• Title/Summary/Keyword: pore solution

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The Preparation of Porous Silica Glass by the Sol-Gel Method -Change of Properties of Gel by Addition of Fromamide- (졸-겔법에 의한 다공질 실리카 유리의 제조에 관한 연구 -Formamide 첨가에 의한 겔의 성질 변화-)

  • 서정민;신대용;최성일;한상목
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.169-174
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    • 1993
  • The porous silica glass prepared by the sol-gel method from the mixed solution of Si(OCH3)4, H2O, HCl and CH3OH with HCONH2 as a DCCA (Drying Control Chemical Additives). For investigation the characteristics of gels and glasses, we examined gels and glasses using TG-DTA, XRD, IR, SEM and porosimeter. The more content of formamide in the mixed solution increased, the more pore size and porosity of gel increased. In the excess formamide added gel, the properties of pore of gel were not so changed. The porous silica glass was prepared from the dry gel after heat treatment at 75$0^{\circ}C$. Porosity and mean pore size of the porous silica glass was 17~25% and 40~60$\AA$ relatively.

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Factors Affecting Z-direction Penetration of PVAm Solution into Paper (PVAm 용액의 종이 두께 방향 침투에 영향하는 인자들)

  • Choi, Do-Chim;Won, Jong Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.104-111
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    • 2015
  • Factors influencing penetration of PVAm solution into paper during impregnation were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, and filler addition, and hydrophobicity of paper was varied by adding AKD. In addition, the viscosity of PVAm solution was varied by changing the concentration of PVAm solution. Important factors influencing penetration of PVAm solution into paper were found to be the pore structure and the hydrophobicity of paper, and the viscosity of PVAm solution. Pore structure of paper could be controlled by refining degree and filler addition and hydrophobicity of paper could be controlled by internal sizing. Denser structure of paper, higher hydrophobicity and higher liquid viscosity slowed down the penetration of PVAm solution into paper.

Preparation and Characteristics of Polyethersulfone Microfiltration Membranes (폴리에테르술폰 정밀여과막의 제조 및 특성 연구)

  • Kim, No-Won
    • Membrane Journal
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    • v.17 no.4
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    • pp.329-337
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    • 2007
  • This is the research about a new method to make the internal separation layer with smallest pore size in polyethersulfone (PES) membrane by adding p-toluenesulfonic acid (TSA) and polyvinylpyrolidone (PVP) to polymeric PES solution. The preparation and morphological characterization of PES sheet membranes containing PVP as a hydrophilic swelling material and TSA as a demixing material were performed. As a result by microflow porometery, the PVP and TSA added PES membranes showed good permeabilities and narrow pore size distributions, comparable to those of the commercial membranes. The concentration of PVP affected the PES characteristics on air permeability and surface structure. The concentration of TSA influenced on pore size distribution but do not affect air permeability. The surface images of FE-SEM shows similar pore size when TSA added or not. However, the cross-section images of FE-SEM show that the TSA added PES membranes have a increase of internal layer thickness with smallest pore size.

Process for the Preparation of Conducting Polymer Composites (I) : Effect of the Porosity on the Conductivity (전도성 고분자 복합체 제조를 위한 신합성 연구 (I) : 다공성정도가 전도성 고분자 복합체의 전도도에 미치는 영향)

  • Son, Suk-Hye;Park, Young-Jun;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.393-400
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    • 1996
  • The conducting polymer composites were prepared by imbibing the porous particle with an $FeCl_3$ oxidant solution, drying the imbibed porous particle, and imbibing again with pyrrole solution for polymerization to take place in the pore. The conductivity of the porous composite particles, was higher than that of nonporous particles. Also, the conductivity of composite was increased with increasing specific surface area and pore specific volume of the host porous particles since the degree of formation of conducting polymer in the pore increased.

