• Title/Summary/Keyword: pore structure

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A Study on the Pore Structure of Hardened Alumina Cement Pste by Water Vapor Sorption ($H_2O$ 증착법에 의한 알루미나 시멘트 경화체의 기공구조 연구)

  • 임용무;장복기
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.273-278
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    • 1993
  • Using water vapor (de)sorption isotherm, pore structure analyses were performed for hardened cement pastes by a combination of the "MP-method" for the micropores and the "corrected modelless method" for the wide pores. This work was carried out to investigate the pore structure and to understand the microstructural basis of alumina cement developing much higher strength than Portland cement. Alumina cement shows extremely low microporosity and its wide pores are also composed mainlyof pores with very small radii. And the pore structure analysis results are consistent with the high strength property of alumina cement.y of alumina cement.

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RHEOLOGICAL STUDY ON STRAINER STRUCTURE OF UNDER DRAIN PIPES FOR SLOPE PROTECTION

  • Mihara. Machito;Yasutomi, Rokuro;Nakamura, Yoshio
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1993.10a
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    • pp.197-204
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    • 1993
  • Pipe drainage is one of the effective slope protein works that can be adopted practically. As fine soil particles are suspended in percolating water, the strainer structure of under drain pipes in necessary to prevent the immediate clogging by soil suspension flow. This study deals with the effective strainer structure of under drain pipes for slope protection. The effective strainer structure of under pipes is the funneled strainer in which pore radius is enlarged toward flow direction. It is designed from the rheological properties of soil suspension flow which prevents the immediate clogging. Experimental results showed that the pipe drain discharge through the funneled strainers was larger than that through the constant pore radius strainers. This theorectial and experimental results indicate that the strainer with enlarged pore radius toward flow direction, is more effective than the strainer with constant pore radius.

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Effects of Pore Structure of Ground Granulated Blast-Furnace Slag Concrete on Freezing-Thawing Resistance (고로슬래그 미분말 콘크리트의 공극구조가 동결융해 저항성능에 미치는 영향)

  • Lee, Bo-Kyeong;Kim, Gyu-Yong;Kim, Rae-Hwan;Shin, Kyoung-Su;Lee, Jun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.284-285
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    • 2014
  • In this study, effects of pore structure of ground granulated blast-furnace slag concrete on freezing-thawing resistance are reviewed. As a result, degradation of freezing-thawing resistance performance was occurred as replacement ratio of ground granulated blast-furnace slag increases under same specified concrete strength condition. It is considered that pore structure of internal binder affects freezing-thawing resistance performance.

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Numerical Analysis of Cyclic Deformation of Polymer Foam Film Using Stretched Truncated Octahedron Model (모서리가 제거된 팔면체 인장모델을 이용한 다공성 폴리머 박막의 반복변형거동 수치해석)

  • Yoo, Ui-Kyung;Lee, Young-Seog
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.3
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    • pp.104-110
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    • 2010
  • Cyclic deformations of polymer foam film are simulated using the finite element method. Material of polymer foam film is polypropylene (PP). The calculated polymer foam film is micro-scale thin film has cellular structure. The polymer foam film is used in ferro-electret applications. The polymer foam film is idealized to one cell structure as lens shaped stretched truncated octahedron model. Cyclic deformation is performed by uniaxial stretching. Stretching direction is perpendicular to plane of cellular film. Various cyclic strain amplitudes, pore wall thicknesses, pore shape are investigated to find deformation tendency of cellular structure. Consequently, cellular structure has various macroscopic stresses on cyclic deformation with various pore thickness and pore shape.

A Study on the 3D Imaging of High Temperature Heating Cement Paste and the Analysis of Variation of the Pore Structure (고온 가열 시멘트 페이스트의 3D 영상화 및 세공구조 변화 분석에 관한 연구)

  • Kim, Min-Hyouck;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.147-148
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    • 2020
  • In case of high temperature damage such as fire, the durability of concrete is reduced due to the collapse of internal pore tissue. Therefore, in this paper, we are going to analyze the pore structure of cement paste hardening agent using MIP analysis and build up 3D data produced using X-ray CT tomography. The test specimen is made of cement paste from W/C 0.4. As the temperature of heating increased, the amount of air gap and the diameter of air gap in cement paste increased. It is judged that the air gap structure inside cement collapsed due to the evaporation of the hydrate, gel count, capillary water, etc. inside the cement due to the high temperature.

