• Korean Journal of Metals and Materials
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• v.47 no.8
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• pp.488-493
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• 2009

Direct syntheses of bulk $Ti_3Al$ via electro-discharge-sintering (EDS) of a stoichiometric elemental powder mixture were investigated. A capacitor bank of $450{\mu}F$ was charged with three input energies, 0.5, 1.0, and 1.5 kJ. The charged capacitor bank was then instantaneously discharged through 0.3 g of a Ti-25.0 at.%Al powder mixture for consolidation. Complete phase transformation occurred in less than $200{\mu}sec$ by the discharge and a bulk $Ti_3Al$ compact was obtained. Compared with consolidated samples fabricated by conventional methods such as high vacuum sintering and casting, the electro-discharge-sintered $Ti_3Al$ compact shows a very fine microstructure with a hardness value of 425 Hv. Electro-discharge-sintering under a $N_2$ atmosphere successfully modified the surface Ti oxide of the $Ti_3Al$ compact into Ti nitride, which concurred with the synthesis and consolidation of $Ti_3Al$. Complete conversion yielding a single phase $Ti_3Al$ is primarily dominated by the fast solid state diffusion reaction.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.33 no.1
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• pp.19-33
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• 2023

Objectives: The purpose of this study is to systematically identify situations where exposure levels are expected to be high by structuring domestic lead measurement data according to exposure processes and activities. Methods: Occupational exposure data on lead was collected from the results of the Evaluation of Reliability of Working Environment Measurement conducted by the government from 2019 to 2020. Lead exposure characteristics were analyzed by PROC (process category) and activity. The Risk Characterization Ratios (RCRs) of five PROCs according to ventilation type and lead content were evaluated using the MEASE (Metal's EASE) model. Results: The exposure data on lead (n=250) was classified into 12 PROCs and 12 activities, with an average concentration of 0.040 mg/m³ and about 14% exceeding the occupational exposure limit of 0.05 mg/m³. Processes with high exposure levels were PROC 7 (industrial spraying), 23 (open processing and transfer operations of molten metal), 24 (mechanical treatment), 25 (welding), and 26 (handling of powder containing lead). The results of evaluating RCR for the five PROCs were greater than 1 or close to 1 even if local exhaust ventilation was used. Conclusions: There is a possibility that the concentration of exposure is high in the casting and tapping of molten metal containing lead, mechanical treatment such as fracturing and abrasion, handling of powder, spraying, battery manufacturing, and waste battery recycling processes. It is necessary to implement chemical management policies for workplaces with such processes.

• Composites Research
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• v.20 no.5
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• pp.49-55
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• 2007

Nanocomposite blade for dicing semiconductor wafer is investigated for micro/nano-device and micro/nano-fabrication. While metal blade has been used for dicing of silicon wafer, polymer composite blades are used for machining of quartz wafer in semiconductor and cellular phone industry in these days. Organic-inorganic material selection is important to provide the blade with machinability, electrical conductivity, strength, ductility and wear resistance. Maintaining constant thickness with micro-dimension during shaping is one of the important technologies fer machining micro/nano fabrication. In this study the fabrication of blade by wet processing of mixing conducting nano ceramic powder, abrasive powder phenol resin and polyimide has been investigated using an experimental approach in which the thickness differential as the primary design criterion. The effect of drying conduction and post pressure are investigated. As a result wet processing techniques reveal that reliable results are achievable with improved dimension tolerance.

• Journal of Korea Foundry Society
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• v.22 no.5
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• pp.265-270
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• 2002

A novel jewelry master pattern manufacturing process which reduce manufacturing steps by employing a Duraform rapid prototyping mold and a low melting alloy has been suggested. The novel process follows the steps of 'jewelry 3D CAD design ${\rightarrow}$ Durafrom RP mold ${\rightarrow}$ low melting alloy master pattern' while the previous process follows more complicated steps of 'jewelry idea sketch ${\rightarrow}$ detailed drawing ${\rightarrow}$ wax carving ${\rightarrow}$ flask ${\rightarrow}$ silver master pattern.' An upper and a lower part of molds have been manufactured of Duraform powder, of which melting point is $190^{\circ}C$. A maser pattern was manufactured by pouring a low melting alloy of Pb-Sn-Bi-Cd, so called Woods Metal, of which melting point is $70^{\circ}C$, into the mold. The master pattern is a shape of a disk of 20mm diameter that contains various design factors. The variations of dimensions, surface roughness, surface pore ratio were measured by an optical microscope, a surface roughness profilometer, and a Rockwell hardness tester. The pattern made of were maeasured by an optical microscope, a surface roughness profilometer, and a Rockwell hardness tester. The pattern made of low melting alloy has sufficient surface hardness, and surface pore ratio to be used as the jewelry master pattern.

