• 한국광물학회:학술대회논문집
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• 한국광물학회.대한자원환경지질학회.대한광업진흥공사 2002년도 추계 공동 심포지엄 논문집: 국내 자원의 현황과 전망
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• pp.119-136
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• 2002

Contrasts in the style of the gold-silver mineralization in geologic and tectonic settings in Korea, together with radiometric age data, reflect the genetically different nature of hydrothermal activities, coinciding with the emplacement age and depth of Mesozoic magmatic activities. It represents a clear distinction between the plutonic settings of the Jurassic Daebo orogeny and the subvolcanic environments of the Cretaceous Bulgugsa igneous activities. During the Daebo igneous activities (c.a. 200-150 (?) Ma) coincident with orogenic time, gold mineralization took place between c.a. 195 and 135 (127 ?) Ma. The Jurassic Au deposits commonly show several characteristics; prominent association with pegmatites, low Ag/hu ratios in the ore-concentrating parts, massive vein morphology and a distinctively simple mineralogy including Fe-rich sphalerite, galena, chalcopyrite, arsenopyrite, Au-rich electrum, pyrrhotite and/or pyrite. During the Bulgugsa igneous activities $(110\~50Ma)$, the precious-metal deposits are generally characterized by such features as complex vein morphology, medium to high AE/AU ratios in the ore concentrates, and diversity of ore minerals including base-metal sulfides, pyrite, arsenopyrite, Ag-rich electrum and native silver nth Ag sulfides, Ag-Sb-As sulfosalts and Ag tellurides. Vein morphology, mineralogical, fluid inclusion and stable isotope results indicate the diverse genetic natures of hydrothermal systems in Korea. The Jurassic Au-dominant deposits (orogenic type) were formed at the relatively high temperature $(about\;300^{\circ}\;to\;450^{\circ}C)$ and deep-crustal level $(4.0{\pm}1.5\;kb)$ from the hydrothermal fluids containing more amounts of magmatic waters $(\delta\;^{18}O_{H2O}\;5\~10\%_{\circ})$. It can. It can be explained by the dominant ore-depositing mechanisms as $CO_2$ boiling and sulfidation, suggestive of hypo- to mesothermal environments. In contrast, the Cretaceous Au-dominant $(l13\~68\;Ma),\;Au-Ag \;(108\~47\;Ma)$ and Ag-dominant $(103\~45\;Ma)$ deposits, which correspond to volcanic-plutonic-related type, occurred at relatively low temperature $(about\;200^{\circ}\;to\;350^{\circ}C)$ and shallow-crustal level $(1.0\{pm}0.5\;kb)$ from the ore-forming fluids containing more amounts of less-evolved meteoric waters$(\delta\;^{18}O_{H2O}\;-10\~5\%_{\circ})$. These characteristics of the Cretaceous precious-metal deposits can be attributed to the complexities in the ore-precipitating mechanisms (mixing, boiling, cooling), suggestive of epi- to mesothermal environments. Therefore, the differences of the emplacement depth between the Daebo and the Bulgugsa igneous activities directly influence the unique temporal and spatial association of the deposit styles.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2009년도 특별 심포지엄
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• pp.57-65
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• 2009

