• Title/Summary/Keyword: pore size distributions

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Effects of Size and Shape of Drain on Horizontal Vacuum Drain (배수재의 직경과 형상변화가 수평진공배수에 미치는 영향)

  • Yoo, Nam-Jae;Park, Byung-Soo;Jeong, Gil-Soo;Lee, Byung-Kon
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.293-301
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    • 2001
  • This paper is experimental results of investigating the efficiency of horizontal vacuum drainage system. Effects of size and shape of drain on horizontal vacuum drainage were studied. Model tests in the laboratory with soft marine clay were carried out with drain pipe of having three different diameters and PBD (Plastic Board Drain) of strip shape so that consolidation settlement of soft clay due to applied vacuum pressure, amount of discharge, ground settlement and distributions of pore pressure and undrained shear strength were measured during testing. From results of model test, amount of discharge due to vacuum pressure was increased with the diameter of pipe drain whereas the drain efficiency of pipe in per unit area of drain surface was decreased with diameter of pipe. The rate of discharge per unit time was reduced very fast with diameter of pipe. Settlement of ground surface with time was increased with diameter of pipe as a result of increase of discharge to drain pipe.

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The Preparation of Low Cost Activated Carbon Fibers for Removal of Volatile Organic Chemicals and Odor (저가 탄소섬유를 이용한 악취제거 기술 개발)

  • Lim, Yun-Soo;Yoo, Ki-Sang;Kim, Hee-Seok;Chung, Yun-Joong
    • Journal of the Korean Ceramic Society
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    • v.38 no.10
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    • pp.928-935
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    • 2001
  • In this study, two kinds of activated carbon fibers were prepared from PAN-based stabilized fibers by physical activation with steam. The variations in specific surface area, amount of iodine adsorption and pore size distribution of the activated carbon fibers after the activation process were discussed. The activated carbon fibers were prepared by two different methods, namely a 1- and 2-step method. For the 2-step method, carbonization of fibers in $N_2$ atmosphere was carried out to make carbon fibers and then activated by steam. In normal two step steam activation, BET surface area of about $1019m^2/g$ was obtained in the study. In the 1-step steam activation process, the carbonization and activation were simultaneously carried out. In the one step steam activation, BET surface area of $1635m^2/g$ was obtained after heat-treatment at $990^{\circ}C$. However, nitrogen adsorption isotherms for oxidized PAN based activated carbon fibers that were prepared by both methods were type I in the Brunauer-Deming-Deming-Teller (BDDT) classification even though they have different BET surface areas, amounts of iodine adsorption and pore size distributions.

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Detectability of Pore Defect in Wind Turbine Blade Composites Using Image Correlation Technique (이미지 상관 기법을 이용한 풍력 발전 블레이드용 복합재료의 기공 결함 검출능)

  • Kim, Jong Il;Huh, Yong Hak;Lee, Gun Chang
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.10
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    • pp.1201-1206
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    • 2013
  • Defects that occur during the manufacturing process or operation of a wind turbine blade have a great influence on its life and safety. Typically, defects such as delamination, pore, wrinkle and matrix crack are found in a blade. In this study, the detectability of the pores, a type of defect that frequently occur during manufacturing, was examined from the full field strain distribution determined with the image correlation technique. Pore defects were artificially introduced in four-ply laminated GFRP composites with $0^{\circ}/{\pm}45^{\circ}$ fiber direction. The artificial pores were introduced in consideration of their size and location. Three different-sized pores with diameter of 1, 2 and 3 mm were located on the top and bottom surface and embedded. By applying static loads of 0-200 MPa, the strain distributions over the specimen with the pore defects were determined using image correlation technique. It was found the pores with diameter exceeding 2 mm can be detected in diameter.

Synthesis of Nano Structured Silica and Carbon Materials and Their Application (계면활성제를 이용한 나노 실리카 및 카본 소재의 합성과 응용)

  • Park Seungkyu;Kim Jongyun;Cho Wangoo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.321-328
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    • 2004
  • Nano silica ball and nano carbon ball are developed commercially by template synthesis method. Adsorption of unpleasant smelling substances such as ammonia, trimethylamine, acetaldehyde and methyl mercaptane onto nano carbon ball with hollow macroporous core/mesoporous shell structures, nano carbon ball, was investigated and compared with that onto odor adsorbent materials, activated carbon, commercially available. The adsorption and decomposition of malodor at nano carbon ball exhibited superior than those onto activated carbon. The physicochemical properties such as mesopore size distributions, large nitrogen BET specific surface area and large pore volume and decomposition of malodor were studied to interpret the predominant adsorption performance. The nano carbon ball is expected to be useful in many applications such as deodorizers, adsorbent of pollutants.

