• International Journal of Naval Architecture and Ocean Engineering
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• 제10권5호
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• pp.644-650
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• 2018

The paper provides some developments of a numerical approach ("Numerical Calculation of Flow Within Armour Units", FWAU) to the design of rubble mound breakwaters. The hydrodynamics of wave induced flow within the interstices of concrete blocks is simulated by making use of advanced, but well tested, CFD techniques to integrate RANS equations. While computationally very heavy, FWAU is gaining ground, due to its obvious advantages over the "porous media", i.e. the possibility of accounting for the highly non stationary effects, the reduced need of ad hoc calibration of filtration parameters and also - in perspective - the evaluation of hydrodynamic forces on single blocks. FWAU however is a complex technique, and in order to turn it into a practical design tool, a number of difficulties have to be overcome. The paper presents recent results about this validation, as well as insight into fluid dynamical aspects.

• 한국구조물진단유지관리공학회 논문집
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• 제22권1호
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• pp.40-47
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• 2018

다공성 보도 블록은 이미 많이 사용되지만, 큰 침투성으로 인해 블록의 강도를 감소시키고, 균열 및 침전의 문제를 만든다. 본 연구에서는 최소 주응력의 결정된 위치를 설계하고 검증하기 위하여, 이동하는 체중하중에 대한 보행로 블록에서의 최소 주응력의 위치를 결정함으로써, 주어진 문제에 대한 최적해를 제시하였다. 최소 주응력의 결정된 위치에 대한 검증 예를, 내부에 빗물을 저장하기위한 통행보도의 탄성 기초상의 2 차원 블록 부재에 대하여 제시하였다. 전단력의 합력에 대한 최소값은 ${\times}1$이 58.58 mm(전체 스팬의 30%, 200 mm)일 때, 최소 변형은 ${\times}2=80mm$(전체 스팬의 70%, 200 mm)에 있다. 수정 된 모델에서, 이동하는 경계 조건(보도 보행 하중)이 ${\times}1$(= 0 mm)에 있을 때, 168 mm (스팬의 84%, 200 mm)에서 최소 주응력의 위치가 발견되었으며, 스프링으로 모델링 된 기초의 응답에 대하여 모델링하였다. 결과적으로, 중립 축(${\times}2=167mm$)에서의 빗물저장을 위한 보도블럭의 "0"변형 위치가 3 차원 FEM 분석 검증을 통하여 결정되었다.

• Journal of Periodontal and Implant Science
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• 제50권2호
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• pp.106-120
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• 2020

Purpose: A new form of porous polyethylene, characterized by higher porosity and pore interconnectivity, was developed for use as a tissue-integrated implant. This study evaluated the effectiveness of porous polyethylene blocks used as an onlay bone graft in rabbit mandible in terms of tissue reaction, bone ingrowth, fibrovascularization, and graft-bone interfacial integrity. Methods: Twelve New Zealand white rabbits were randomized into 3 treatment groups according to the study period (4, 12, or 24 weeks). Cylindrical specimens measuring 5 mm in diameter and 4.5 mm in thickness were placed directly on the body of the mandible without bone bed decortication, fixed in place with a titanium screw, and covered with a collagen membrane. Histologic and histomorphometric analyses were done using hematoxylin and eosin-stained bone slices. Interfacial shear strength was tested to quantify graft-bone interfacial integrity. Results: The porous polyethylene graft was observed to integrate with the mandibular bone and exhibited tissue-bridge connections. At all postoperative time points, it was noted that the host tissues had grown deep into the pores of the porous polyethylene in the direction from the interface to the center of the graft. Both fibrovascular tissue and bone were found within the pores, but most bone ingrowth was observed at the graft-mandibular bone interface. Bone ingrowth depth and interfacial shear strength were in the range of 2.76-3.89 mm and 1.11-1.43 MPa, respectively. No significant differences among post-implantation time points were found for tissue ingrowth percentage and interfacial shear strength (P>0.05). Conclusions: Within the limits of the study, the present study revealed that the new porous polyethylene did not provoke any adverse systemic reactions. The material promoted fibrovascularization and displayed osteoconductive and osteogenic properties within and outside the contact interface. Stable interfacial integration between the graft and bone also took place.

