• Title/Summary/Keyword: pores structure

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Improvement of the Corrosion Resistance of PVD Hard Coating/Substrate Systems - Recent Developments -

  • Jehn, Hermann A.;Kang, Sung-Goon
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.472-483
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    • 1999
  • Hard coatings playa continuously increasing role in the field of tribology as well as for decorative applications. In both areas they are often also exposed to corrosive media. While especially hard nitride coatings show a high corrosion resistance for themselves, hard $coating_strate systems may suffer from a severe corrosion attack due to the defects in the coating structure (pores, pinholes) resulting from the PVD-typical film morphology. While a huge number of investigations cover the tribological properties, only limited studies deal with the corrosion behavjour of coating substrate systems and attempts are made to improve their corrosion resistance. The present paper shortly describes the corrosion mechanisms and repots characteristic examples of the system behaviour. Special emphasis is laid on recent investigations to improve the corrosion resistance by alloying, interlayers or multilayered coating structures.es.

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Reduction of Tractive Force by Revetment Mattress/Filter (호안 Mattress/Filter에 의한 소류력 저감)

  • Seo Young-Min;Lee Seung-Yun;Heo Chang-Hwan;Jee Hong-Kee
    • Journal of Environmental Science International
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    • v.15 no.1
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    • pp.33-43
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    • 2006
  • Revetment Mattress/Filter is the porous structure filled fillers in meshed structure so that it cail use the fillers of various sizes and form various pores. The porous structure of the Mattress/Filter increases drainage so that it decreases the energy and erosion of flow therefore the tractive force is decreased and the erosion of revetment is mitigated. The filler of Mattress/Filter uses gravels, waste concretes and slags so that the surface is rough and the roughness coefficient increases and the increase of the roughness coefficient decreases flow velocity and tractive force. On the other hand Mattress/Filter and vegetation are combined so that the increase of roughness coefficient and flow velocity still more progress therefore the effect of decrease of tractive force is increased after a few months have passed since the Mattress/Filter is constructed so that the vegetation is developed and be stabilized. The vegetation channel of Mattress/Filter is set tip and the inspection comes into operation by varing flowrate and vegetation spacing to examine these characters of the Mattress/Filter The coefficient of flow velocity U/U*' is decreased exponentially as vegetation esity aH' or $\lambda$ is increased and the coefficient of friction f is increased as vegetation desity aH' is increased but decreased as the coefficient of flow velocity U/U*' is increased. The effective tractive force $F_0$ is decreased exponentially as the vegetation desity aH' is increased. From the inspection the results are obtained that the porous and vegetation structure of the revetment Mattress/Filter system increases the coefficient of friction of revetment so that flow velocity and effective are decreased therefore greatly contributes the stability of the revetment.

Characteristics of Micro-pore Structure of Foam Composite using Palm-based Activated Carbon (야자계 활성탄을 활용한 폼 복합체의 미세기공 구조특성)

  • Choi, Young-Cheol;Yoo, Sung-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.157-164
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    • 2021
  • Recently, a number of studies have been conducted on photocatalysts and adsorbents that can remove harmful substances to improve environmental problems related to fine particles. In this study, a porous foam composites were fabricated using palm-based activated carbon having a large amount of micro-pores and foam concrete with a significantly larger total pore volume compared to general construction materials. To evaluate the adsorption potential of fine particles, the pore structure of the foam composites were analyzed. For the analysis of the pore structure of the foam composite, BET and Harkins-jura theory were applied from the measured nitrogen adsorption isotherm. From the results of the analysis, the specific surface area and micro-pore volume of the foam composite containing activated carbon increased significantly compared to Plain. As thereplacement of activated carbon increased, the specific surface area and micro-pore volume of the foam composite tended to increase. It seems that the foam composite has high adsorption performance for gaseous fine particle precursor such as nitrogen oxides.

