• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.3
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• pp.96-102
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• 2022

Hydroxyapatite (HAp) was synthesized from calcium hydroxide (Ca(OH)₂) reacting with phosphoric acid (H₃PO₄) in aqueous solution. HAp powders were synthesized from extremely high concentration of precursor solutions over 3 M of Ca(OH)₂ aqueous suspension using modified process parameters such as phosphoric acid (H₃PO₄) pouring rate, aging time and post ball milling process. Regardless of phosphoric acid pouring rate, the DCPD (dicalcium phosphate dihydrate) was formed at room temperature and when heated above 700℃, β-TCP (tricalcium phosphate) was synthesized and the amount reached its maximum at 900℃. When the synthesized powder was sintered at 1150℃, β-TCP, a high temperature impurity phase, remained. The single HAp phase without DCPD was obtained from post ball-milled precipitates followed by 3 day aging. For the ball-milled precipitates even without the aging process, the desired single HAp phase without β-TCP could be obtained by heat treatment above 500℃. The post ball milling process provided a convenient route for HAp synthesis.

• Journal of the Korean Ceramic Society
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• v.42 no.6 s.277
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• pp.437-442
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• 2005

We fabricated BSCCO-2212 (2212) bulk superconductor by melt casting process, and evaluated the dependence of the critical properties on the temperature and cooling .ate of mold and the pouring methods of melt. It was observed that the critical current (Ic) of 2212 was significantly dependent on the pre-heating temperature of the mold. At the pre-heating temperature of $500^{\circ}C$ followed by air cooling condition, Ic of 48 A at 77 K was obtained which was higher than others processed at different temperatures. In addition, the Ic improved to 132 A when tilt casting method was applied. The improved Ic is probably due to the fact that the tilt casting reduced a turbulent flow of the melt during casting causing less porosity and more homogeneous microsructure. Critical temperature was measured to be 87-89 K after the first heat treatment and it improved to 90-91 K when subsequently heat treated at $650^{\circ}C$ in a nitrogen atmosphere. This improvement was considered to be due to an optimization of the oxygen content in the range of 8.16-8.2.

• International Journal of Highway Engineering
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• v.16 no.6
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• pp.95-104
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• 2014

PURPOSES : The purpose of this study is to evaluate the degree of restraint (DOR) of longitudinal steel at continuously reinforced concrete pavement (CRCP) against environmental loadings. METHODS : To measure the longitudinal steel strain, 3-electrical resistance and self-temperature compensation gauges were installed to CRCP test section (thickness = 250mm, steel ratio = 0.7%) and continuously measured 10 min. intervals during 259 days. In order to properly analyze the steel strains first, temperature compensation process has been conducted. Secondly, measured steel strains were divided into 12 phases with different events such as before paving, during concrete hardening, and after first cracking, etc. RESULTS : Thermal strain rate (TSR) concept is defined as the linear strain variations with temperature changes and restraints rate of longitudinal steel against environmental loadings (especially thermal loading) with different cases is defined as degree of restraint(DOR). New concept of DOR could be indirect indicator of crack width behaviors of CRCP. CONCLUSIONS : Before paving, DOR of longitudinal steel is almost same at the coefficient of thermal expansion of steel ($12.44m/m/^{\circ}C$) because of no restraint boundary condition. After concrete pouring, DOR is gradually changed into -1 due to concrete stiffness developing with hydration. After first cracking at crack induced area, values of DOR are around -3~-5. The negative DOR stands for the crack width behavior instead of steel strain behavior. During winter season, DOR reached to -5.77 as the highest, but spring this values gradually reduced as -1.7 as the lowest. Based on this observation, we can presume crack width decreased over time within the time frame of this study. This finding is not consistent with the current theory on crack width variations over time, so further study is necessary to identify the causes of crack width reducing. One of the reasons could be related to concrete stress re-distribution and stress relaxation.