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Vibrio vulnificus Cytolysin Forms Anion-selective Pores on the CPAE Cells, a Pulmonary Endothelial Cell Line

  • Choi, Bok-Hee;Park, Byung-Hyun;Kwak, Yong-Geun
    • The Korean Journal of Physiology and Pharmacology
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    • v.8 no.5
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    • pp.259-264
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    • 2004
  • Cytolysin produced by Vibrio vulnificus has been incriminated as one of the important virulence determinants in V. vulnificus infection. Ion selectivity of cytolysin-induced pores was examined in a CPAE cell, a cell line of pulmonary endothelial cell, using inside-out patch clamp techniques. In symmetrical NaCl concentration (140 mM), intracellular or extracellular application of cytolysin formed ion-permeable pores with a single channel conductance of $37.5{\pm}4.0$ pS. The pore currents were consistently maintained after washout of cytolysin. Replacement of $Na^+$ in bath solution with monovalent ions $(K^+,\;Cs^+\;or\;TEA^+)$ or with divalent ions $(Mg^{2+},\;Ca^{2+})$ did not affect the pore currents. When the NaCl concentration in bath solution was lowered from 140 to 60 and 20 mM, the reversal potential shifted from 0 to -11.8 and -28.2 mV, respectively. The relative permeability of the cytolysin pores to anions measured at $-40\;mV\;was\;Cl^-\;=\;NO_2^-\;{\geq}\;Br^-\;=\;I^-\;> \;SCN^-\;>\;acetate^-\;>\;isethionate^-\;>\;ascorbic acid^-\;>\;EDTA^{2-},$ in descending order. The cytolysin-induced pore current was blocked by $CI^-$ channel blockers or nucleotides. These results indicate that V. vulnificus cytolysin forms anion-selective pores in CPAE cells.

Free-strain solutions for two-dimensional consolidation with sand blankets under multi-ramp loading

  • Zan Li;Songyu Liu;Cuiwei Fu
    • Geomechanics and Engineering
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    • v.35 no.4
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    • pp.385-393
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    • 2023
  • To analyze the consolidation with horizontal sand drains, the plane strain consolidation model under multi-ramp loading is established, and its corresponding analytical solution is derived by using the separation of variables method. The proposed solution is verified by the field measurement data and finite element results. Then, the effects of the loading mode and stress distribution on consolidation and dissipation of pore pressure are investigated. At the same time, the influence of hydraulic conductivity and thickness of sand blankets on soil consolidation are also analyzed. The results show that the loading mode has a significant effect on both the soil consolidation rate and generation-dissipation process of pore water pressure. In contrast, the influence of stress distribution on pore pressure dissipation is obvious, while its influence on soil consolidation rate is negligible. To guarantee the fully drained condition of the sand blanket, the ratio of hydraulic conductivity of the sand blanket to that of clay layer kd/kv should range from 1.0×104 to 1.0×106 with soil width varying from 100 m to 1000 m. A larger soil width correspondingly needs a greater value of kd/kv to make sure that the pore water can flow through the sand blanket smoothly with little resistance. When the soil width is relatively small (e.g., less than 100 m), the effect of thickness of the sand blanket on soil consolidation is insignificant. And its influence appears obvious gradually with the increase of the soil width.

Treatment of Naphtalenes-Contaminated Soil by Surfactant/ Coagulant (계면활성제/응집제를 이용한 나프탈렌 오염토양 처리)

