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A Study on the recycling of sewage sludge cake using microwave drying (하수슬러지 케이크의 마이크로파 건조 후 재활용 연구)

  • Ha, Sang An;Yeom, Hae Kyong;You, Mi Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.3
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    • pp.77-84
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    • 2006
  • The objective of this research is to evaluate various reclamation methods of sewage sludge cake after treating with microwave under optimum conditions. In this study the sewage sludge cakes used from S and N wastewater treatment plants in the P city. Microwave with an induced electricity heating way was employed for dehydration of sewage sludge cake. Microwave operation conditions is 2,450 MHz of frequency and the power with 1 to 4 kW. This sewage sludge cake had a moisture content of 70%. The moisture content of the sludge decreased notable up to 2%(wt) resulted in breaking of cell wall. When the treated sewage sludge cake mixed with soils could be applied to use midterm and last cover material soils. Moreover, the adsorption ability of heavy metals such as copper, lead, chromium and cadmium was greatly enhanced by treated sewage sludge cake. Within 30 minutes, 1ppm of copper, chromium and cadmium and 10ppm of lead with 1g of the treated sewage sludge cake in $100m{\ell}$ were below detection. It was possible to use the treated sewage sludge cake as an absorbent for absorption of toxic heavy metals. Results from this research indicated that using of microwave radiation was an effective method for treating sewage sludge cake economically and environmental. A point of view of reclamation, the treated sewage sludge cake appeared to be feasible with an adsorption of heavy metals in steady of using expensive yellow earth.

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Sorptive Removal of Radionuclides (Cobalt, Strontium and Cesium) using AMP/IO-PAN Composites (AMP/IO-PAN 복합체를 이용한 방사성 핵종(코발트, 스트론튬, 세슘)의 흡착 제거)

  • Park, Younjin;Kim, Chorong;Shin, Won Sik;Choi, Sang-June
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.259-269
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    • 2013
  • Applicability of ammonium molybdophosphate/iron oxides-polyacrylonitrile (AMP/IO-PAN) composites on the removal of radionuclides in the radioactive wastewater generated from nuclear power plants was investigated. The composites were characterized using the following analytical techniques: X-ray diffraction (XRD), Fourior transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), particle size analyzer (PSA), nitrogen adsorption-desorption and magnetic property measurement system (MPMS). 10wt% of AMP/IO-PAN composite has a saturation magnetization of 2.038 emu/g. Single-solute sorptions of Co, Sr and Cs onto 10wt% of AMP/IO-PAN composite were investigated. The maximum sorption capacities ($Q^0$) predicted by the Langmuir model on 10wt% of AMP/IO-PAN composite were 0.097, 0.086 and 0.66 mmol/g for Co, Sr and Cs, respectively. The maximum sorption capacities ($Q^0$) of Cs predicted by Langmuir model on 0, 10, 20 and 30wt% of AMP/IO-PAN composites were 0.702, 0.655, 0.602 and 0.559 mmol/g, respectively. The maximum sorption capacities ($Q^0$) of Cs decreased with increasing the iron oxide content in the AMP/IO-PAN composites.

A Study of Frangibility of 9MM Bullet Related to Material Composition and Sinter Condition (합금 조성 및 소결 조건에 따른 9MM 탄자의 파쇄성에 관한 연구)

  • Kim, Bo-Ram;Seo, Jung-Hwa;Jung, Hee-Chur;Kim, Kyu-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.5
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    • pp.615-622
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    • 2020
  • Frangible bullets, which are shredded after impact on a target, reduce the possibility of both ricochet and unexpected injury in shooting training and in mission acts in dams, nuclear power plants, and cultural properties. Reducing the levels of hazardous materials in shooting ranges, such as lead, has become an important agenda for the government and environmental groups. In this study, the shape of a frangible bullet was designed for efficient shredding, and the safety and reliability were confirmed by actual firing under different process conditions. In addition, the physical characteristics, such as compaction pressure, density, and frangibility of each process, were compared by analyzing the microstructure of the sintered frangible bullet. The experiment revealed the smallest fragmentation after impact on the target under the following conditions: Cu-Sn 85:15; sintering temperature, 600℃; sintering time, one hour. Further development of the process conditions and experimental methods will contribute to the performance and environmental improvement of a frangible bullet.