• Journal of the East Asian Society of Dietary Life
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• v.20 no.6
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• pp.947-956
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• 2010

The purpose of this study was to synthesize tasty and healthy solomon's seal coffee by combining solomon's seal and a coffee-making process. Therefore, this study was carried out to establish the most suitable conditions for coffee-making by surface response surface methodology. Using the center synthesis method, we synthesized solomon's seal coffee by considering three factors (solomon's seal, coffee, and temperature) and three levels. The sixteen experimental items for solomon's seal coffee based on surface-reaction analysis were scent (crust break-scent when pouring water in solomon's seal coffee, flavorscent when tasting solomon's seal coffee), taste (clean-cup-pure taste without loose scent, sweetness, and acidity), mouth-feel, aftertaste, overall quality, and other taste degrees. Scores were from 1 to 7, with 7 indicating the highest preference. The optimum mixing rates which meet sensory items were coffee 19.51g, solomon's seal 2.07g, and temperature $93.39^{\circ}C$. Based on the above results, solomon's seal seems to be well suited for coffee. It was also found that solomon's seal has great potential to be well suited with other foods.

• International Journal of Highway Engineering
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• v.18 no.1
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• pp.13-21
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• 2016

PURPOSES : In this study, we analyzed the compressive strength characteristics of lean base concrete in relation to changes in the outdoor temperature after analyzing the cold and hot weather temperature standards and calculated the minimum and maximum temperatures when pouring concrete. We examined the rate of strength development of lean base concrete in relation to the temperature change and derived an appropriate analysis formula for FRC base structures by assigning the accumulated strength data and existing maturity formula. METHODS : We measured the strength changes at three curing temperatures (5, 20, and $35^{\circ}C$) by curing the concrete in a temperature range that covered the lowest temperature of the cold period, $5^{\circ}C$, to the highest temperature of the hot period, $35^{\circ}C$. We assigned the general lean concrete and FRC as test variables. A strength test was planned to measure the strength after 3, 5, 7, 14, and 28 days. RESULTS : According to the results of compressive strength tests of plain concrete and FRC in relation to curing temperature, the plain concrete had a compressive strength greater than 5 MPa at all curing temperatures on day 5 and satisfied the lean concrete standard. In the case of FRC, because the initial strength was substantially reduced as a result of a 30% substitution of fly ash, it did not satisfy the strength standard of 5 MPa when it was cured at $5^{\circ}C$ on day 7. In addition, because the fly ash in the FRC caused a Pozzolanic reaction with the progress into late age, the amount of strength development increased. In the case of a curing temperature of $20^{\circ}C$, the FRC strength was about 66% on day 3 compared with the plain concrete, but it is increased to about 77% on day 28. In the case of a curing temperature of $35^{\circ}C$, the FRC strength development rate was about 63% on day 3 compared with the plain concrete, but it increased to about 88% on day 28. CONCLUSIONS : We derived a strength analysis formula using the maturity temperatures with all the strength data and presented the point in time when it reached the base concrete standard, which was 5 MPa for each air temperature. We believe that our findings could be utilized as a reference in the construction of base concrete for a site during a cold or hot weather period.

• Journal of Korea Foundry Society
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• v.12 no.4
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• pp.305-316
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• 1992

Steel and iron castings made with expandable polystylene (referred to hereafter as EPS) patterns are often affected by distinctive defects associated with incomplete decomposition of the EPS as the molds are filled with metal. The effects of practical factors on carbon pick-up were investigated on the specimens, by taking successive layers of swarf and analysis, whereas the lustrous carbon is determined by using combustion analysis. The quality of the castings, with particular reference to carbon pick-up in low carbon steel and lustrous carbon on gray iron, is further influenced to a significant extent by such practical factors as reduced pressure, the pouring temperature, the density of EPS pattern, the additive in coating and in pattern and the casting thickness. The rate at which carbon pick-up and lustrous carbon deposites are formed can be reduced by reducing the density of the pattern and also reducing pressure, especially by adding $Na_2CO_3$ in coating and in pattern to promote $CO_2$ evolution. The upper parts of castings obtained using EPS patterns are slightly higher in carbon pick-up and in lustrous carbon than other parts.

