감마선 조사장치의 선량평가)

  • Shin, Sang-Hun;Lee, Sung-Hyun;Son, Ki-Hong;Lee, Hyun-Ho;Kim, Kum-Bae;Jung, Hai-Jo;Ji, Young-Hoon
    • Progress in Medical Physics
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    • v.22 no.4
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    • pp.198-205
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    • 2011
  • Gamma irradiator is widely used for cell, animal experiment, irradiation for blood, dose measurement, and education. Biobeam8000 gamma irradiator (STS Steuerungstechnik &. Strahlenschutz GmbH, Braunschweig, Germany, Cs137, 81.4 TBq) that KIRAMS (Korea Institute of Radiological and Medical Science) has is a irradiation device that enables to be used in large-capacity of 7.5 L and extensive area. Cs-137 source moves range of 24 cm back-and-forth in a regular cycle in beaker for uniform irradiation and a beaker that puts a specimen like existing radiation irradiator such as Gammacell3000 rotates $360^{\circ}$ during irradiation. Precise dose information according to the location of radiation source would be needed because of the movement of radiation source, whereas radiation could be uniformly irradiated in comparison with existing gamma irradiator. In this study, dose distribution of the inside beaker located in Biomeam8000 gamma irradiator was measured using glass dosimeter, and dose evaluation and distribution regarding dose linearity and dose reproducibility were implemented based on measurement results. This aims to show guideline for efficient use of irradiator based on measurement result when doing experiment or radiation exposure.

Usefulness of Non-Invasive Measurement Tool on Performance Evaluation of Inverter Type X-ray Unit (인버터식 X선장치의 성능평가 시 비접속형 측정기의 유용성)

  • Kang, Se-Sik;Kim, Chang-Soo;Ko, Sung-Jin
    • Journal of radiological science and technology
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    • v.31 no.2
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    • pp.123-127
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    • 2008
  • Purpose: As the demand of a simple and precise method increases to evaluate the performance of the inverter type x-ray unit, we evaluated the usefulness of the recently-introduced X-ray Multi-Function Test Device (moldel : Xi (unfors)-prestige). Method: We compared the performance of X-ray Multi-Function Test Device (XMFTD) which is non-inveasive type device with the performance of Dynalyzer III that has been most widely used inveasive type measure device. Result: X-ray output dose was increased a little in the XMFTD, but both devices were below the performance evaluation standard, 0.002 in the output reproducibility. Linearity of XMFTD were below 0.1 which means that Dynalyzer III showed more excellency in linearity. As the the accuracy of exposure factor, 1.8 and 2 tube voltage, 2.01 and 2.3 tube current were measured. The exposure time was also measured by 0.01 sec ${\pm}10%$. Both devices were within the acceptance of performance evaluatioin standard. Conclusion: We proved the usefulness of X-ray Multi-Function Test Device (model: Xi (unfors)-prestige) to evaluated the performance on reproductibility and linearity of X-ray output and accuracy of exposure factor of inverter type unit.

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Study on the Hardness Measurement of Earthenware : Focusing on the Cup of the Baekje (토기의 경도측정법 연구: 백제시대 배(杯)류를 중심으로)

  • Moon, Eun-Jung;Kang, Hee-Jun;Kim, Su-Kyoung;Lee, Han-Hyoung;Hong, Jong-Ouk;Hwang, Jin-Ju
    • Journal of Conservation Science
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    • v.25 no.4
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    • pp.431-438
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    • 2009
  • We have investigated the suitable measuring method and condition on the hardness testing for the earthenwares excavated from Poongnap mud castle in Hanseong Baekje period. The earthenwares which used on hardness testing have been classified according to Mohs hardness and external form and color. The Ultrasonic and Equotip testing method have used to the hardness testing on the surface of the earthenwares and the Rockwell and Micro-vickers testing methods have used to the hardness testing on the cross section of the earthenwares. As the results, the two methods applied to the surface of the earthenwares were very hard on the precise measurement and the measuring values were incompatible with the tendency classified according to Mohs hardness and external form and color. On the testing for the cross section of earthenware, the Rockwell-superficial hardness testing method was more suitable for the soft texture earthenware and highest reproducibility of the measuring value obtained at the test load and indentor are 15kgf and 1/16 “iron ball, respectively. The Micro-Vickers hardness testing method was suitable for the hard texture earthenware and highest reproducibility and accuracy of the measuring value obtained at the test load is 100gf. This results show strong possibility of progress on the classifying and comparing study for hardness of the earthenware and therefore active studies are expected on the field.