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The Analysis of the Micro-structure of Oxygen Plasma Treated PET Using a Nitrogen Porosimeter (Nitrogen Porosimeter를 이용한 산소 플라즈마 처리 PET의 미세구조 분석)

  • 김병인;김태경;조규민;임용진
    • Textile Coloration and Finishing
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    • v.11 no.6
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    • pp.1-6
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    • 1999
  • The porosities of PET fibers were investigated using a nitrogen porosimeter according to oxygen plasma treatment and dyeing with a disperse dye, and they were discussed in terms of the change of internal micro-structure of the PET fiber. The total pore volume, surface area and average pore size of the plasma treated PET fibers increased expectably compared with the untreated sample. The PET fibers treated with oxygen plasma and then dyed with a disperse dye were increased significantly in the surface area and the total pore volume comparing with those of plasma treated only, but decreased in the average pore size. The increase of the surface area, after dyeing, of the plasma treated PET fibers was due to addition of the surface area of the dye itself to that of the PET fiber. The increase of the total pore volume of the plasma treated PET fibers by dyeing, which is the opposite result to the general idea that the pore volume of fibers would be reduced by occupation of dye molecules in the pores, could be explained by the free-volume model. This is that the amorphous region in the fiber expanded by occupation of dye molecules, and the marginal space surrounding dyes was generated as many smaller pores, and the decrease of the average pore size of the dyed sample also could be explained The decrease of the average pore size was caused by the splitting of a larger pore into smaller pores.

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Pore Size Distribution and Chloride Diffusivity of Concrete Containing Ground Granulated Blast Furnace Slag

  • Moon Han-Young;Kim Hong-Sam;Choi Doo-Sun
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.277-282
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    • 2004
  • In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

Estimation of Pore Structure Characteristic and Permeability of Hybrid Concrete by Image Analysis Method (화상분석법을 이용한 하이브리드 콘크리트의 공극구조 특성 및 투수성 평가)

  • Jang, Bong Jin;Chon, Beom Jun;Hong, Young Ho;Bae, Jong Oh;Lim, Hong Beom
    • International Journal of Highway Engineering
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    • v.17 no.1
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    • pp.59-67
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    • 2015
  • PURPOSES : In this study, an image analysis method is used to evaluate the pore structure characteristics and permeability of hybrid concrete. METHODS : The binder weight of hybrid concrete is set to $400kg/m^3$, $370kg/m^3$, and $350kg/m^3$, and for each value of binder weight, the pore structure and permeability of concrete mixture is evaluated. The permeability of hybrid concrete is evaluated using a rapid chloride penetration test(RCPT). RESULTS : The concrete pore structure characteristics of hybrid concrete reveals that as the binder weight is reduced, the entrained air is reduced and the entrapped air is increased. The permeability of the hybrid concrete for all values was measured to be below 1000 C, which indicates a "Very Low" level of permeability relative to the evaluation standard of KS F 2711. Additionally, as the binder weight is decreased, there is a significant increase in the permeability of chloride ions. CONCLUSIONS : In this study, the pore structure characteristics of hybrid concrete at different binder weights shows that as the binder weight is reduced, the entrained air is reduced and the entrapped air is increased. Consequently, chloride ion penetration resistance of the hybrid concrete is diminished. As a result, it is expected that this will reduce the concrete's durability.

A Study on the Hydration Ratio and Autogenous Shrinkage of Low Water/cement Ratio Paste (저물시멘트비 페이스트의 시멘트수화율 및 자기수축에 관한 연구)

  • Hyeon, Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.385-390
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    • 2002
  • Autogenous shrinkage of concrete has been defined as decrease in volume due to hydration cement, not due to other causes such as evaporation, temperature change and external load and so on. For ordinary concretes, autogenous shrinkage is so little compared to the other deformations that it has been dignored. It has recently been proved, however, that autogenous shrinkage considerably increase with decrease in water to cement ratio. And it has been reported that cracking can be caused by autogenous shrinkage, when high- strength concretes were used. In this study, we propose an analytical system to represent autogenous shrinkage in cement paste in order to control crack due to autogenous shrinkage. The system is composed with the hydration model and pore structure model. Contrary to the usual assumption of uniform properties in the hydration progress, the hydration model to refine Tomosawa's represents the situation that inner and outer products are made in cement paste. The pore structure model is based upon the physical phenomenon of ion diffusion in cement paste and chemical phenomenon of hydration in cement particle. The proposed model can predict the pore volume ratio and the pore structure in cement paste under variable environmental conditions satisfactorily The autogenous shrinkage prdiction system with regard to pore structure development and hydration at early ages for different mix-proportions shows a reasonable agreement with the experimental data.

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Pore structure evolution characteristics of sandstone uranium ore during acid leaching

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Zhang, Ni;Zhang, Shuwen;Feng, Song
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.4033-4041
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    • 2021
  • To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.