• Title/Summary/Keyword: porous ceramics

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Nanocomposites for microelectronic packaging

  • Lee, Sang-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.99.1-99.1
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    • 2016
  • The materials for an electronic packaging provide diverse important functions including electrical contact to transfer signals from devices, isolation to protect from the environment and a path for heat conduction away from the devices. The packaging materials composed of metals, ceramics, polymers or combinations are crucial to the device operating properly and reliably. The demand of effective charge and heat transfer continuous to be challenge for the high-speed and high-power devices. Nanomaterials including graphene, carbon nanotube and boron nitride, have been designed for the purpose of exploiting the high thermal, electrical and mechanical properties by combining in the matrix of metal or polymer. In addition, considering the inherent electrical and surface properties of graphene, it is expected that graphene would be a good candidate for the surface layer of a template in the electroforming process. In this talk, I will present recent our on-going works in nanomaterials for microelectronic packaging: 1) porous graphene/Cu for heat dissipations, 2) carbon-metal composites for interconnects and 3) nanomaterials-epoxy composites as a thermal interface materials for electronic packaging.

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Synthesis of Ultra-long Hollow Chalcogenide Nanofibers

  • Jwa, Yong-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.3.1-3.1
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    • 2011
  • Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

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Fabrication of Porous Ceramics for Microorganism Carrier by Hydrothermal Reaction (수열반응을 이용한 미생물 담체용 다공성 세라믹스의 제조)

  • 정승화;양성구;강종봉;조범래
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.192-192
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    • 2003
  • 오염된 폐수를 처리하는 과정으로 다양한 방법이 사용되고 있으나, 담체를 이용하여 미생물을 배양하고, 미생물에 의해 정수하는 방법이 이용되고 있다. 이를 위해서는 미생물을 배양을 위한 담체의 조건으로 다양한 크기의 연속기공을 갖고, 젖음성과 표면거칠기가 높으며, 이들 중 초기 미생물번식의 조건을 제공하는 기체 포집용 미세기공을 보유하고, 미생물이 성장할 수 있는 수백 $\mu\textrm{m}$까지의 다양한 크기의 연속된 기공을 갖는 미생물 담체용 다공성 세라믹스의 제조를 목적으로 본 연구를 행하였다. 본 연구는 다양한 크기의 기공분포를 형성하기 위하여 첨가물로 activated carbon과 무기염, 고분자 binder를 활성알루미나 기지재료에 사용하여 수열반응에 의해 각각의 물질이 형성할 수 있는 기공의 크기를 확인하고, 수 nm에서 수백 $\mu\textrm{m}$까지의 연속된 기공이 존재하는 담체를 제조하였다. 수열조건과 첨가물의 양에 따라 수은침투가압을 이용하여 기공의 크기와 분포를 측정하고 평균기공률을 얻을 수 있었고, 압축강도를 측정하고, 기공의 형상을 주사전자현미경을 통해 확인하였다.

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An Investigation on Combustion Characteristics of Hydrogen-Air Premixture in a Sub-millimeter Scale Catalytic Combustor using Infrared Thermography (적외선 열화성 온도 측정법을 이용하여 살펴본 서브밀리미터 스케일 촉매 연소기에서의 수소-공기 예혼합 가스의 촉매 연소 특성)

  • Choi, Won-Young;Kwon, Se-Jin
    • Journal of the Korean Society of Combustion
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    • v.10 no.3
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    • pp.17-24
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    • 2005
  • A sub-millimeter scale catalytic combustor with a simple plate-shaped combustion chamber was fabricated. A porous ceramics support coated with platinum catalyst was placed in the chamber. The combustor has a gallium arsenide window on the top that is transparent to infrared ray. The temperature distribution in the combustion chamber was measured using infrared thermal imager while hydrogen-air premixture is steadily supplied to the combustor. The area where the catalytic reaction took place broaden for higher flow rate and lower equivalence ratio made activated area in the combustion chamber broaden. The amount of coated platinum catalyst did not affect the reaction. Stop of reaction, which is similar to flame quenching of conventional combustion, was investigated. Large content of heat generation and broad activated area are essential criteria to prevent stop of reaction that has a bad effect on the combustor performance.

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Physical Characteristics of ALC Controlled by Particle Size and Contents of Raw Materials (원료의 입도 및 함량제어에 따른 ALC의 물성 변화)

  • Jeong, Eui-Jong;Chu, Yong-Sik;Lee, Jong-Kyu;Song, Hun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.367-368
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    • 2009
  • High-rise building in modern society is becoming increasingly necessary to reduce the weight of the building. Accordingly, increased use of lightweight bubble concrete is a trend Porous ceramics (ALC) is the most common, lightweight bubble concrete. And it is by lightweight blocks the same used as building materials. This research is related to the physical characteristics of ALC controlled by particle size and contents of raw materials.