• Korean Chemical Engineering Research
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• 제56권3호
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• pp.404-409
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• 2018

나노사이즈의 유기물과 무기물을 조합하여 계층적인 크기의 기공을 가지는 촉매의 개발은 서로 다른 특징을 갖는 물질의 구조제어를 통한 반응물의 이동 통로를 만들어 주어 다양한 촉매에 적용 될 수 있다. 본 연구에서는 계층적 크기의 기공을 가지기 때문에 PET 글리콜리시스에서 우수한 촉매 활성을 보일 수 있는 코발트 옥사이드/그래핀 3D 젤을 수열합성법에 의하여 제조하였다. 코발트 옥사이드와 그래핀 시트의 상호작용에 의하여 3D 젤을 얻었고, 다양한 크기의 기공 구조는 넓은 활성 면적을 주어 코발트 옥사이드의 효과적인 촉매반응을 가능하게 하였다. 촉매로 사용하였을 때 코발트와 그래핀의 시너지 효과는 제조한 물질의 구조적 장점을 가지도록 하였고, 제조한 물질을 PET 분해반응의 BHET의 높은 전환률(97.5%), 빠른 PET 분해속도(94.5%, 60 min), 반응 안정성(93.1%, 18회 재사용) 등 우수한 촉매 활성능을 보였다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.3.1-3.1
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• 2011

Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.296-296
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• 2006

Highly temperature stable mesoporous materials have excellent properties and potential applications. Here we show a novel poly(vinyl)silazane-block-polystyrene diblock copolymer, which was synthesized by controlled/living free radical polymerization with reversible addition fragmentation chain transfer (RAFT) route. The obtained diblock copolymer occurs the phaseseparation on the nanoscale to form ordered nanostructure, which is converted to mesoprorous ceramic after heating at 800oC. This route demonstrates the preparation of highly temperature stable mesoporous silicon carbon nitrides (SiCN) ceramic film directed from highly cross-linking poly(vinyl)silazane blocks with high ceramic yield, which is different from previous pathway.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.367-368
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• 2009

현대사회 건축물들의 고층화로 인하여 구조물의 중량부담 경감의 필요성이 대두되고 있다. 이에 따라 비구조용 재료로 경량기포콘크리트의 수요가 꾸준히 증가하는 추세이다. 다공성 세라믹스(ALC)는 가장 대표적인 경량기포콘크리트로서 경량블록 등의 건축자재로 많이 사용되고 있다. 본 연구는 원료의 입도 및 함량 제어를 통하여 저 고비중 ALC의 물리적 특성을 확인하고자 하였다.

• 한국세라믹학회지
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• 제54권6호
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• pp.525-529
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• 2017

To improve the thermal resistance of a porous borosilicate lining block, we prepared and applied polysiloxane-fumed silica-ethanol slurry on top of the block and fired the coating layer using a torch for 5 minutes at $800^{\circ}C$. We conducted magnified characterizations using a microscope and XRD analysis to observe phase transformations, and TGA-DTA analysis to determine the thermal resistance. Thermal characterizations showed improved heat resistance with relatively high polysiloxane content slurry. Cross-sectional optical microscope observation showed less melting near the surface and decreased pore formation area with higher polysiloxane content slurry. XRD analysis revealed that the block and coating layer were amorphous phases. TGA-DTA analysis showed an endothermic reaction at around $550^{\circ}C$ as the polysiloxane in the coating layer reacted to form SiOC. Therefore, coating polysiloxane on a borosilicate block contributes to preventing the melting of the block at temperatures above $800^{\circ}C$.