Selection of good mineralized area is a combination of the integration of all the available geo-scientific (i.e., geological, geochemical, and geophysical) information, extrapolation of likely features from known mineralized terrenes and the ability to be predictive. The time-space relationships of the hydrothermal deposits in the East Asia are closely related to the changing plate motions. Also, two distinctive hydrothermal systems during Mesozoic occurred in Korea: the Jurassic/Early Cretaceous deep-level ones during the Daebo orogeny and the Late Cretaceous/Tertiary shallow geothermal ones during the Bulguksa event. Both the Mesozoic geothermal system and the mineralization document a close spatial and temporal relationship with syn- to post-tectonic magmatism. The Jurassic mineral deposits were formed at the relatively high temperature and deep-crustal level from the mineralizing fluids characterized by the relatively homogeneous and similar ranges of ${\delta}^{18}O$ values, suggesting that ore-forming fluids were principally derived from spatially associated Jurassic granitoid and related pegmatite. Most of the Jurassic auriferous deposits (ca. 165-145 Ma) show fluid characteristics typical of an orogenic-type gold deposits, and were probably generated in a compressional to transpressional regime caused by an orthogonal to oblique convergence of the Izanagi Plate into the East Asian continental margin. On the other hand, Late Cretaceous ferroalloy, base-metal and precious-metal deposits in the Taebaeksan, Okcheon and Gyeongsang basins occurred as vein, replacement, breccia-pipe, porphyry-style and skarn deposits. Diverse mineralization styles represent a spatial and temporal distinction between the proximal environment of sub-volcanic activity and the distal to transitional condition derived from volcanic environments. However, Cu (-Au) or Fe-Mo-W deposits are proximal to a magmatic source, whereas polymetallic or precious-metal deposits are more distal to transitional. Strike-slip faults and caldera-related fractures together with sub-volcanic activity are associated with major faults reactivated by a northward (oblique) to northwestward (orthogonal) convergence, and have played an important role in the formation of the Cretaceous Au-Ag lode deposits (ca. 110-45 Ma) under a continental arc setting. The temporal and spatial distinctions between the two typical Mesozoic deposit styles in Korea reflect a different thermal episodes (i.e., late orogenic and post-orogenic) and ore-forming fluids related to different depths of emplacement of magma (i.e., plutonic and sub-volcanic) due to regional changes in tectonic settings.

• 대한자원환경지질학회:학술대회논문집
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• 대한자원환경지질학회 2002년도 추계 공동 심포지엄 논문집
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• pp.119-136
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• 2002

Contrasts in the style of the gold-silver mineralization in geologic and tectonic settings in Korea, together with radiometric age data, reflect the genetically different nature of hydrothermal activities, coinciding with the emplacement age and depth of Mesozoic magmatic activities. It represents a clear distinction between the plutonic settings of the Jurassic Daebo orogeny and the subvolcanic environments of the Cretaceous Bulgugsa igneous activities. Dunng the Daebo igneous activities (c.a. 200～150 (\ulcorner) Ma) coincident with orogenic time, gold mineralization took place between c.a. 195 and 135 (127 \ulcorner) Ma. The Jurassic Au deposits commonly show several characteristics; prominent association with pegmatites, low Ag/Au ratios In the ore-concentrating parts, massive vein morphology and a distinctively simple mineralogy including Fe-rich sphalerite, galena, chalcopyrite, arsenopyrite, Au-rich electrum, pyrrhotite and/or pyrite. During the Bulgugsa igneous activities (110～50 Ma), the precious-metal deposits are generally characterized by such features as complex vein morphology, medium to high Ag/Au ratios in the ore concentrates, and diversity of ore minerals including base-metal sulfides, pyrite, arsenopyrite, Ag-rich eletrum and native silver with Ag sulfides, Ag-Sb-As sulfosalts and he tellurides. Vein morphology, mineralogical, fluid inclusion and stable isotope results indicate the diverse genetic natures of hydrothermal systems in Korea. The Jurassic Au-dominant deposits (orogenic type) were formed at the relatively high temperature (about 300$^{\circ}$ to 45$0^{\circ}C$) and deep-crustal level (4.0$\pm$1.5 kb) from the hydrothermal fluids containing more amounts of magmatic waters ($\delta$$^{18}$ $O_{H2O}$; 5～10$\textperthousand$). It can be explained by the dominant ore-depositing mechanisms as $CO_2$ boiling and sulfidation, suggestive of hypo- to mesothermal environments. In contrast, the Cretaceous Au-dominant (l13～68 Ma), Au-Ag (108～47 Ma) and AE-dominant (103～45 Ma) deposits, which correspond to volcanic-plutonic-related type, occurred at relatively low temperature (about 200$^{\circ}$ to 35$0^{\circ}C$) and shallow-crustal level (1.0$\pm$0.5 kb) from the ore-forming fluids containing more amounts of less-evolved meteonc waters ($\delta$$^{18}$ $O_{H2O}$;-10～5$\textperthousand$). These characteristics of the Cretaceous precious-metal deposits can be attributed to the complekities in the ore-precipitating mechanisms (mixing, boiling, cooling), suggestive of epi- to mesothermal environments. Therefore, the differences of the emplacement depth between the Daebo and the Bulgugsa igneous activities directly influence the unique temporal and spatial association of the deposit styles.les.

