• 한국분말재료학회지
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• 제23권2호
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• pp.136-142
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• 2016

As precursors of cathode materials for lithium ion batteries, $Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$ powders are prepared in a continuously stirred tank reactor via a co-precipitation reaction between aqueous metal sulfates and NaOH in the presence of $NH_4OH$ in air or nitrogen ambient. Calcination of the precursors with $Li_2CO_3$ for 8 h at $1,000^{\circ}C$ in air produces dense spherical cathode materials. The precursors and final powders are characterized by X-ray diffraction (XRD), scanning electron microscopy, particle size analysis, tap density measurement, and thermal gravimetric analysis. The precursor powders obtained in air or nitrogen ambient show XRD patterns identified as $Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$. Regardless of the atmosphere, the final powders exhibit the XRD patterns of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ (NCM). The precursor powders obtained in air have larger particle size and lower tap density than those obtained in nitrogen ambient. NCM powders show similar tendencies in terms of particle size and tap density. Electrochemical characterization is performed after fabricating a coin cell using NCM as the cathode and Li metal as the anode. The NCM powders from the precursors obtained in air and those from the precursors obtained in nitrogen have similar initial charge/discharge capacities and cycle life. In conclusion, the powders co-precipitated in air can be utilized as precursor materials, replacing those synthesized in the presence of nitrogen injection, which is the usual industrial practice.

• 대기
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• 제28권2호
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• pp.211-222
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• 2018

Cloud droplet activation process is well described by $K{\ddot{o}}hler$ theory and several parameterizations based on $K{\ddot{o}}hler$ theory are used in a wide range of models to represent this process. Here, we test the two different method of calculating the solute effect in the $K{\ddot{o}}hler$ equation, i.e., osmotic coefficient method (OSM) and ${\kappa}-K{\ddot{o}}hler$ method (KK). To do that, each method is implemented in the cloud droplet activation parameterization module of WRF-CHEM (Weather Research and Forecasting model coupled with Chemistry) model. It is assumed that aerosols are composed of five major components (i.e., sulfate, organic matter, black carbon, mineral dust, and sea salt). Both methods calculate similar representative hygroscopicity parameter values of 0.2~0.3 over the land, and 0.6~0.7 over the ocean, which are close to estimated values in previous studies. Simulated precipitation, and meteorological variables (i.e., specific heat and temperature) show good agreement with reanalysis. Spatial patterns of precipitation and liquid water path from model results and satellite data show similarity in general, but on regional scale spatial patterns and intensity show some discrepancy. However, meteorological variables, precipitation, and liquid water path do not show significant differences between OSM and KK simulations. So we suggest that the relatively simple KK method can be a good alternative to the OSM method that requires various information of density, molecular weight and dissociation number of each individual species in calculating the solute effect.

• 한국물환경학회지
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• 제29권1호
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• pp.88-96
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• 2013

Much attention has been needed in water resource management at the watershed due to drought and flooding issues caused by climate change in recent years. Increase in air temperature and changes in precipitation patterns due to climate change are affecting hydrologic cycles, such as evaporation and soil moisture. Thus, these phenomena result in increased runoff at the watershed. The Soil and Water Assessment Tool (SWAT) model has been used to evaluate rainfall-runoff at the watershed reflecting effects on hydrology of various weather data such as rainfall, temperature, humidity, solar radiation, wind speed. For bias-correction of RCP data, at least 30 year data are needed. However, for most gaging stations, only precipitation data have been recorded and very little stations have recorded other weather data. In addition, the RCP scenario does not provide all weather data for the SWAT model. In this study, two scenarios were made to evaluate whether it would be possible to estimate streamflow using measured precipitation and long-term average values of other weather data required for running the SWAT. With measured long-term weather data (scenario 1) and with long-term average values of weather data except precipitation (scenario 2), the estimate streamflow values were almost the same with NSE value of 0.99. Increase/decrease by ${\pm}2%$, ${\pm}4%$ in temperature and humidity data did not affect streamflow. Thus, the RCP precipitation data for Hongcheon watershed were bias-corrected with measured long-term precipitation data to evaluate effects of climate change on streamflow. The results revealed that estimated streamflow for 2055s was the greatest among data for 2025s, 2055s, and 2085s. However, estimated streamflow for 2085s decreased by 9%. In addition, streamflow for Spring would be expected to increase compared with current data and streamflow for Summer will be decreased with RCP data. The results obtained in this study indicate that the streamflow could be estimated with long-term precipitation data only and effects of climate change could be evaluated using precipitation data as shown in this study.