  • Park, Joon-Seok;Park, Jong-Un;Shin, Chul-Ho;Park, Hee-Jung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.2
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    • pp.82-90
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    • 2004
  • This study was conducted to evaluate in situ soil flushing and coagulation for naphtalenes-contaminated soil remediation. Mixed-surfactant of 1% POE12 and 1% SDS (1 : 1 by volume basis) was used as a flushing solution. When 5 pore volumes of mixed -surfactant were added to soil column, the flushing efficiencies of 2-methylnaphtalene and 1,5-dimethylnaphtalene with about 1,500 mg/kg(dry soil) were approximately 80% and 60% respectively. In adding 13 pore volumes of mixed-surfactant, the flushing efficiencies of 2-methylnaphtalene and 1,5-dimethylnaphtalene were 90% and 82%. However, considering in situ soil flushing with distilled water, about 42% and 71% were flushed for 2-methylnaphtalene and 1,5-dimethylnaphtalene by surfactant-only. For about 10,000 mg/kg(dry soil) diesel-contaminated soil, 40% and 70% of TPH were flushed-out in 5 pore volumes and 13 pore volumes addition. However, for naphtalenes in diesel TPH, 90% of flushing efficiency was discovered in adding only 5 pore volumes of flushing solution. There was not discovered significant difference among coagulation efficiencies of 6 kinds of polymers, and the coagulation efficiencies were near 50%.

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토양 세정법을 이용한 실제 유류 오염 토양 및 지하수 정화

  • 강현민;이민희;정상용;강동환
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.418-421
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    • 2003
  • Surfactant enhanced in-situ soil flushing was peformed to remediate the soil and groundwater at an oil contaminated site, and the effluent solution was treated by the chemical treatment process including DAF(Dissolved Air Flotation). A section from the contaminated site(4.5m$\times$4.5m$\times$6.0m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average Hydraulic conductivity of 2.0$\times$10$^{-4}$ cm/sec. Two percent of sorbitan monooleate(POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminant section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed by GC(gas-chromatography) for TPH concentration with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit(WWDL). Total 18.5kg of oil (TPH) was removed from the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. Results suggest that in-situ soil flushing and chemical treatment process including DAF could be a successful process to remediate contaminated sites distributed in Korea.

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The formation of highly ordered nano pores in Anodic Aluminum Oxide

  • Im, Wan-soon;Cho, Kyung-Chul;Cho, You-suk;Park, Gyu-Seok;Kim, Dojin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.53-53
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    • 2003
  • There has been increasing interest in the fabrication of nano-sized structures because of their various advantages and applications. Anodic Aluminum Oxide (AAO) is one of the most successful methods to obtain highly ordered nano pores and channels. Also It can be obtained diverse pore diameter, density and depth through the control of anodization condition. The three types of substrates were used for anodization; sheets of Aluminum on Si wafer and Aluminum on Mo-coated Si wafer. In Aluminum sheet, a highly ordered array of nanoholes was formed by the two step anodization in 0.3M oxalic acid solutions at 10$^{\circ}C$ After the anodization, the remained aluminum was removed in a saturated HgCl$_2$ solution. Subsequently, the barrier layer at the pore bottom was opened by chemical etching in phosphoric acid. Finally, we can obtain the through-channel membrane. In these processes, the effect of various parameters such as anodizing voltage, anodizing time, pore widening time and pre-heat treatment are characterized by FE-SEM (HITACH-4700). The pore size. density and growth rate of membrane are depended on the anodizing voltage and temperature respectively. The pore size is proportional to applied voltage and pore widening time The pore density can be controlled by anodizing temperature and voltage.

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Modeling radon diffusion equation in soil pore matrix by using uncertainty based orthogonal polynomials in Galerkin's method

  • Rao, T.D.;Chakraverty, S.
    • Coupled systems mechanics
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    • v.6 no.4
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    • pp.487-499
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    • 2017
  • This paper investigates the approximate solution bounds of radon diffusion equation in soil pore matrix coupled with uncertainty. These problems have been modeled by few researchers by considering the parameters as crisp, which may not give the correct essence of the uncertainty. Here, the interval uncertainties are handled by parametric form and solution of the relevant uncertain diffusion equation is found by using Galerkin's Method. The shape functions are taken as the linear combination of orthogonal polynomials which are generated based on the parametric form of the interval uncertainty. Uncertain bounds are computed and results are compared in special cases viz. with the crisp solution.