Physical Properties Evaluation of Porous Concrete according to Target Porosity and Pumice Contents Ratio for Application of the Aquatic Environment (수계환경 적용을 위한 설계공극률 및 부석 혼입률에 따른 포러스콘크리트의 물리적 특성 평가)

  • Kim, Woo-Suk;Park, Jae-Roh;Kim, Bong-Kyun;Seo, Dae-Seuk;Park, Jun-Seok
    • Journal of the Korea Concrete Institute
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    • v.28 no.6
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    • pp.703-711
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    • 2016
  • The present study is mainly aimed at securing adequate pores which are applicable to the aquatic environment and satisfying the required strength of porous concrete as a structure by substituting pumice for crushed stone which is usually used for the fabrication of porous concrete. Accordingly, in order to deduce the optimum mixing conditions applicable to the aquatic environment, we sought to evaluate the porosity, coefficient of permeability and compressive strength of porous concrete based on the target porosity and the mixing factors for pumice. By examining the porosity and coefficient of permeability of porous concrete and the physical properties of its compressive strength based on the target porosity and the mixing factors for pumice, it is judged that the optimum mixtures for porous concrete applicable to the aquatic environment which satisfy both the necessity of securing adequate pores and the required strength for porous concrete as a structure are PC I I-10-0, PC I I-10-5 and PC I I-10-10.

Silver Coating on the Porous Pellets from Porphyry Rock and Application to an Antibacterial Media (반암(맥반석)으로 제조한 다공성 펠렛의 Ag 담지 및 항균 메디아로서의 적용)

  • Han, Yo-Sep;Kim, Hyun-Jung;Shin, Young-Seop;Park, Jai-Koo;Ko, Jae-Churl
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.16-23
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    • 2009
  • The porous pellets were prepared from porphyry by slurry foaming method. The effect of sintering temperatures on pore structure of porous porphyry pellets with different extension ratio ($E_R$) was investigated by specific surface area, water absorption and porosity, which changed with sintering temperatures. When the sintering temperatures increased from $975^{\circ}C$ to $1075^{\circ}C$, specific surface area and water absorption of the all samples decreased. In case of the sample with an equal sintering temperature, $E_R=3.0$ pellets had little influence on pore structure compared to the $E_R=2.0$ pellets. As a results, it was shown by SEM that facilitated formation of micro pores at $E_R=2.0$ pellets shrunk increasingly after sintering process. At $E_R=3.0$ and sintering temperature at $1025^{\circ}C$, optimum conditions of the porous porphyry porous pellets was found. Also, Escherichia coli removal efficiency of the silver-containing porphoyry porous pellets was measured for the feasibility as a antibacterial media. The antibacterial activity of prepared silver-containing sample was maintained above 90% for 40 days.

Effect of $ZnCl_2$ on Formation of Carbonized Phenol Resin Anode

  • Kim Han-Joo;Hong Ji-sook;Son Won-Ken;Park Soo-Gil;Oyama Noboru
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.85-89
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    • 2000
  • For replacing Li metal at Lithium ion Battery(LIB) system, we used carbon powder material which prepared by Pyrolysis of Phenol resin as starting material. It became amorphous carbon by Pyrolysis through it's self condensation by thermal treatment. Amorphous carbon can be doped with Li intercalation and deintercalation because it has wide interlayer. However, it has a problem with structural destroy due to weak carbon-carbon bond. So, we used $ZnCl_2$ as the pore-forming agent. This inorganic salt was used together with the resin serves not only as the pore-forming agent to form open pores, which grow into a three-dimensional network structure in the cured material, but also as the microstructure-controlling agent to form a loose structure doped with bulky dopants. We used SEM in order to find to difference of structure, and can calculate the distance of interlayer by XRD analysis. CV test showed oxidation and reduction.

Chemical structure and PVC shape after dehydrochlorination of PVC (탈염화수소후의 PVC형상과 화학구조)

  • 신선명;전호석
    • Resources Recycling
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    • v.13 no.3
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    • pp.37-42
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    • 2004
  • PVC powder was dehydrochlorinated by hydrothermal reaction at reaction time 0∼5 hr, reaction temperature $200∼250^{\circ}C$ in 0∼2M NaOH solution, and shape and structure of the PVC residue was investigated. The shape of the residue was changed largely according to NaOH concentration. Most of the residue was cohered in the aqueous solution, and many pores less than 10 $\mu\textrm{m}$ were formed on the surface. Dense network structure was well developed inside the residue. On the other hand, the residue in the NaOH solution was not cohered and its shape is roughly spherical. In the IR spectrum of the residue both in water and NaOH solution at $250^{\circ}C$, aromatic rings and absorption peak by C=C double bond were observed. From the results, it was observed that aromatic circle reaction and bridge reaction occured inter and intra molecules.

