• 한국신재생에너지학회:학술대회논문집
• /
• 2005.11a
• /
• pp.634-637
• /
• 2005

Hydrogen adsorption mechanism onto the porous metal-organic frameworks (MOFs) has been studied by density functional theory calculation. The selected functionals for the predict ion of interact ion energies between hydrogen and potential adsorption sites of MOF was utilized after the evaluation with the various functionals for interaction energy of $H_2C_6H_6$ model system the adsorption energy of hydrogen molecule into MOF was investigated with the consideration of the favorable adsorption sites and the orientations. We also calculated the second favorable adsorption sites by geometry optimization using every combination of two first absorbed hydrogen molecules. Based on the calculation of first and second adsorption sites and energies, the hydrogen adsorption into MOF follows a cooperative mechanism in which the initial metal sites initiate the propagation of the hydrogen adsorption on the whole frameworks. In addition, it was found that the interaction strength between the simple benzene ring with hydrogen is significantly reinforced when the benzene ring has been incorporated into the framework of MOFs.

• Journal of Powder Materials
• /
• v.3 no.2
• /
• pp.104-111
• /
• 1996

In order to obtain homogeneous and high quality products in powder compaction forging process, it is very important to control stress, strain, density and density distributions. Therefore, it is necessary to understand quantitatively the elasto-plastic deformation and densification behaviors of porous metals and metal powders. In this study, elasto-plastic finite element method using Lee-Kim's pressure dependent porous material yield function has been used for the analysis of three dimensional indenting process. The analysis predicts deformed geometry, stress, strain and density distribution and load. The calculated load is in good agreement with experimental one. The calculated results do not show axisymmetric distributions because of the edge effect. The core part which is in contact with the indentor and the outer diagonal edge part are in compressive stress states and the middle part is in tensile stress state. As a results, it can be concluded that three dimensional analysis is more realistic than axisymmetric assumption approach.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2002.05a
• /
• pp.35-41
• /
• 2002

Dense oxygen ionic conducting materials can be used for oxygen separation membranes at high temperatures. However, they show relatively low permeation flux because of their large resistances. To reduce resistances and improve the oxygen permeation flux, thin dense yttria-stabilized-zirconia (YSZ)/Pd composite dual-phase membranes were fabricated by a new approach that combines the reservoir method and chemical vapor deposition (CVD). A thin porous YSZ layer was coated on a porous alumina support by dip-coating the YSZ suspension. A continuous Pd phase was formed inside pores of the YSZ layer by the reservoir method. The residual pores of the YSZ/Pd layer were plugged with yttria/zirconia by CVD to ensure the gas tightness of the membranes. The oxygen permeation fluxes through these composite membrane were 2.0$\times$10$^{-8}$ mol/cm$^2$.s and 4.8$\times$10$^{-8}$ mol/cm$^2$.s at 105$0^{\circ}C$ when air and oxygen were used as the permeate gases, respectively. These oxygen permeation values are about 1 order of magnitude higher than those of pure YSZ membranes prepared under similar conditions.

• Proceedings of the SAREK Conference
• /
• 2009.06a
• /
• pp.774-779
• /
• 2009

The purpose of this research is to develop the high performance of solar chemical reactor for producing hydrogen by methane reforming reaction with steam. Two shape of chemical reactor is suggested: first type is filled with porous material and second type is spiral type. These reactors is installed on the dish-type thermal system of Inha University, Inha Dish-1. Performance analysis of these two reactors is conducted from getting methane conversion.

• Journal of the Korean Ceramic Society
• /
• v.39 no.4
• /
• pp.336-340
• /
• 2002

Pure and nano-sized $TiO_2$ and $CaTiO_3$ powders were fabricated by a polymeric steric entrapment route and planetary milling process. An ethylene glycol was used as a polymeric carrier for the preparation of organic-inorganic precursors. Titanium isopropoxide and calcium nitrate were dissolved in liquid-type ethylene glycol without any precipitation. At the optimum amount of the polymer, the metal cations were dispersed in solution and a homogeneous polymeric network was formed. The dried precursor ceramic gels were turned to porous powders through calcination process. The porous powders were crystallized at low temperatures and the crystalline powders were planetary milled to nano size.

• Advances in nano research
• /
• v.7 no.5
• /
• pp.325-335
• /
• 2019

In the present study, nonlocal strain gradient theory (NSGT) is developed for wave propagation of functionally graded (FG) nanoscale plate in the thermal environment by considering the porosity effect. $Si_3N_4$ as ceramic phase and SUS304 as metal phase are regarded to be constitutive material of FG nanoplate. The porosity effect is taken into account on the basis of the newly extended method which considers coupling influence between Young's modulus and mass density. The motion relation is derived by applying Hamilton's principle. NSGT is implemented in order to account for small size effect. Wave frequency and phase velocity are obtained by solving the problem via an analytical method. The effects of different parameters such as porosity coefficient, gradient index, wave number, scale factor and temperature change on phase velocity and wave frequency of FG porous nanoplate have been examined and been presented in a group of illustrations.

