• Journal of Magnetics
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• 제21권1호
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• pp.46-50
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• 2016

$Fe_2O_3/TiO_2$ nanocomposite were successfully synthesized by co-precipitation method using $Fe(NO_3)_3{\cdot}9H_2O$ and $Ti(SO_4)_2$ as raw materials. Structural and textural features of the mixed oxide samples were characterized by X-ray diffractometer, field emission scanning electron microscopy and energy-dispersive X-ray. The effects of initial concentration of oxytetracycline (OTC), different competitive ions and organics on the photocatalytic degradation rate of OTC by the $Fe_2O_3/TiO_2$ nanocomposite were analyzed under UV and visible light irradiation. The results indicate that the optimized initial concentration of OTC was 50 mg/L to achieve the best photocatalytic efficiency. $Cu^{2+}$, $NH_4{^+}$, $C_3H_8O$ and EDTA in the aqueous suspension were found to suppress the degradation rate of OTC, whereas the effect of $NO_3{^-}$ and $H_2C_2O_4$ can be ignored.

• 대한화학회지
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• 제24권1호
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• pp.53-62
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• 1980

본 실험에서는 혼합물중에서 한쪽 성분은 분체인 상태로 용액중에 분산시키고 이 용액중에서 다른 한 성분을 침전으로 석출시켜서 혼합물을 만드는 "부분침전법"이라는 새로운 혼합법으로 PZT ceramics를 만들기 위한 기초적 연구를 했다. 먼저 간단화 하기 위해서 $PbTiO_3$와 $PbZrO_3$의 생성반응을 개별적으로 검토했다. 그리고 이들 혼합상태가 ceramics 제조에 있어서 얼마나 중요한 인자인가도 다시 한번 확인시켰다.

• 센서학회지
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• 제17권5호
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• pp.361-368
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• 2008

Nanosized $SnO_2$ particles were synthesized by homogeneous precipitation method using tin chloride ($SnCl_4{\cdot}5H_{2}O$) and urea ($CO(NH_2)_2$). The powders were heated at $500^{\circ}C$ and $600^{\circ}C$ for 2h. The crystal structure, microstructure, thermal behavior, specific surface area were analyzed using XRD, FE-SEM, TGA and BET, respectively. The initial resistance and the $H_2$ sensing properties were measured as a function of ${Sb_2}{O_3}$ and Pd doping concentrations. The resistance was decreased with the addition of ${Sb_2}{O_3}$ and the sensitivity for $H_2$ gas was increased with the addition of Pd. Thus, the optimum $H_2$ gas sensing property was obtained in the 0.25.mol% ${Sb_2}{O_3}$ and 1.w% added $SnO_2$ powders.

• 전기화학회지
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• 제10권1호
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• pp.48-51
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• 2007

리튬이온전지의 스피넬형 양극활물질 $LiMn_2O_4$의 입자 크기 및 비표면적의 전기화학 특성상의 영향을 고찰하기 위하여 스피넬 물질을 공침법과 고상법에 의해 합성되었다. X-선 회절분석을 통하여 합성된 두 물질 모두 Fd3m space group을 갖는 스피넬 구조가 형성된 것을 확인하였다. 공침법을 사용하여 얻은 물질은 상대적으로 높은 충진 밀도와 균일한 입도 분포를 갖는 구형의 분말이었다. 그러나 고상법을 사용하여 얻은 활물질은 비교적 입자 크기가 작고 넓은 입도분포를 나타내었다. 측정된 두 물질의 비표면적(BET)은 각각 $0.8m^2g^{-1}$(공침법)과 $3.6m^2g^{-1}$(고상법)로 큰 차이를 보였다. 두 물질의 전기화학적 특성을 평가하기 위하여 코인타입(CR2032)전지를 제작하여 고온($55^{\circ}C$)에서 충 방전테스트를 하였다. 공침법으로 합성된 물질의 고온에서 방전용량 유지율은 50사이클 이후 고상법으로 합성된 물질의 68.3% 보다 14% 향상된 82.3%로 향상된 방전용량 유지율을 보였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.115-116
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• 2023

This study aims to investigate and improve the carbon dioxide sequestration capability and the mechanical properties of non-hydraulic low calcium silicate cement especially designed for CO₂ reaction and ordinary Portland cement subjected to the carbonation curing facilitating pH swing method. Nitric acid (HNO₃) was utilized as an liquid for the mixing of cement paste to enhance the initial dissolution of Ca ions from the cements by promoting low pH environment and prevent the direct precipitation of Ca with the anion, owing to the high solubility of Ca(NO₃)₂ in water. The results presented that the higher the concentration of HNO₃, the higher the compressive strength and CO₂ sequestration (until 0.1 M). Ca dissolution caused by the harsh acid attack onto the anhydrous cement particle lead to the higher carbonation reaction degree, forming abundant CaCO₃ crystals after the reaction. However, cement paste mixed with excessively high concentration of HNO₃ presented deterioration due to the too harsh pH environment and abundant NO₃- ions which are known to retard the reaction of cement.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2000년도 추계학술대회
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• pp.290-293
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• 2000

After kaolin clay was compulsorily contaminated with Co$^{2+}$ion, the remediation characteristics by electrokinetic method were analyzed. Ethanoic buffer was injected in the soil column and $CH_3$COOH was continuously inputted in cathode reservoir to restrain the pH elevation. Since pH of the cathode side of the soil column was 4.0 at initial and was restrained by 6.5 at 43.6 hours, Precipitation, Co(OH)$_2$, was not formed in the column. Effluent rate increased with time passage and remediation in the column in initial time was mainly controlled by ion migration. 13.1% of total in the soil column was remediated in 10 hours, and the 6.8% of total in 20.8 hours, and the 71.7% of total in 43.6 hours, and the 94.6% of total in 43.6 hours. Meanwhile, the residual concentrations in the column calculated by the developed model were similar to those by experiment.t.