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Rapid and Precise Determination of Pb Isotope Ratios Using Mu1ti-Collector ICP/MS (다검출기 유도결합 플라즈마 질량분석기를 이용한 신속하고 정밀한 Pb 동위원소 분석)

  • 최만식;정창식;신형선;임태선
    • The Journal of the Petrological Society of Korea
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    • v.10 no.3
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    • pp.157-171
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    • 2001
  • This study investigated the effects of Pb/Tl ratio, Pb concentration and concomitant matrix elements on the measurement of Pb isotope ratios using multi-collector ICP/MS (AXIOM MC model). Accuracy and reproducibility of Pb isotope ratios in NBS 981 solution were estimated for 42 data measured from March to August 2001. Pb isotopes measured in rocks, bronzes and sediments were compared to data measured by TIMS. Reproducibilities for $^{206}Pb/^{204}Pb,\; ^{207}Pb/^{204}Pb,\;and\;^{208}Pb/^{204}Pb$ ratio were about 500 ppm (2sd) and for $^{207}Pb/^{206}Pb$\;and\;^{208}Pb/^{206}Pb$ were 100~200 ppm for 200 ng of Pb in NBS 981 solution. The optimum conditions for the analysis of Pb isotope ratios with AXIOM MC for best accuracy and reproducibility were defined as follows; 1) Pb/Tl ratio is about 10 2) Pb concentration is about 100 ng/ml 3) correction for mass discrimination is performed by exponential law using 2.3887 of $^{205}Tl/^{203}Tl$ and Pb mass fractionation factor empirically obtained from $ln(^{208}Pb/^{206}Pb)-ln(^{205}Tl/^{203}Tl)$ relationship. The sample data measured with MC/ICP/MS for acid-digested and chemically separated rock samples, and acid-digested bronze samples and sediment samples coincide with those of TIMS within analytical errors. Therefore, MC/ICP/MS is a rapid analytical technique for Pb isotope ratios with the similar precision compared with TIMS.

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Construction of 3D Spatial Information of Vertical Structure by Combining UAS and Terrestrial LiDAR (UAS와 지상 LiDAR 조합에 의한 수직 구조물의 3차원 공간정보 구축)

  • Kang, Joon-Oh;Lee, Yong-Chang
    • Journal of Cadastre & Land InformatiX
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    • v.49 no.2
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    • pp.57-66
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    • 2019
  • Recently, as a part of the production of spatial information by smart cities, three-dimensional reproduction of structures for reverse engineering has been attracting attention. In particular, terrestrial LiDAR is mainly used for 3D reproduction of structures, and 3D reproduction research by UAS has been actively conducted. However, both technologies produce blind spots due to the shooting angle. This study deals with vertical structures. 3D model implemented through SfM-based image analysis technology using UAS and reproducibility and effectiveness of 3D models by terrestrial LiDAR-based laser scanning are examined. In addition, two 3D models are merged and reviewed to complement the blind spot. For this purpose, UAS based image is acquired for artificial rock wall, VCP and check point are set through GNSS equipment and total station, and 3D model of structure is reproduced by using SfM based image analysis technology. In addition, Through 3D LiDAR scanning, the 3D point cloud of the structure was acquired, and the accuracy of reproduction and completeness of the 3D model based on the checkpoint were compared and reviewed with the UAS-based image analysis results. In particular, accuracy and realistic reproducibility were verified through a combination of point cloud constructed from UAS and terrestrial LiDAR. The results show that UAS - based image analysis is superior in accuracy and 3D model completeness and It is confirmed that accuracy improves with the combination of two methods. As a result of this study, it is expected that UAS and terrestrial LiDAR laser scanning combination can complement and reproduce precise three-dimensional model of vertical structure, so it can be effectively used for spatial information construction, safety diagnosis and maintenance management.

Evaluation of Respiration Reproducibility of Chest General X-ray Examination using Self-made Respiratory Synchronization Device (자체 제작한 호흡 동기화 장치를 통한 흉부 일반촬영 검사의 호흡 재현성 평가)

  • Kwon, Oh-Young;Lee, Chang-Hun;Yong, Keum-Ju;Jin, Seon-Hui;Jung, Da-Bin;Heo, Yeong-Cheol
    • Journal of the Korean Society of Radiology
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    • v.15 no.7
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    • pp.1049-1056
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    • 2021
  • The purpose of this study was to develop a respiratory synchronization device for X-ray (X-RSD) to increase the reproducibility of inspiration when examining the Chest X-ray of a patient who difficulty in breathing coordination. The X-RSD was self-made using an air pressure sensor and air was injected by connecting a ventilator to the mannequin for CPR. At this time, the amount of injected air was quantified using the SkillReporting device. After placing the X-RSD on the chest of the mannequin, the amount of air was tested in 6 steps from 200 to 700 cc by 100 cc increased. For the accuracy evaluation, the sensitivity of X-RSD was measured by repeating a total of 80 measurements, and the sensitivity was 100%, and very precise results were obtained. After that, the images examined while viewing the X-RSD of the chest lateral examination and the images obtained by the blind examination were compared and evaluated. The lung volume of X-RSD was larger than that of the blind test, and the deviation was smaller. Overall, the use of X-RSD can help with chest X-ray examination of patients who have difficulty in cooperating, and it is thought that it will be possible to contribute to the reduction of exposure dose by reducing the repeat rate of general X-ray examinations.