• 한국항해항만학회지
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• 제44권4호
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• pp.305-311
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• 2020

지구온난화에 따른 연안의 해수면 상승은 해안에 가해지는 파랑에너지의 상승을 유발한다. 이러한 해수면의 상승은 상대적으로 수심이 깊어지는 효과를 초래하고 이는 과거 발생하지 않았던 해안지역의 침식 및 해빈에서의 모래를 유실시킨다. 일반적으로 연안침식에 대응하는 방법은 호안을 쌓아 보호하게 되는 경성공법으로 외력의 변화에 따라 현장여건에 맞는 호안의 경사, 단면형상 및 재료를 선택하게 된다. 하지만 현상에 대한 불충분한 이해에 근거한 공법 적용으로 다양한 피해가 발생하고 있으며, 이는 신뢰도 향상을 위한 기술개발 및 융합기술 도입의 필요성을 보여준다. 본 연구에서는 파랑저감에 효과적인 다공성 구조물 바이오코스트(Biocoast)를 활용하여 해안침식피해억제를 위한 친환경 투수 바이오폴리머 콘크리트 블록을 개발하였다. 자연에서 내구성이 강하고 안정된 구조인 벌집, 주상절리, 클로버에서 정육각형 모양과 삼각형의 복합체로 디자인을 도출하였으며, 월파방지와 처오름 현상 감소를 위해 바이오코스트로 요철(凹凸)을 적용하도록 디자인에 변화를 가하였다. 한국 동해안의 해수욕장의 자연조건을 반영하여 디자인 한 블록의 중량과 크기를 계산하여 실형을 제작하고 이를 현장에의 설치를 앞두고 있다. 특히, 자연해변 및 호안시설에 대해 자연 및 인위적 외력에 의한 침식과 세굴로부터 연안을 보호하고, 블록의 단위화를 통해 품질관리 및 공정관리의 효율성을 향상시킬 수 있을 것으로 사료되며 하천, 호수의 호안과 자연산책로에 확장 적용하고자 한다.

• Journal of Periodontal and Implant Science
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• 제26권1호
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• pp.27-46
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• 1996

The purpose of this study was designed to compare with the effects of 4 different surface active bioceramics on the healing process of alveolar bone defects in dogs. Artificial alveolar bone defects depth 4-6mm, width 3-4mm) were created with # 6 round bur at interproximal areas of maxillary canine, maxillary 2nd premolar, mandibular canine, and mandibular 3rd premolar. porous hydroxyapatite(Interpore $200^R$) , 45S5 bioglass, CJ4/lOC crystalline glass, and JJ crystalline glass were implanted in intrabony defects randomly. Experimental groups were divided into 4 categories according to its implant material. After implantation, all groups were examined postoperatively 4 weeks to 12 weeks. 3 dogs was selected randomly and sacrificed after vascular perfusion with 2.5% glutaraldehyde at every 4 weeks. Tissue blocks with surroundig alveolar bone and soft tissues were removed and immersed in formaldehyde/glutaraldehyde fixative. After 20 weeks decalcification with EDTA and formic acid, sections were made and observed under light microscope and transmission electron microscope. In all experimental groups, the encapsulation of inactive connective tissue was observed around graft particles in 4 weeks. As time elapsed, the thickness of surrounding connective tissue was decreased. Osteoconductive bone growth pattern was seen apparently in all groups. CJ4/lOC crystalline glass showed the most active bone formation until 8 weeks. 45S5 bioglass was, however, the most active in new bone formation at 12 weeks. Though there was difference in resorption rate among grafting materials, the size of graft particles was decreased gradually. 45S5 bioglass was resorbed faster than the others. On the other hand, porous hydroxyapatite was degraded most slowly. Phagocytosed particulate matters was observed in the cytoplasm of multinuclear multinuclear giant cell and macrophage under transmission electron microscope. The results suggested suggested that 45S5 bioglass and CJ4/lOC crystalline glass may have some enhanced reparative potential when compared to porous hydroxapatite in the treatment of periodontal defeds. JJ crystalline glass reguires a further investigation of the safety of its use.