• Journal of the Korean Ceramic Society
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• v.32 no.2
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• pp.189-196
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• 1995

Materials retaining electrolyte of a phosphoric acid fuel cell (PAFC) have been prepared with SiC powder to SiC whisker mixing ratios of 1:1, 1:2, 1:3, 1:4, 0:1 by a tape casting method. When 3wt% dispersant (sorbitan monooleate) is added to a matrix, the porosity of the matrix decreases a little while the bubble pressure and area of the matrix increase remarkably in comparison with no dispersant content. Effect of the electrolyte resistance and the polarization resistance on perfomance of a PAFC has been investigated using A.C. impedance spectroscopy. With the increase of whisker content, the electrolyte resistance decreases due to the increase of porosity and acid absorbancy, and the polarization resistance increases due to the increase of surface roughness. The polarization resistance affects current density predominantly at the higher potential than 0.7V becuase the polarization resistance is considrably larger than the electrolyte resistance. Both the electrolyte resistance and the polarization resistance affect current density near 0.7V of the fuel cell operating potential because they have similar values. The electrolyte resistance affects current density predominantly at the lower potential than the fuel cell operating potential because the electrolyte resistance is larger than the polarization resistance.

• Korean Journal of Materials Research
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• v.3 no.4
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• pp.381-387
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• 1993

The silicon oxynitride bonded $Si_3N_4-BN$ composite has been developed based on the selective oxidation behavier of $Si_3N_4$ over BN. The silicon oxynitride phase converted to the reaction between $Si_3N_4$ and $SiO_2$ formed on $Si_3N_4$ powder surface during oxidation treatment at the sintering temperature. The developed composite has excellent high-temperature strength, thermal shock resistance, precision machinability and corrosion resistance to the molten steel. The developed composite may therefore be used as, for example, break ring materials in continuous casting of steel.

• Journal of the Korean Ceramic Society
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• v.35 no.4
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• pp.355-363
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• 1998

The oxygen flux of SDC ($Sm_2O_3\;doped\;CeO_2$) solid electrolyte membranes with electronic and oxygen ion-ic conductivities has been investigated as a basic research in order to develop the conversion process of na-tural gas to syngas using the ceramic membrane reactor. Tube type membranes(1 mm thickness) were fa-bricated by slip casting of SDC powders prepared by the oxalate coprecipitaion method. Dense oxygen per-meation membranes(0.1 mm thickness) could be synthesized via sintering at $1450^{\circ}C$ for 2h and their re-lative density was over 95% The oxygen flux through SDC membranes doped 20mol% $Sm_15$ was about $1.13{\times}10^{-5}\;mol/m_2{\cdot}sec$ at low temperature around $800^{\circ}C$. In addition the SDC membranes showed a good thermaal stability for a long period of service.

• New & Renewable Energy
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• v.4 no.1
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• pp.11-18
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• 2008

In-situ lithiated NiO has been manufactured as a conventional cathode material of molten carbonate fuel cell (MCFC), however this material has a weakness for commercialization of MCFC because NiO is spontaneously dissolved into the electrolyte under MCFC operating conditions, resulting in short circuit between cathode and anode. In this research, therefore, $Co(OH)_2$-coated Ni powder was prepared by precipitation method with controlling pH at low temperature and atmospheric pressure. Modified cathode was fabricated by a conventional tape casting method and sintered at 700$^{\circ}C$ in a $H_2/N_2$ atmosphere, Based on characterization result, Pore size distribution and porosity was suitable for the cathode of MCFC. According to the result of dissolution, Ni solubility of modified cathode was 33% lower than that of conventional cathode. In addition, modified electrode showed a good performance from the single cell operation.

• New & Renewable Energy
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• v.3 no.1 s.9
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• pp.54-59
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• 2007

A sintering aid, $B_{2}O_{3}$ have been included into a $LiAlO_{2}$ electrolyte support by a tape casting method in order to reinforce mechanical strength of the support for molten carbonate fuel cells [MCFCs). Starting idea originates from the low melting point of $B_{2}O_{3}$ ($450^{\circ}C$), which can provide the low temperature consolidation of ceramic materials. The mechanical properties and the microstructure changes of the $B_{2}O_{3}$-included electrolyte support were examined by scanning electron microscope, mercury porosimetry, X-ray powder diffraction [XRD], high temperature differential scanning calorimeter and three-point bending strength measurement. The mechanical strength was clearly improved by addition of $B_{2}O_{3}$. The increase of mechanical strength results from the neck growth of a new $LiAlO_{2}$ phase between $LiAlO_{2}$ particles by the liquid phase sintering. Average pore size and porosity of the electrolyte support reinforced by addition of the sintering aid, $B_{2}O_{3}$, was $0.24{\mu}m$ and 59%, respectively which were suitable microstructure of a matrix for an application of MCFCs.

• Journal of Pharmaceutical Investigation
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• v.34 no.5
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• pp.363-368
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• 2004

In order to investigate the effect of bovine serum albumin (BSA), as a pore former, on the controlled release of an antibiotic from a biodegradable polymeric device, polycaprolactone (PCL)-cefadroxil matrices were prepared by the solvent casting method. The amount of cefadroxil released from various formulations at $37^{\circ}C$ was measured by HPLC. The duration of antimicrobial activity of matrices against S. aureus was evaluated by measuring the diameters of the inhibition zone. The morphology of the matrices was investigated by scanning electron microscopy (SEM). The release rate and extent of cefadroxil from PCL matrix increased as the loading dose and particle size of BSA/cefadroxil mixture powder increased. Cefadroxil released from the matrix exhibited antibacterial activity for up to 4 days. SEM of the cross-section of matrix showed the typical channel formation after 3 days of release study. Thus, a biodegradable polymeric matrix loaded with antibiotic/BSA mixture can effectively prevent bacterial infection on its surface, thereby bringing about an enhancement of biocompatibility of biomaterials.