• Title/Summary/Keyword: precipitation treatment system

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Precipitation Behavior of Laves Phase in 10%Cr Ferrite System Alloy (10%Cr 페라이트계 합금에서 라베스상의 석출거동에 관한 연구)

  • Kim, I.S.;Kang, C.Y.;Bae, D.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.21-30
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    • 1999
  • The present study were investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and precipitation of laves phase under stress. Hardness changes in ferrite phase appeared two hardness peaks by precipitation of initial fine precipitator and laves phase in 3Mo-0.3Si and 3Mo-0.3Si-C specimens, respectively. Hardness changes in martensite phase of 3Mo-0.3Si-C specimen was lower in the initial stage of aging by carbide precipitation and after this, increased by re-hardening due to precipitation of laves phase. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time, laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. In the ferrite-martensite interface, laves phase was mainly precipitated and carbide was mainly formed at boundary of lath martensite than grain boundary. Adding the stress in aging, fine precipitator of inital precipitation of laves phase precipitated in (100) of perpendicular to tensile direction and has grown to only followed<010>direction and also, volume fraction of laves phase increased. Consequently, the stress added was accelerated initial precipitation of laves phase.

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Development of an environmentally friendly precipitation treatment system utilizing open space in residential estates (주거단지의 외부공간을 활용한 친환경적 우수처리 시스템 개발)

  • Lee, Eun-Heui
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.4 no.3
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    • pp.55-65
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    • 2001
  • The hydrological cycle system in the city is generally characterized by quick runoff, bad infiltration, low evaporation rate, and so on. It is caused by sealing greens up with pavements. Also, there are lots of contradictory environmental problems, such as inundation, the lack of underground water and dryness in the city, caused by the urban drainage system which is mostly focused on the quick draining off rainfall. In addition, the technique joining rain and sewage, which has more dangers of inundation, occupies 66% between two Korean drainage systems which consist of joining and dividing system. There has been some need to convert the present drainage system into the environmentally friendly hydrological cycle system. This is a theoretical study to examine some foreign cases and suggested applicable methods in our country, focusing on the environmentalyl friendly system of rainfall drainage. The precipitation treatment system can be made up of some possible phases choosing from premanagement, utilization, infiltration, retention, and inducement phases. Therefore, this study mostly focused on infiltration, retention, and inducement phases. It is necessary to suggest the multifunctional utilization of outdoor spaces, especially applying in new constructing and re-constructing residential estates.

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A Study on the Precipitation Behavior of $L2_1$-type $Ni_2AlTi$ Phase in B2-Ordered NiAl System (B2-규칙 NiAl계에 $L2_1$$Ni_2AlTi$상의 석출거동에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.4
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    • pp.187-194
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    • 2007
  • A transmission electron microscope (TEM) investigation has been performed on the precipitation of $L2_1$-type $Ni_2AlTi$ phase in B2-ordered NiAl system. The hardness after solution treatment is high in NiAl-Ti alloys suggesting the large contribution of solid solution strengthening in this alloy system. However, the amount of age hardening is not large as compared to the large microstructural variations during aging. At the beginning of aging, the $L2_1$-type $Ni_2AlTi$ precipitates keep a lattice coherency with the NiAl matrix. By longer periods of aging $Ni_2AlTi$ precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. Misfit dislocations, which are observed on {100} planes of H-precipitates have the Burgers vector of a <100> with a pure edge type. The lattice misfits of NiAl-$Ni_2AlTi$ system is estimated from the spacings of misfit dislocations to be 1.1% at 1273 K. The lattice misfits decrease with increasing aging temperature in this system.

Effect of Precipitation and Dissolution of Si on the Thermal Diffusivity in the Al-Si Alloy System (열처리를 통한 Si 고용 및 석출 반응이 Al-Si 합금의 열확산도에 미치는 영향)

  • Kim, Yumi;Kim, Youngchan;Choi, Seweon
    • Korean Journal of Materials Research
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    • v.30 no.9
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    • pp.474-479
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    • 2020
  • The effect of precipitation and dissolution of Si on the thermal diffusivity in the Al-Si alloy system is reported in this study and solution heat treatment followed by aging treatment is carried out to determine the effects of heat treatment on the thermal characteristics. The solution treatment is performed at 535 ℃ for 4 and 10 h and then the specimens are cooled by rapid quenching. The samples are aged at 300 ℃ for 4 h to precipitate Si solute. The addition of 9 wt% silicon contents makes the thermal diffusivity decrease from 78 to 74 mm/s2 in the cases of solid solution treated and quenched samples. After quenching and aging, the Si solute precipitates on the Al matrix and increases the thermal diffusivity compared with that after the quenched state. In particular, the increase of the thermal diffusivity is equal to 10 mm/s2 without relation to the Si contents in the Al-Si alloy, which seems to corresponded to solute amount of Si 1 wt% in the Al matrix.

Fundamental study on sustainable treatment system of mine water using magnetized solid catalyst

  • Mukuta, Chisato;Akiyama, Yoko
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.15-21
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    • 2019
  • In the mine exploration sites, sustainable treatment system of mine water with energy saving and minimized chemical additives is required. Since most of the mine water contains highly-concentrated ferrous ion, it is necessary to study on the removal method of iron ions. We propose the system consisting of two processes; precipitation process by air oxidation using solid catalyst-modified magnetite and separation process combining gravitational sedimentation and magnetic separation using a permanent magnet. Firstly, in the precipitation process (a former process of the system), we succeeded to prepare solid catalyst-modified magnetite. Air oxidation using solid catalyst-modified magnetite using $Fe_2(SO_4)_3$ as a starting material showed high iron removal capability. Secondly, in the separation process (latter process of the system), solid catalyst-modified magnetite using $Fe_2(SO_4)_3$ as a starting material can be separated by a superconducting bulk magnet and a permanent magnet.