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Nanocomposite Ni-CGO Synthesized by the Citric Method as a Substrate for Thin-film IT-SOFC

  • Wang, Zhenwei;Liu, Yu;Hashimoto, Shin-ichi;Mori, Masashi
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.782-787
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    • 2008
  • Ni-ceria cermets have been extensively investigated as candidates for the anode in intermediate-temperature solid oxide fuel cells. We have used the citric method to synthesize nanocomposite powders consisting of NiO (Ni metal content: $40{\sim}60%$ by volume) highly dispersed in $Ce_{0.9}Gd_{0.1}O_{1.95}$ (CGO). The microstructure characteristics and sintering behaviors of the nanocomposites were investigated. No impurity phases were observed and the shrinkage of these substrates matched well with that of a CGO electrolyte with a specific surface area of $11\;m^2/g$. Densification of the CGO electrolyte layer to $<5\;{\mu}m$ thickness was achieved by co-firing the laminated electrolyte with the porous NiO-CGO substrate at $1400^{\circ}C$ for 6 h.

State-of-the-art of the multi-scale analysis of advanced composite materials by homogenization method (일본내 연구동향 (6편중 제4편))

  • Takano, Naoki
    • Composites Research
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    • v.15 no.5
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    • pp.44-52
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    • 2002
  • To study numerically the mechanical behaviors of advanced composite materials considering the microscopic phenomena as well as the macroscopic properties and behaviors, a multi-scale modeling and analysis by the mathematical homogenization method with the help of the finite element method(FEM) are reviewed. The hierarchical modeling strategy and the formulation are briefly described first to give some idea of the multi-scale framework. The latter half of this article focuses on the verification of the multi-scale analysis by the homogenization method in its applications to real advanced materials. The first example is the verification of the predicted macroscopic(homogenized) properties based on the microstructure of porous ceramics. In spite of the complexity of the random microstructure, the error between the predicted and the measured values was only 1%. Next, two applications to the process simulation of fiber reinforced polymer matrix composites are presented. The permeability characteristics are evaluated for sheared weave fabrics for resin transfer molding(RTM) simulation, and the thermoforming of FRTP sheet is analyzed considering the large deformation of the knit structure during the deep-draw forming was verified by comparison with the experimental results.

Synthesis and Conductivity Properties of $LaNiO_3$ Ceramic Conductors ($LaNiO_3$전도성 세라믹의 합성과 도전특성)

  • Cho, Jung-Ho;Cho, Joo-Hun;Kim, Kang-Eun;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.406-409
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    • 2001
  • The conductivity properties and synthesis of $LaNiO_{3}$ ceramics from $La_{1+\delta}NiO_{3}(\delta=-0.06,0,0.06)$ were investigated. A single perovskite phase was realized at $800^{\circ}C$. $La_{2}NiO_{4}$ and other unexpected oxide were observed at $1000^{\circ}C$. The Microstructure was showed clearly that it is a low density porous material. $LaNiO_3$ ceramic showed a metallic conductivity. The conductivity of La rich samples had a higher value than the La poor samples.

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Manufacturing Characteristics of Wood ceramics from Thinned Small Logs (I) - Resin Impregnation Rate and Bending Strength -

  • Oh, Seung-Won;Hirose, Takashi;Okabe, Toshihiro
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.4
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    • pp.51-55
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    • 2000
  • The woodceramics which are new porous carbon materials were obtained by carbonizing from thinned small log of Aomori HIBA (Thujopsis dolabrata S. et. Z. var. hondae M.) impregnated with phenol resin in a vacuum furnace. During the carbonization process, the resin changes into glassy carbon, which has superior property. The resin impregnation rate and bending strength depend on the types of board and density. In this paper, the manufacturing method of woodceramics made from thinned small logs of Aomori HIBA was introduced and some properties were examined.

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Electrical Properties of $Ba_{1-x}Sr_xTiO_3$ Thin Films Deposited by Metalorganic Chemical Vapor Deposition

  • Yoon, Jong-Guk;Yoon, Soon-Gil;Lee, Won-Jea
    • The Korean Journal of Ceramics
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    • v.1 no.4
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    • pp.204-208
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    • 1995
  • The microstructure and electrical propetries were investigated for polycrystalline $Ba^{1-x}Sr_xTiO_3$(BST) thin films deposited on Pt/Ti/$SiO_2$(PTSS) and Pt/MgO(PM) substrates by metalorganic chemical vapor deposition (MOCVD). BST films on PTSS have coulmnar and porous structures, while on PM have an equiaxied and dense structure. The dielectric constant and a dissipation factor of BST films on PTSS and 20 fC/$\mu \textrm{cm}^3$ on PTSS and 12fC/$\mu \textrm{cm}^2$ on PM was obtained at an applied electric field of 0.06 MV/cm. Leakage current density of BST films on PM was smaller than that on PTSS. The leakage current density level was about $8\times10^{-8}A/\textrm{cm}^2$ at 0.04MV/cm.

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