Phase Composition and Pore Structure of Sol-Gel Derived Zirconia Nanopowders (Sol-Gel법에 의해 제조된 Zirconia 나노분말의 결정상과 기공특성)

  • Cheong, Chul-Won;Park, Si-Hyun;Song, Ki-Chang;Lee, Hae-Hyoung;Oh, Sang-Chun;Dong, Jin-Keun;Cha, Yong-Youp;Byun, Tae-Gang
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.741-745
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    • 2002
  • Yttria-stabilized zirconia(YSZ) nanopowders were prepared by sol-gel method using zirconium-n-butoxide(ZNB) and yttrium nitrate as precursors. In addition, the effect of water content added during the hydrolysis reaction of ZNB was investigated on the phase composition and pore structure of the product powders. The phase composition of YSZ nanopowders with calcination temperatures showed the same trend, irrespective of $H_2O$ amounts added during the hydrolysis reaction of ZNB. All powders dried at $100^{\circ}C$ were amorphous and transformed to cubic phase at $400^{\circ}C$, which converted to tetragonal phase at $1,000^{\circ}C$. Monoclinic phase also appeared at $1,000^{\circ}C$. The powders showed the mixture of tetragonal and monoclinic phases from $1,000^{\circ}C$ to $1,400^{\circ}C$. The pore size distributions of the dried powders prepared with small amounts of water(less than or equal to $H_2O/ZNB=20$) showed mesopores, while those prepared with large amounts of water(greater than or equal to $H_2O/ZNB=50$) exhibited micropores.

Effect of Pore Structure Change on the Adsorption of NOM and THMs in Water Due to the Increase of Reactivation Number of Coal-based Activated Carbon (석탄계 활성탄의 재생 횟수 증가에 따른 세공 구조 변화가 수중의 NOM과 THM 흡착에 미치는 영향)

  • Son, Hee-Jong;Ryu, Dong-Choon;Jang, Seong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.965-972
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    • 2010
  • The objective of this research was to evaluate for the changes of pore structures and adsorption capacities due to the increase the numbers of reactivation. The reactivated GAC had experienced three cycles of water treatment and thermal reactivation. The pore size distributions of virgin and reactivated GACs were very different. The virgin GAC was mostly microporous (< $15\;{\AA}$), with less mesopores ($20{\sim}100\;{\AA}$). The reactivated GACs was mostly mesoporous ($20{\sim}100\;{\AA}$), with less micropores (< $15\;{\AA}$). The specific surface area and total pore volume were reduced as the number of reactivation increased. The maximum adsorption capacity (X/M) of virgin GAC ($964.6\;{\mu}g/g$) for $CHCl_3$ was 2~3 times larger than 1st~3rd reactivated GAC ($255.6{\sim}399.5\;{\mu}g/g$). The maximum adsorption capacity (X/M) of virgin GAC (19.5 mg/g) for DOC (dissolved organic carbon) was equal to that of 1st~3rd reactivated GAC (18.0~18.7 mg/g).

Comparisons of Drainage Performance on Coarse Grained Soils with Regard to Horizontal Drainage Type (조립질 지반에서의 수평배수재 종류에 따른 배수성능 비교)

  • Teawan Bang;Wanjei Cho;Seunghwan Seo
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.11
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    • pp.25-31
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    • 2023
  • Horizontal drainage, which are representative dewatering method of domestic and foreign slope, are applied to reducing pore water pressure. Accordingly, several previous studies have been conducted, but horizontal drainage are standardized which is an unclean standard for a quantity calculation in filed. Therefore, this study presents field soil and laboratory model box to identify a drainage performance and influencing factors of various horizontal drainage. Furthermore, this study verifies the performance comparison of drainage shape or size according to different particle size distributions. In the outflow results for steady state, the study found that all samples are drained at a constant rate after a minimum of 3 minutes to maximum of 15 minutes. In the case of comparing the outflow per hour (Unit flux) in coarse grained soils, it found that drainage shape and size affect drainage performance. In the result, the future expected to be used basic data that experiment of drainage performance on fine grained soils and determine the quantity.