Development of CANDU Spent Fuel Disposal Concepts for the Improvement of Disposal Efficiency (처분효율 향상을 위한 CANDU 사용후핵연료 처분개념 도출)

  • Lee, Jong-Youl;Cho, Dong-Geun;Kook, Dong-Hak;Lee, Min-Soo;Choi, Heui-Joo;Lee, Yang
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.4
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    • pp.229-236
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    • 2009
  • There are two types of spent fuels generated from nuclear power plants, CANDU type and PWR type. PWR spent fuels which include a lot of reusable material can be considered to be recycled. CANDU spent fuels are considered to directly disposed in deep geological formation, since they have little reusable material. In this study, based on the Korean Reference spent fuel disposal System(KRS) which is to dispose both PWR and CANDU spent fuels, the more effective CANDU spent fuel disposal systems have been developed. To do this, the disposal canister has been modified to hold the storage basket which can load 60 spent fuel bundles. From these modified disposal canisters, the disposal systems to meet the thermal requirement for which the temperature of the buffer materials should not be over $100^{\circ}C$ have been proposed. These new disposals have made it possible to introduce the concept of long tenn storage and retrievabililty and that of the two-layered disposal canister emplacement in one disposal hole. These disposal concepts have been compared and analyzed with the KRS CANDU spent fuel disposal system in terms of disposal effectiveness. New CANDU spent fuel disposal concepts obtained in this study seem to improve thermal effectiveness, U-density, disposal area, excavation volume, and closure material volume up to 30 - 40 %.

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Characteristics of the Co-Combustion of Coal and Bio-Solid Fuel using Biomass as an adjunct (석탄과 보조제로 바이오매스를 사용한 바이오 고형연료의 혼소 특성)

  • Hyeon, Wan-Su;Jin, Yong-Gyun;Jo, Eun-Ji;Han, Hyun-Goo;Min, Seon-Ung;Yeo, Woon-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.2
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    • pp.49-57
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    • 2020
  • Due to the sewage sludge's characteristics of high water content and low calorific value, it is hard to use sewage sludge as an energy source. In this study, we investigated production of bio-solid fuel which is mixed both sewage sludge and woody biomass in order to improve the sewage sludge's characteristics and replace fossil fuels. A thermogravimetric analysis was used to investigate the co-combustion characteristics of the mixed coal and bio-solid fuel of 5%, 10%, 15%, respectively. The analysis was carried out under non-isothermal conditions by raising the internal temperature of 25℃ to 900℃ with an increment of 10℃/min. In the case of comparing single coal sample and mixture sample of coal and bio-solid fuel, the initiation combustion temperature has slightly changed. However, both the maximum combustion temperature and the termination start combustion temperature were hardly noticeable. The initiation combustion was occurred between 200~315℃ and the thermal decomposition causing a significant weight change occurred between 350~700℃. As a result of the kinetic analysis of the co-combustion, the activation energy was decreased as the mixing rate was higher. Therefore, it is able to co-combust the mixed coal and bio-solid fuel in power plants.

A Study of the Korean Historical Development of Explosives Technology(Korean Traditional Explosive Technology) (화약기술발전의 사적고찰에 관한 연구 (한국의 고대 화약기술))