• Journal of Korea Foundry Society
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• v.24 no.1
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• pp.34-39
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• 2004

The effects of casting condition and hot melt glue during Lost Foam Casting were investigated on the fluidity of Al alloy melt. The fluidity increased linearly with increasing pouring temperature in thick castings but non-linearly in thin casting due to the difference in main heat flow direction. The metal flow velocity was in range of $0.5{\sim}2.7$ cm/s in no evacuation condition and the minimum value of it was measured after the melt flow through the hot melt barrier. The mold evacuation improved the metal flow velocity by around $0.5{\sim}1$ cm/s. And the reaction zone layer thickness was about 1 cm in no-evacuation conditions but about 0.6 cm in mold evacuation condition of 710 torr due to the easier removal of pyrolsis product of EPS. And hot melt barrier thickness of 0.6 mm increased the reaction zone layer thickness up to about 2.5 cm. The fluidity decreased remarkably with an enlarged thickness of hot melt due to a lot of pyrolysis products.

• Journal of Korea Foundry Society
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• v.20 no.5
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• pp.290-299
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• 2000

A three-dimensional model was developed in order to simulate heat and fluid flow of a continuous casting billet. The model was coded with the general-purpose CFD program FIDAP, using the finite element method. The present model consists of 2 individual calculation schemes, named model 1 and model 2. Mold region only was calculated to check the pouring stream through submerged nozzle with model 1. Entire region, which consists of mold, secondary cooling, radiation cooling was calculated to predict crater end position, temperature profile and solid shell profile(model 2). Standard $k-{\bullet}\hat{A}$ turbulence model has been applied to simulate the turbulent flow induced by submerged nozzle. Enthalpy method was adopted for the latent heat of solidification. Fluid flow in mushy zone was treated using variable viscosity approach. The more casting speed and superheat increased, the more metallurgical length increased. The shell thickness at the mold exit is proved to be mainly controlled by superheat by the present simulation. It may be concluded that the present model can be successfully applied far the prediction of heat and fluid flow behavior in the continuous casting process.

• Journal of Korea Foundry Society
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• v.25 no.4
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• pp.156-160
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• 2005

There are many factors that influence solidification behavior during continuous casting, e.g. include superheat, casting speed, cooling rate and holding time. However, when melt is stirred by electromagnetic force, there would be some changes in its solidification behavior compared to that of the ordinary casting process. In this study, the billets of A356 alloy with a diameter of 3 inch were fabricated with electromagnetic stirring under various conditions of superheat, casting speed and input voltage of electro magnetic stirring (EMS) device. The microstructure was also investigated under the various casting conditions and electromagnetic input voltages. When increase in input voltage, the microstructure was changed from dendritic to rosette type and finally to spheroidal. With pouring temperature, casting speed and electromagnetic input voltage were $650^{\circ}C$, 100 mm/min and 140 V, respectively, the billet with a diameter of 3 inch, which has a uniform dispersed spheroidal particles in the whole area of billet except for the surface area, was manufactured.

• Journal of Korea Foundry Society
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• v.37 no.6
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• pp.186-192
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• 2017

The lost foam casting method was used to fabricate Al-Si alloy thin sheet specimens; the effects of chemical composition and process variables on the mold filling and mechanical properties were investigated. The mold filling capability was observed to be proportional to the pouring temperature, and both the vibration imposed during the casting and the application of a pattern coating had rather negative effects. The mold filling capability also decreased with the addition of Mg or TiB. When the Mg content increased, the tensile strength of the cast alloy was enhanced, but the elongation decreased. However, after T6 heat treatment, both the strength and the elongation were improved. TiB addition for grain refining or pattern coating did not significantly affect the tensile properties.