Techniques to Estimate Permeability Based on Spectral Induced Polarization Survey (광대역유도분극 탐사에 기초한 유체투과도 예측기법들)

  • Kim, Bitnarae;Cho, AHyun;Weller, Andreas;Nam, Myung Jin
    • Journal of Soil and Groundwater Environment
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    • v.25 no.2_spc
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    • pp.55-69
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    • 2020
  • Permeability-analyzing methods commonly involve small-scale drilling, such as pumping or slug test, but it is difficult to identify overall distribution of permeability of the entire target sites due to high cost and time requirement. Spectral induced polarization (SIP) method is known to be capable of providing distributions of both the porosity and the pore size, the two major parameters determining permeability of the porous medium. The relationship between SIP variables and permeability has been studied to identify the hydrological characteristics of target sites. Kozeny-Carman formula has been improved through many experiments to better predict fluid permeability with electrical properties. In this work, the permeability prediction techniques based on SIP data were presented in accordance with the hydrogeological and electrical characteristics of a porous medium. Following the summary of the techniques, various models and related laboratory experiments were analyzed and examined. In addition, the field applicability of the prediction model was evaluated by field case analysis.

Preparation of Mesoporous Molecular Sieve by the Reaction of Na2SiO3 and H2SiF6 in the Presence of an Aqueous Nonionic Surfactant Solution (비이온성 계면활성제 수용액에서 Na2SiO3와 H2SiF6의 반응을 통한 메조포러스 실리카의 제조)

  • Kim, Jin-Yeong;Kwon, Oh-Yun
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.122-126
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    • 2018
  • Mesoporous molecular sieves were prepared by the reaction of $Na_2SiO_3$ and $H_2SiF_6$ using nonionic micelle templates in an aqueous solution. Well-crystalline mesoporous molecular sieves were obtained after several seconds at atmospheric conditions. Powder samples exhibited d-spacing of 3.8-5.1 nm with the sharpness of the d00l peak, showing well-crystalline mesoporous molecular sieves, pore size distributions of 2.5-3.1 nm and large specific surface areas of $290-1,018m^2/g$, depending on types of surfactants. SEM images of samples showed well-divided spherical particles with an uniform size of ${\sim}0.5{\mu}m$ and TEM images demonstrated uniform pores with a worm hole shape.

Electrochemical Behavior of Pt-Ru Catalysts on Zeolite-templated Carbon Supports for Direct Methanol Fuel Cells

  • Lim, Tae-Jin;Lee, Seul-Yi;Yoo, Yoon-Jong;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3576-3582
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    • 2014
  • Zeolite-templated carbons (ZTCs), which have high specific surface area, were prepared by a conventional templating method using microporous zeolite-Y for catalyst supports in direct methanol fuel cells. The ZTCs were synthesized at different temperatures to investigate the characteristics of the surface produced and their electrochemical properties. Thereafter, Pt-Ru was deposited at different carbonization temperatures by a chemical reduction method. The crystalline and structural features were investigated using X-ray diffraction and scanning electron microscopy. The textural properties of the ZTCs were investigated by analyzing $N_2$/77 K adsorption isotherms using the Brunauer-Emmett-Teller equation, while the micro- and meso-pore size distributions were analyzed using the Barrett-Joyner-Halenda and Harvarth-Kawazoe methods, respectively. The surface morphology was characterized using transmission electron microscopy and inductively coupled plasma-mass spectrometry. The electrochemical properties of the Pt-Ru/ZTCs catalysts were also analyzed by cyclic voltammetry measurements. From the results, the ZTCs carbonized at $900^{\circ}C$ show the highest specific surface areas. In addition, ZTC900-PR led to uniform dispersion of Pt-Ru on the ZTCs, which enhanced the electro-catalytic activity of the Pt-Ru catalysts. The particle size of ZTC900-PR catalyst is about 3.4 nm, also peak current density from the CV plot is $12.5mA/cm^2$. Therefore, electro-catalytic activity of the ZTC900-PR catalyst is higher than those of ZTC1000-PR catalyst.