  • 나윤호;손선관
    • Journal of the Korean Professional Engineers Association
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    • v.12 no.1
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    • pp.12-20
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    • 1979
  • The early history of gun powder (black powder) and explosives was closely connected with the discovery of methods of preparing and purifing salpetre (potassium nitrate KNO$_3$). The Chineses apparently became acquainted with salpetre firstly on about 11th century, and they were possibly the original discoverers of salpetre for raw material of gun powder. The Egyptians called it “Chinese snow”, and it is significant that Chingis-Khan, the Mongol conqueror, took the Chinese eenginees with him in 1218 to use it for attacking the fortifications of the Persian cities. The black powder was invented by chance by Chinese alchemists during the Song dynasty (11th century) in the process of manufacturing medicine, and the powder was introduced to Europe by Mongol army. The manufacturing method of salpetre and gun powder was introduced to Korea from China in 1374, and the powder alld gunnery manufacturing project was developed by Mu Sun Choe(崔茂宣), the first Korean engineer late in Koryo dynasty. Coming in to Yi dynasty the explosive technic, extractive method of salpetre, and gunnery manufacturing process were developed greatly by Mu Sun Choe and Hai Sin Choe (崔海臣). However, confronting with the Japanes invasion at Imjin War (1597) with more powerful western style rifles which had been introduced from the Portuguese, on the contrary Korean army with the traditional guns couldn't compete with them. The Chochong(烏銃, the western rifle introduced in Japane) were much superior to the Chinese style traditional guns in the shooting power and striking efficiency. On the other hand, the Japanese battle ships armed only with the Chochong, when confronted with the Korean turtle shaped ships under the commanding of Admiral Yi Sun-Sin(李舞臣), were defeated by the Korean canons on the ships. The technical development of the modern powder industry in Korea. with the construction of four big explosive plants from 1930 to 1945, has resulted the mass-production of explosives. This study was purposed to investigate to the process with regard to the details of introduction to the explosive technology in Korea, and intended to give a help to the engineers who are engaged in study of the explosive technics by means of giving a spot light data on the early process of the designs, and making suggestion to the researchers for further study and invent a new and modern explosive.

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Influence of the Cr-Carbides on the Mechanical Characteristics during Isothermal Heat-Treatment of the Mod.9Cr-1Mo Steel (Mod.9Cr-1Mo강의 항온변태시 기계적 특성변화에 미치는 Cr탄화물의 영향)

  • Hur, Sung-Kang;Lee, Jae-Hyun;Gu, Ji-Ho;Shin, Kee-Sam;He, Yinsheng;Shin, Jong-Ho
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.46-53
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    • 2012
  • In this study, mechanical tests and microstructural analyses including TEM analyses with EDX of precipitates in modified 9Cr-1Mo steel were carried out to determine the cause of embrittlement observed after heat-treatment, which limits the usage of the alloy for power plants. Mod. 9Cr-1Mo steel specimens at austenite temperature were quenched to the molten salt baths at $760^{\circ}C$ and $700^{\circ}C$, in which the specimens were kept for 10 min ~ 10 hr with subsequent air-cooling. Impact tests showed that the impact value dropped abruptly when the specimens were kept longer than 30 min at $\sim760^{\circ}C$ reaching to minima in about 1 hr, and then increasing at further retention. The tensile strength of the specimens reached the minimum value without much change afterward, whereas the values of elongation showed the same trend as that of the impact value. The isothermally heat-treated steel at $700^{\circ}C$ also showed a minimum impact value in about 1 hr. These results suggest that the isothermal heattreatment at 760 and $700^{\circ}C$ for about 1 hr induces temporal embrittlement in Mod. 9Cr-1Mo steel. The microstructural examination of all the specimens with extraction replica of the carbides revealed that the specimens with temporal embrittlement had $Cr_2C$, indicating that the cause of the embrittlement was the precipitation of the $Cr_2C$. In addition, TEM/EDX results showed that the Fe/Cr ratio was 0.033 to 0.055 for $Cr_2C$, whereas it was 0.48 to 0.75 for $Cr_{23}C_6$, making the distinction of the $Cr_2C$ and $Cr_{23}C_6$ possible even without direct electron diffraction analyses.