• 대한화학회지
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• 제58권1호
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• pp.100-104
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• 2014

Magnetite nanoparticles were prepared by co-precipitation method and then silica was coated onto the surface of $Fe_3O_4$ by hydrolysis of TEOS. The silica coated magnetite nanoparticles were characterized for its structural, microstructural, optical, vibrational and magnetic properties by X-ray diffraction analysis, Scanning electron microscopy, UV-visible spectroscopy, Infrared spectroscopy and Vibration sample magnetometer, respectively. XRD study confirmed the presence of $SiO_2$ on the surface of magnetite nanoparticles. SEM study indicated that with increase in TEOS content the particles become bigger and mono-disperse. It was also found that the silica coating prevents magnetic particles from aggregation and imparts excellent stability.

• 청정기술
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• 제24권1호
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• pp.35-40
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• 2018

$N_2O$ 촉매 분해 반응을 위한 $Co_3O_4$ 촉매는 공침법을 이용하여 제조하였으며, 조촉매로서 Ce 및 Zr의 양을 (Ce 또는 Zr)/Co = 0.05의 몰비로 고정하여 제조하였다. 또한 K가 촉매에 미치는 영향을 조사하기 위해 1 wt%의 $K_2CO_3$를 함침하여 촉매를 제조하였다. 제조된 촉매의 특성은 BET, SEM, XRD, $H_2-TPR$, XPS를 통해 분석하였다. $Co_3O_4$ 촉매는 스피넬 결정상을 나타냈으며, 조촉매의 첨가는 입자 크기와 결정 크기를 감소시켜 비표면적을 증가시키는 것으로 나타났다. K의 도핑은 촉매 활성 물질인 Co의 활성 종인 $Co^{2+}$의 농도를 증가시켜 촉매 활성을 향상시키는 것으로 확인되었다. $N_2O$ 분해 반응 테스트는 $GHSV=45,000h^{-1}$, $250{\sim}375^{\circ}C$에서 수행되었으며 $Co_3O_4$ 촉매에 조촉매를 첨가하였을 때도 반응성이 증가하였지만, K를 함침하면 활성이 더욱 크게 증가하는 것으로 나타났다. K의 도핑이 활성 종인 $Co^{2+}$의 농도를 증가시키며, 환원온도를 낮춰 주어 활성에 큰 영향을 주는 것으로 확인하였다.

• Geomechanics and Engineering
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• 제20권2호
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• pp.165-174
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• 2020

The enzyme-induced carbonate precipitation (EICP) method has been investigated to improve the hydro-mechanical properties of natural soil deposits. This study was conducted to explore the stiffness evolution during various stress scenarios. First, the optimal concentration of urea, CaCl₂, and urease for the maximum efficiency of calcite precipitation was identified. The results show that the optimal recipe is 0.5 g/L and 0.9 g/L of urease for 0.5 M CaCl₂ and 1 M CaCl₂ solutions with a urea-CaCl₂ molar ratio of 1.5. The shear stiffness of EICP-treated sands remains constant up to debonding stresses, and further loading induces the reduction of S-wave velocity. It was also found that the debonding stress at which stiffness loss occurs depends on the void ratio, not on cementation solution. Repeated loading-unloading deteriorates the bonding quality, thereby reducing the debonding stress. Scanning electron microscopy and X-ray images reveal that higher concentrations of CaCl₂ solution facilitate heterogeneous nucleation to form larger CaCO₃ nodules and 11-12 % of CaCO₃ forms at the interparticle contact as the main contributor to the evolution of shear stiffness.

• Korean Chemical Engineering Research
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• 제56권3호
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• pp.381-387
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• 2018

Our study focuses on upgrading real biogas obtained under Indian scenario using carbon capture and utilization (CCU) technology to remove carbon dioxide ($CO_2$) and utilize it by forming metal carbonate. Amines such as monoethanolamine (MEA), diethanolamine (DEA), and sodium hydroxide (NaOH) were used to rapidly convert gaseous $CO_2$ to aqueous $CO_2$, and $BaCl_2$ was used as an additive to react with the aqueous $CO_2$ and rapidly precipitating the aqueous $CO_2$. All experiments were conducted at $25^{\circ}C$ and 1 atm. We analyzed the characteristics of the $BaCO_3$ precipitates using X-ray diffractometry (XRD), scanning electron microscopy - Energy dispersive spectroscopy (SEM-EDS) and Fourier-transform infrared spectroscopy (FT-IR) analyses. The precipitates exhibited witherite morphology confirmed by the XRD results, and FT-IR confirmed that the metal salt formed was $BaCO_3$, and EDS showed that there were no traces of impurities present in it. The quantity of the $BaCO_3$ was larger when formed with DEA. Also, a comparison was done with a previous study of ours conducted in Korean conditions. Finally, we observed that the carbonate obtained using real biogas showed similar properties to carbonates available in the market. An economic analysis was done to show the cost effectiveness of the method employed by us.