• 한국수자원학회논문집
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• 제47권5호
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• pp.421-433
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• 2014

본 연구에서는 과거 50년간(1961~2010)의 서울 기후관측지점의 월 및 연별 강수량대비 잠재증발산량의 비인 건조지수의 변화를 분석하고, 과거기간(1971~2000)의 건조지수 대비 기후변화시나리오(RCP 4.5, RCP 8.5)에 따른 미래기간별(2011~2040, 2041~2070, 2071~2100) 건조지수 변화율(%) 분석을 실시하였다. 또한 각기 다른 5개의 잠재증발산량 산정식(FAO P-M식, Penman식, Makkink식, Priestley-Taylor식, Hargreaves식)을 적용하여 잠재증발산량 산정식이 건조지수와 건조지수 변화율(%)에 미치는 영향을 분석하였다. 분석결과에 의하면 RCP 4.5와 8.5 모두에서 과거기간에 비해서 기후변화시나리오에 따른 미래기간에서 월별 강수량, 평균기온 그리고 잠재증발산량이 증가하였다. 또한 잠재증발산량은 겨울철이 여름철과 비교하여 과거기간 대비 미래기간에서 큰 증가를 보였으나, 건조지수는 강수량의 영향으로 잠재증발산량과 다른 양상을 보였다. 따라서 수자원관리 측면에서 미래기후변화에 따른 겨울철 증발산량의 증가에 따른 적절한 대응이 필요하다. 기후변화시나리오를 반영하여 산정된 미래기간의 월 및 연별 건조지수 값은 각기 다른 잠재증발산량 적용식에 따라서 큰 차이를 보였다. 하지만 과거기간대비 미래기간의 월 및 연별 건조지수 변화율(%) 양상은 적용된 잠재증발산량 산정식에 따라서 큰 차이가 없었다.

• 한국광물학회:학술대회논문집
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• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
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• pp.45-47
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• 2001

Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

• 한국재료학회지
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• 제12권11호
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• pp.840-844
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• 2002

A spherical $BaMgAl_{10}$ $O_{17}$ :Eu phosphor has been synthesized by a multi-step precipitation route. In order to successfully synthesize the phosphor with spherical shape, the hydrated-alumina particles should be controlled for spherical shape. In this process, the hydroxypropyl cellulose (HPC) was used as a dispersing reagent. This reagent plays an important role in that the particles were controlled to have the uniform size of sub-micron. The final product prepared by the multi-step precipitation method maintained spherical shape with uniform size of 0.4$\mu\textrm{m}$. It can be seen in X-ray diffraction patterns, formation of the single phase of $BaMgAl_{10}$ $O_{17}$ :Eu phosphor prepared by the multi-step precipitation method at $1350^{\circ}C$. Also, the emission spectra of spherical $BaMgAl_{O}$ $10_{17}$ :Eu phosphor in the present case was compared with those of commercially-available blue phosphor under VUV (Vacuum Ultra Violet) excitation. The luminescence process of the $BaMgAl_{10}$ $O_{17}$ :Eu phosphor is characterized by the $4f^{6}$$5d^1$longrightarrow4f$^{7}$ transition (blue) of the $Eu^{2+}$ ion acting as an activating center and the maximum luminescence intensity was obtained by reduction treatment at 145$0^{\circ}C$.