• Coupled systems mechanics
• /
• v.13 no.4
• /
• pp.337-357
• /
• 2024

This paper studies, the analysis of nonlinear thermal vibration of fluid-infiltrated FG nanobeam with voids. The effect of nonlinear thermal in a FG ceramic-metal nanobeam is determined using Murnaghan's model. Here the influence of fluids in the pores is investigated using the Skempton coefficient. Hamilton's principle is used to find the equation of motion of functionally graded nanobeam with the effect of refined higher-order state space strain gradient theory (SSSGT). Numerical solutions of the FG nanobeam are employed using Navier's solution. These solutions are validated against the impact of various parameters, including imperfection ratio, fluid viscosity, fluid velocity, amplitude, and piezoelectric strain, on the behavior of the fluid-infiltrated porous FG nanobeam.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.5
• /
• pp.639-646
• /
• 2004

Metal treated activated carbons are prepared using various metals. Adsorption behaviors, morphologies, as well as antibacterial effects of metal treated samples are compared before and after solvent washing. Adsorption isotherms are used to characterize the porous structure of metal treated activated carbons before and after the solvent washing with acetone or ethyl alcohol. From these data, it is noticed that the changes in physicochemical properties of metal treated activated carbons depend on the solvents employed. Similar results are observed from BET data obtained from nitrogen adsorption isotherms. From scanning electron microscopy (SEM) studies, the changes in shape and size of metal particles are observed after the samples are washed with solvents. These changes result in different blocking effects, which, in turn, affect the adsorption behavior of metal treated activated carbons. X-ray diffraction (XRD) patterns of the samples treated with different metals are different each other. High intense sharp peaks attributed to metals are observed from silver treated samples, while the peaks are not observed from copper treated samples. To compare thermodynamic behavior of metal treated activated carbons washed with different type of solvents, differential scanning calorimetric (DSC) analysis is carried out. The analysis shows similar endothermic curves for all of the samples. Finally, antibacterial effects of metal treated activated carbon against Escherichia coli are discussed. Comparing the effects among the metals employed, highest effects are obtained from Cd, while lowest effects are obtained from Cu. Antibacterial activity becomes higher with the increase of the amount of metals treated, Optimum concentrations of metals to treat activated carbons, obtained from a shake flask test, are known to be 0.4, 0.1, and 0.6 moles for Ag, Cd, and Cu, respectively.

• Applied Chemistry for Engineering
• /
• v.26 no.3
• /
• pp.239-246
• /
• 2015

The hybridization of carbon nano-materials enhances the efficiency of each function of the resulting structure or composites. Also, the addition of non-carbon elements to nanomaterials modifies the electrochemical properties. Electrodes combining porous carbon nanofibers (CNFs) and metal oxides benefit from the combination of the double-layer capacitance of the CNFs and the pseudocapacitive character associated with the surface redox-type reactions. Consequently, they demonstrate superior supercapacitor performance in terms of high capacitance, high energy/power efficiency and high rate capability. This paper presents a comprehensive review of the latest advances made in the development and application of various metal oxide/CNF composites (CNFCs) to supercapacitor electrodes.

• Nuclear Engineering and Technology
• /
• v.41 no.8
• /
• pp.1101-1108
• /
• 2009

The ocean contains around eighty elements of the periodic table and uranium is also one among them, with a uniform concentration of 3.3 ppb and a relative abundance factor of 23. With a large coastline, India has a large stake in exploiting the 4 billion tonnes of uranium locked in seawater. The development of radiation grafting techniques, which are useful in incorporating the required functional groups, has led to more efficient adsorbent preparations in various geometrical configurations. Separation based on a polymeric adsorbent is becoming an increasingly popular technique for the extraction of trace heavy metals from seawater. Radiation grafting has provided definite advantages over chemical grafting. Studies related to thermally bonded non woven porous polypropylene fiber sheet substrate characterization and parameters to incorporate specific groups such as acrylonitrile (AN) into polymer back bones have been investigated. The grafted polyacrylonitrile chains were chemically modified to convert acrylonitrile group into an amidoxime group, a chelating group responsible for heavy metal uptake from seawater/brine. The present work has been undertaken to concentrate heavy metal ions from lean solutions from constant potential sources only. A scheme was designed and developed for investigation of the recovery of heavy metal ions such as uranium and vanadium from seawater.