The Effect of Alloying Elements and Heat Treatment on the Intergranular Corrosion of 440A Martensitic Stainless Steel(II) (440A 강의 입계부식에 미치는 합금원소와 열처리의 영향(II))

  • Kim,, Y.C.;Jung, B.H.;Kang, C.Y.
    • Journal of Power System Engineering
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    • v.15 no.3
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    • pp.52-57
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    • 2011
  • 440A martensitic stainless steels which were modified with reduced carbon content(~0.5wt.%) and addition of small amount of vanadium, tungsten and molybdenum 0.4wt.%, 0.4wt.% and 0.68wt.% respectively were manufactured. Effects of alloying elements and tempering temperatures on the intergranular corrosion were investigated through the method of DL-EPR(Double-electrochemical potentiodynamic reactivation). It was thought that the highest DOS(Degree of sensitization) of specimens was obtained at the tempering temperature of $450^{\circ}C$ regardless of types of alloy because of the precipitation of Cr7C3. Addition of vanadium lowered DOS a little above the tempering temperature of $550^{\circ}C$. It was considered to be effected by precipitation of VC carbides. Intergranular corrosion was influenced more by tempering temperature than by alloying elements of V, W and Mo.

Characterization of Hydroxy-interlayered Mineral in Non-Andic Soils from Jeju Island

  • Lee, Gyoo-Ho;Yungoo Song;Ha, Dae-Ho;Moon, Hi-Soo;Moon, Ji-Won
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.45-47
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    • 2001
  • Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

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Electron Microscope Analyses of Self-aligned HgTe Nanocrystallites Induced by Controlled Precipitation Technique

  • Lee, Man-Jong
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.3
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    • pp.8-13
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    • 2002
  • Controlled precipitation of quasi-binary semiconductor system is newly proposed as an effective and reliable technique for the formation of well-defined and crystallographically aligned semiconductor nanostructures. Using HgTe-PbTe quasi-binary semiconductor system, self-aligned HgTe nanocrystallites distributed three dimensionally within PbTe matrix were successfully formed by the simple three step heat treatment process routinely found in age hardening process of metallic alloys. Examination of the resulting nano precipitates using conventional transmission electron microscopy (CTEM) and high resolution TEM (HRTEM) reveals that the coherent HgTe precipitates form as thin discs along the (100) habit planes making a crystallographic relation of {100}$\_$HgTe///{100}$\_$PbTe/ and [100]$\_$HgTe///[100]$\_$PbTe/. It is also found that the precipitate undergoes a gradual thickening and a faceting under isothermal aging up to 500 hours without any noticeable coarsening. These results, combined with the extreme dimension of the precipitates (4-5 nm in length and sub-nanometer in thickness) and the simplicity of the formation process, leads to the conclusion that controlled precipitation is an effective method for preparing desirable quantum-dot nanostructures.

Effect of Sigma Phase on Electrochemical Corrosion Characteristics of a Deposited Metal of ER2594 (ER2594 용착금속의 전기화학적 부식특성에 미치는 시그마상의 영향)

  • Jung, Byong-Ho;Kim, Si-Young;Seo, Gi-Jeong;Park, Joo-Young
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.75-81
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    • 2015
  • A deposited metal specimen of ER2594 which is a super duplex steel welding wire used to investigate the effect of sigma(${\sigma}$) phase on electrochemical corrosion characteristics was prepared by gas tungsten arc welding. Aging treatment was conducted for the specimen at the temperature range of $700^{\circ}C$ to $900^{\circ}C$ for 5 to 300 minutes after annealing at $1050^{\circ}C$. Corrosion current density has decreased a little with an increase of aging time over 60 minutes at $700^{\circ}C$ to $900^{\circ}C$ and the uniform corrosion of deposited metal had more influence on the precipitation of ferrite than the precipitation of sigma phase. Therefore, the precipitation of sigma phase did not have much effect on the uniform corrosion. Pitting potential representing pitting corrosion has shown decreasing tendency as the precipitation of sigma phase increased. The degree of sensitization representing intergranular corrosion has shown increasing tendency as the precipitation of sigma phase increased at $700^{\circ}C$ to $800^{\circ}C$, while it has decreased at $900^{\circ}C$ for 60 to 300 minutes.

Treatment Technologies for Arsenic Removal from Groundwater: review paper (비소오염지하수의 현장처리기술동향: 리뷰)

  • Bang Sunbaek;Choe Eun Young;Kim Kyoung-Woong
    • Economic and Environmental Geology
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    • v.38 no.5 s.174
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    • pp.599-606
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    • 2005
  • Arsenic is a significantly toxic contaminant in groundwater in many countries. Numerous treatment technologies have been developed to remove arsenic from groundwater. The USEPA recommends several technologies as the best available technology (BAT) candidates for the removal of arsenic. Based on the USEPA classification, arsenic treatment technologies can be divided into four technologies such as precipitation, membrane, ion exchange, and adsorption technology. The recent amendment of arsenic drinking water standard from 50 to $10{\mu}g/L$ in the United States have impacted technology selection and application for arsenic removal from arsenic contaminated groundwater. Precipitation technology is most widely used to treat arsenic contaminated groundwater and can be applied to large water treatment facility. In contrast, membrane, ion exchange, and adsorption technologies are used to be applied to small water treatment system. Recently, the arsenic treatment technology in the United States and Europe move towards adsorption technology to be applied to small water treatment system since capital and maintenance costs are relatively low and operation is simple. The principals of treatment technologies, effect factors on arsenic removal, arsenic treatment efficiencies of real treatment systems are reviewed in this paper.