Spark Plasma Sintering of Fe-Ni-Cu-Mo-C Low Alloy Steel Powder

  • Nguyen, Hong-Hai;Nguyen, Minh-Thuyet;Kim, Won Joo;Kim, Ho Yoon;Park, Sung Gye;Kim, Jin-Chun
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.207-212
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    • 2016
  • In this study, Fe-Cu-Ni-Mo-C low alloy steel powder is consolidated by spark plasma sintering (SPS) process. The internal structure and the surface fracture behavior are studied using field-emission scanning electron microscopy and optical microscopy techniques. The bulk samples are polished and etched in order to observe the internal structure. The sample sintered at $900^{\circ}C$ with holding time of 10 minutes achieves nearly full density of 98.9% while the density of the as-received conventionally sintered product is 90.3%. The fracture microstructures indicate that the sample prepared at $900^{\circ}C$ by the SPS process is hard to break out because of the presence of both grain boundaries and internal particle fractures. Moreover, the lamellar pearlite structure is also observed in this sample. The samples sintered at 1000 and $1100^{\circ}C$ exhibit a large number of tiny particles and pores due to the melting of Cu and aggregation of the alloy elements during the SPS process. The highest hardness value of 296.52 HV is observed for the sample sintered at $900^{\circ}C$ with holding time of 10 minutes.

Ultrastructure of Egg Micropyles and Zona Radiata in Three Aquacultural Teleosts (양식산 경골어류 3종의 난문과 방사대의 미세구조)

  • Yoon, Jong-Man
    • Korean Journal of Ichthyology
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    • v.11 no.2
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    • pp.126-133
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    • 1999
  • Ultrastructure of the zona radiata and the micropyle of ripe eggs in the rainbow trout (Oncorhynchus mykiss), catfish (Silurus asotus) and loach (Misgurnus anguillicaudatus) were examined by light, scanning and transmission microscopes. The egg micropyle of rainbow trout and catfish consists of a funnel-shaped vestibule and a tapered canal transversing the zona radiata. The micropyle of rainbow trout and catfish showed the similar structure with flat pit and long canal. The micropylar wall showed the clockwise spiral structure in rainbow trout. The micropyle of the loach showed the type with a hollow pit leading into a short canal and the micropylar wall showed the counterclockwise spiral structure. There are numerous and various size pores at the surface area around the opening in every experimented fish. Interconnecting ridges were observed in the unfertilized eggs of every fish.

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Fabrication of Porous 3-Dimensional Ti Scaffold and Its Bioactivity by Alkali Treatment (다공성 3차원 Ti 지지체의 제조 및 알카리처리에 따른 생체활성 평가)

  • An, Sang-Hyun;Kim, Seung-Eon;Kim, Kyo-Han;Yun, Hui-Suk;Hyun, Yong-Taek
    • Korean Journal of Materials Research
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    • v.19 no.7
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    • pp.362-368
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    • 2009
  • Ti scaffolds with a three-dimensional porous structure were successfully fabricated using powder metallurgy and modified rapid prototyping (RP) process. The fabricated Ti scaffolds showed a highly porous structure with interconnected pores. The porosity and pore size of the scaffolds were in the range of 66$\sim$72% and $300\sim400\;\mu$m, respectively. The sintering of the fabricated scaffolds under the vacuum caused the Ti particles to bond to each other. The strength of the scaffolds depended on the layering patterns. The compressive strength of the scaffolds ranged from 15 MPa to 52 MPa according to the scaffolds' architecture. The alkali treatment of the fabricated scaffolds in an aqueous NaOH solution was shown to be effective in improving the bioactivity. The surface of the alkali-treated Ti scaffolds had a nano-sized fibre-like structure. The modified surface showed a good apatite forming ability. The apatite was formed on the surface of the alkali treated Ti scaffolds within 1 day. The thickness of the apatite increased when the soaking time in a simulated body fluid (SBF) solution increased. It is expected that the surface modification of Ti scaffolds by alkali treatment could be effective in forming apatites in vivo and can subsequently enhance bone formation.