Appropriateness of Location of Nuclear Accident Evacuation Shelters based on Population Characteristics and Accessibility -The Case of Busan Gijang-gun, Geumjeong-gu and Haeundae-gu in Korea- (인구특성과 접근성을 고려한 방사능재난 대피시설 입지 적정성 분석 -부산광역시 기장군, 금정구, 해운대구를 대상으로-)

  • DONG, Ah-Hyeon;LEE, Sang-Hyeok;KANG, Jung-Eun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.22 no.4
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    • pp.131-145
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    • 2019
  • Korea has set up a radiation emergency planning zone based on the 「Act on Physical Protection and Radiological Emergency」 to protect residents living near nuclear power plants in the event of nuclear disasters. Little research has been conducted on the appropriateness of existing nuclear evacuation facilities because of a general lack of interest in nuclear accidents. This research addresses this gap by analyzing the location adequacy of evacuation facilities in Busan's emergency protection planning area based on vulnerable populations and accessibility analyses. The Gijang-gun which has the greatest risk, shows that only 4.05% of the total urban area was included in the evacuation service area within 5 minutes while only 36.93% of Geumjeong-gu and 37.23% of Haeundae-gu were included in the evacuation-enabled area. In addition, evaluation facilities in the elderly population hotspots were lacking, and there was a wide gap between dongs within the same Gu. Thus, additional evacuation facilities need to be designated and installed considering the spatial equity between areas and safety of both the public and vulnerable populations.

Study on the Use of Bracketed Summations of the Peak Ground-motion Acceleration Per Second for Rapid Earthquake Alert Notifications (신속 지진피해통보를 위한 지반가속도의 초당 최대값 구간적산 방법의 활용에 관한 연구)

  • Yun, Kwan-Hee
    • Journal of the Earthquake Engineering Society of Korea
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    • v.16 no.1
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    • pp.37-45
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    • 2012
  • In an effort to further exploit the peak ground-motion acceleration (PGA) information per second available in real time by the enacted law, bracketed summations of the PGA per second ($BSPGA_k$) for 30 seconds based on the records with a rate of 100 samples were compared with the cumulative absolute velocity (CAV) and earthquake intensities based on a worldwide database of records from small-to-large earthquakes. The CAV, currently in use as an earthquake damage indicator for nuclear power plants due to its strong correlation with the earthquake intensity, has the disadvantage of requiring a massive amount of digital data with a rate of more than 100 samples per second. The comparative study shows that the $BSPGA_k$ is well correlated with the CAV over the wide range of strong ground-motion levels, which suggests that the $BSPGA_k$ is one of the new promising ground-motion parameters especially useful for rapid earthquake alert notifications through an earthquake monitoring network. Based on the domestic database of records from small-to-moderate earthquakes with felt reports, it is also observed that the $BSPGA_k$ is comparable to the CAV and better than the PGA in predicting the intensity by using the correlation relation.

Analysis of Characteristics of Seismic Source and Response Spectrum of Ground Motions from Recent Earthquake near the Backryoung Island (최근 백령도해역 발생지진의 지진원 및 응답스펙트럼 특성 분석)

  • Kim, Jun-Kyoung
    • Geophysics and Geophysical Exploration
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    • v.14 no.4
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    • pp.274-281
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    • 2011
  • We analysed ground motions form Mw 4.3 earthquake around Backryoung Island for the seismic source focal mechanism and horizontal response spectrum. Focal mechanism of the Backryoung Islands area was compared to existing principal stress orientation of the Korean Peninsula and horizontal response spectrum was also compared to those of the US NRC Regulatory Guide (1.60) and the Korean National Building Code. The ground motions of 3 stations, including vertical, radial, and tangential components for each station, were used for grid search method of moment tensor seismic source. The principal stress orientation from this study, ENE-WSW, is consistent fairly well with that of the Korean Peninsula. The horizontal response spectrum using 30 observed ground motions analysed and then were compared to both the seismic design response spectra (Reg Guide 1.60), applied to the domestic nuclear power plants, and the Korean Standard Design Response Spectrum for general structures and buildings (1997). Response spectrum of 30 horizontal ground motions were used for normalization with respect to the peak acceleration value of each ground motion. The results showed that the horizontal response spectrum revealed higher values for frequency bands above 3 Hz than Reg. Guide (1.60). The results were also compared to the Korean Standard Response Spectrum for the 3 different soil types and showed that the vertical response spectra revealed higher values for the frequency bands below 0.8 second than the Korean Standard Response Spectrum (SD soil condition). However, through the qualitative improvements and quantitative enhancement of the observed ground motions, the conservation of horizontal seismic design response spectrum should be considered more significantly for the higher frequency bands.