• 한국자동차공학회논문집
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• 제14권1호
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• pp.8-16
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• 2006

The research was conducted to characterize of Rh-Pd-Pt TWC with a double-layer washcoat for gasoline vehicle. The physical characteristics on surface of catalyst were inspected by BET, SEM and TEM. The characteristics of catalytic reaction were examined by the TPD/TPR and CO-pulse chemisorption. The catalyst $6Hx(0.35\times11\times3)$ showed superior conversion performance after hydrothermal aging process, which was due to small difference of the surface area between. the fresh and the aged catalyst. The CO-chemisorption and surface area were superior in the 600 cpsi catalyst than other catalysts, this catalyst also shown the higher conversion efficiency of the exhaust emissions. From the TPR test, the conversion performance of the aged catalyst was decreased by the agglomeration and sintering of the PM and metal oxides. From the TPD result, it was found that the NO chemisorption was happed on the bottom-layer washcoat with Pd, and the NO chemisorption was re-happened on the upper-layer washcoat with Pt and Rh in the desorption process.

• 열처리공학회지
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• 제16권2호
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• pp.90-96
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• 2003

The effect of betatizing temperature on microstructure and transformation characteristics in a Cu-AI-Ni based pseudoelastic alloy fabricated by heated mold continuous casting by using metallography, XRD and calorimetry. The microstructure of cast rod betatized at $600^{\circ}C$ revealed a ${\beta}_1$ parent phase and a ${\gamma}_2$ phase precipitated along the casting direction. When the cast rod was betatized at the elevated temperature above $600^{\circ}C$, the ${\gamma}_2$ phase is completely dissolved into the matrix so that the volume fraction of the ${\gamma}_2$ phase was decreased. The parent phase was stabilized by betatizing at $600^{\circ}C$. However, the ${\beta}_1$ parent phase was transformed to both ${{\beta}_1}^{\prime}$ and ${{\gamma}_1}^{\prime}$ martensites with increasing betatizing temperatures above $600^{\circ}C$, while $M_s$ and $A_s$ temperatures were decreased. The stress-strain curves for compression test were not same with betatizing temperature; the stress-strain curves of the specimen betatized at $600^{\circ}C$ and $700^{\circ}C$ were linear but those of the specimen betatized at $800^{\circ}C$ and $900^{\circ}C$ were not linear.

• 한국표면공학회지
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• 제51권5호
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• pp.332-336
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• 2018

Alkaline oxygen electrocatalysis, targeting anion exchange membrane alkaline-based metal-air batteries has become a subject of intensive investigation because of its advantages compared to its acidic counterparts in reaction kinetics and materials stability. However, significant breakthroughs in the design and synthesis of efficient oxygen reduction catalysts from earth-abundant elements instead of precious metals in alkaline media still remain in high demand. One of the most inexpensive alternatives is carbonaceous materials, which have attracted extensive attention either as catalyst supports or as metal-free cathode catalysts for oxygen reduction. Also, carbon composite materials have been recognized as the most promising because of their reasonable balance between catalytic activity, durability, and cost. In particular, heteroatom (e.g., N, B, S or P) doping on carbon materials can tune the electronic and geometric properties of carbon, providing more active sites and enhancing the interaction between carbon structure and active sites. Here, we focused on boron and nitrogen doped nanocarbon composit (BNC nanocarbon) catalysts synthesized by a solution plasma process using the simple precursor of pyridine and boric acid without further annealing process. Additionally, guidance for rational design and synthesis of alkaline ORR catalysts with improved activity is also presented.

• 멤브레인
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• 제34권3호
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• pp.163-171
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• 2024

환경오염을 제어하기 위한 청정에너지에 대한 수요 증가는 빠르게 증가하고 있습니다. 리튬 이온 배터리와 같은 충전식 배터리는 청정에너지의 우수한 원천이지만 높은 수요와 공급 불일치로 인해 리튬 금속이 빠르게 고갈되고 있습니다. 배터리 폐기물에서 귀금속을 회수하는 것은 환경오염 제어와 함께 가능한 해결책 중 하나입니다. 멤브레인 기반 분리 방법은 폐기물에서 리튬을 회수할 수 있는 매우 성공적인 상업적 공정입니다. 이 작업은 최근에 보고된 다양한 방법을 다룰 것이며 검토 형식으로 작성될 것입니다.