• 한국지리정보학회지
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• 제5권4호
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• pp.1-8
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• 2002

TRMM/PR (Tropical Rainfall Measuring Mission/Precipitation Radar)과 기상청의 C-band 도플러 레이더(제주, 군산, 부산)의 비교는 지상 레이더의 검증을 위해서 이루어졌다. 검증에 사용된 사례는 2000년 하계에 TRMM이 한반도 남부, 약 $36^{\circ}N$ 이남을 지나갈 때 강한 강수가 있는 날을 선택하였다. 서로 view angle, bandwidths와 주파수가 다른 두 개의 레이더를 정량적으로 비교하는 것은 어려운 문제이다. 본 연구에서는 이를 해결하기 위해서 지상 레이더와 TRMM/PR을 동일한 격자로 만들어 동일 영역에서 비교하였다. 지상 레이더로부터 관측된 반사도는 PR에 의해 관측된 반사도에 비해 4-9dBZ정도 낮은 것으로 밝혀졌으며 이는 기계적인 성능이나 지형과 같은 많은 이유에 의해서 발생할 수 있다. 세 개의 지상 레이더 사이트 모두에서 TRMM과 비교하여 30dBZ 이상에서 RMSE가 가장 높게 나타나서 강한 에코를 지상레이더가 잘 관측하지 못하는 것을 알 수 있었다.

• 대한금속재료학회지
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• 제49권2호
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• pp.93-103
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• 2011

Precipitation behavior of high-nitrogen duplex Fe-24Cr-7Mn-4Ni-4Mo-0.43N stainless steel aged at $850^{\circ}C$ was investigated using scanning transmission electron microscopy. Based on the analyses of selected area diffraction patterns, four kinds of precipitates (intermetallic sigma (${\sigma}$) and chi (${\chi}$), $Cr_2N$ and secondary austenite) were identified. At the ferrite/austenite phase boundary, the ${\sigma}$ phase and secondary austenite were formed via ${\alpha}{\rightarrow}{\gamma}+{\sigma}$ eutectoid reaction. The precipitation of $Cr_2N$ occurred at the austenite grain boundary as well as the interior of the ferrite. The intermetallic ${\chi}$ phase also formed within the ferrite and showed a cube-cube orientation relationship with the ferrite. Further aging produced a lamellar structure composed of $Cr_2N$ and austenite along the ferrite/austenite boundary and enhanced the precipitation of the ${\chi}$ phase. The crystallographic features of the precipitates were also examined in terms of the orientation relationship with the austenite or ferrite matrix.

• International Journal of Advanced Culture Technology
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• 제12권1호
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• pp.51-59
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• 2024

Qiang ethnic group is one of the fifty-six ethnic minorities in China, and Qiang embroidery, as an important achievement of Qiang's intangible cultural heritage, is the precipitation and testimony of the history and culture of the Qiang ethnic group. However, with the development of the times, traditional and ancient Qiang embroidery is facing a dilemma due to the problem of a single form of communication. Therefore, it is necessary to add new communication media for Qiang embroidery to help it spread and develop better. In this paper, we extract the core representative patterns of Qiang embroidery, use the "shape grammars" as the rules of morphological changes, and generate new decorative pattern patterns with the characteristics of Qiang embroidery by adding, deleting, mirroring, rotating, and other relevant rules of changes, and combine the new patterns with the rules of formal beauty to combine the layout, which is then applied in the design of different cultural creations and products. The new patterns are combined with the rules of formal beauty and applied in the design of different cultural and creative products. To provide a quantitative method for the digital protection of Qiang embroidery in the new era of Chinese traditional art, and also provide new ideas for the industrialization application.

• 한국환경복원기술학회지
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• 제13권3호
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• pp.36-45
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• 2010

To analyze the relationship between climatic factors (monthly mean temperature and total precipitation) and tree-ring growths of Quercus mongolica Fischer (Mongolian oak) with different topographic sites in Mt. Worak, more than 10 trees were selected from each of seven stands. Two cores from each tree were measured for ring width. After crossdating, each ring-width series was double standardized by fitting first a negative exponential or straight regression line and secondly a 60-year cubic spline. Seven stands were categorized in two groups using cluster analysis for tree-ring index patterns. Cluster I (four stands) was located in higher elevation (550-812 m) with aspects of east, west and northwest, and cluster II (three stands) was located in rather lower election (330-628 m) with aspects of north and northwest. The aspects of two clusters were not significantly different. Response-function analysis showed a significant positive response to March precipitation for both clusters. It indicates that moisture supply during early spring season is important to radial growth because the cambial growths of ring-porous species, such as Mongolian oak, start before leaf growth. Cluster II showed a positive response to the precipitation of middle and late growing season, too.