• 대한치과보철학회지
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• 제29권2호
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• pp.67-84
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• 1991

This study was carried out to investiagate the residual stress caused by the mismatch of thermal expansion and the bond failure resistance of alloy-porcelain specimens. The thermal expansions of alloys and porcelains were measured by using a straight push-rod dilatometer. Porcelain glass transition temperatures, thermal expansion coefficients, and thermal compatibility indices were derived from length-versus-temperature curves. Strain gauges were used to experimentally determine the Young's moduli of porcelains, the residual stresses of porcelain surface, and tensile bond strengths of the specimens of simulated porcelain metal crown. The obtained results were as follows: 1. The coefficients of thermal expansion for alloys were the minimum of $13.53\mu/^{\circ}C$ and the maximum of $20.11\mu/^{\circ}C$ in the range of $100\sim600^{\circ}C$ and those for porcelains were the minimum of $7.72\mu/^{\circ}C$ and the maximum of $31.24\mu/^{\circ}C$ in the range of $100\sim500^{\circ}C$. 2. The glass transition temperature of porcelains exhibited the same value without my relation to the healing rate, and the thermal disharmony of porcelain and alloy was more affected by porcelains than by the alloys. 3. The Young's moduli of body porcelains were larger than those of opaque porcelains(P<0.01) 4. It seemed that the residual stresses of porcelain surfaces in the porcelainalloy systems were more affected by porcelains than by alleys. 5. The bond strengths of the procelain-base metal alloy systems were larger than those of the porcelain-precious metal alloy systems. The fracture strengths of porcelain surfaces showed significant difference between porcelains (P<0.05).

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2003년도 가을 학술논문집
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• pp.117-123
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• 2003

지난 논문에 이어서 삼중수소 취급시설의 일부인 삼중수소 주입계통과 재생계통을 소개하였다. 두 계통은 모두 삼중수소의 유출이 가능한 계통들로서 GB안에 설치되어야 하는 계통들이다. 삼중수소 주입계통은 삼중수소 취급시설을 사용하여 목적하는 제품을 생산하게 되는 주 계통으로서 삼중수소의 관리를 위하여 정확히 삼중수소의 주입/분배량을 계량할 수 있어야 하고, 주입 후 계통내 잔여 삼중수소를 최대한 회수할 수 있도록 하여 방사성 물질의 환경방출을 최소화 할 뿐만 아니라 귀한 자원의 손실을 최소화하도록 설계되었다. MS, Ni catalyst bed, metal getter 등 재생이 필요한 TRS 내부의 장치들은 별도의 재생계통을 사용하여 재생한다. 다른 장치들의 재생은 장치를 가열하면서 적절한 purge gas를 흘려주는 비교적 간단한 방법으로 재생이 가능하나 삼중수소를 흡착한 metal getter의 삼중수소를 회수해야 하기 때문에 복잡한 공정을 거쳐야 한다.

• 디지털융복합연구
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• 제18권3호
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• pp.349-355
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• 2020

제4차 산업혁명이 대두되며 다양한 산업들의 기술들이 융·복합 되거나 클라우딩 컴퓨팅, 모바일, 빅테이터 등의 기술로 인해 인류의 삶이 물질적이나 정신적으로 크게 변화하고 있다. 다양한 기술과 이에 맞는 새로운 직업의 탄생은 전통금속공예기술에 대한 교육과 직업에 있어 대중의 외면을 가져오고 있다. 이런 변화에 있어 공예교육 또한 현 시대에 맞는 교육방식을 찾고 연구하며, 교육 현장에 적용해 대중의 관심과 부흥을 일으켜야 한다. 이를 위해 새로운 소재 혹은 기술이 도입된 타 산업의 교육현장 사례를 조사하고 전통금속공예기법 교육에 활용하고자 한다. 또한 3D프린팅 기술의 다양한 사례와 특징을 조사하고 시간과 공간, 자원의 제약이 많은 공예기법 교육에 활용하여 전통금속공예기법 교육에 새로운 변화를 주고자 한다.