• Title/Summary/Keyword: pore size distribution

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A Study on Selective Adsorption of Phenanthrene Dissolved in Triton X-100 Solution using Activated Carbons (활성탄을 이용한 Triton X-100 용액에서의 phenanthrene의 선택적 흡착에 관한 연구)

  • Ahn, Chi-Kyu;Kim, Young-Mi;Woo, Seung-Han;Park, Jong-Moon
    • Journal of Soil and Groundwater Environment
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    • v.11 no.2
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    • pp.13-21
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    • 2006
  • Polycyclic aromatic hydrocarbons (PAHs) are widespread soil contaminants and major environmental concerns. PAHs have extremely low water solubility and are strongly sorbed to soil. A potential technology for remediation of PAHcontaminated soils is a soil washing with surfactant solutions. While the use of surfactants significantly enhances the performance of soil remediation, operation costs are increased. Selective adsorption of PAHs by activated carbons is proposed to reuse the surfactants in the soil-washing process. The adsorption isotherms of pure chemicals (Triton X-100 and phenanthrene) onto three granular activated carbons were obtained. The selective adsorption of phenanthrene in mixed solution was examined at various concentrations of phenanthrene and Triton X-100. The selectivity results were discussed with pore size distribution of activated carbons and molecular sizes of phenanthrene and the Triton X-100 monomer. The selectivity for phenanthrene was much larger than 1 regardless of the particle size of activated carbons. The selective adsorption using activated carbons with proper pore size distribution would greatly reduce the material cost for the soil washing process by the reuse of the surfactants.

Quantitative Evaluation of Geotextile Void Structures Using Digital Image Analysis (디지털 이미지 분석을 이용한 지오텍스타일 공극 분포의 정량화)

  • Kim, Duhwan
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.1
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    • pp.51-61
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    • 2013
  • This paper presents results from a study undertaken to quantitatively evaluate the geotextile pore sizes using optical image analysis. The evaluation was conducted by observing surfaces of coupons cut from resin-impregnated specimens of geotextile-geomembrane layered under various load conditions. Stereological concepts were applied to collect representative specimens from a series of laboratory tests. The sizes of voids enclosed by filaments were expressed in terms of the largest inscribing opening size (LIOS) distribution. The opening diameter corresponding to the 50% cumulative frequency decreased by about 45mm as the load increased from 10 to 300kPa and recovered to about 90% of its initial state on unloading back to 10kPa. The average void size was reduced by 32 and 16.5% as the geotextile was sheared against a textured geomembrane under normal stresses of 100 and 300kPa, respectively. The results showed how the LIOS distribution varied as a function of normal stress and interface shear displacement against a smooth and a textured geomembrane surfaces.

Flocculation Efficiency and Particle Distribution of Total Suspended Solids in the Effluent from Semi-recirculating Aquaculture Systems Treated with Polymers (고분자 응집제를 이용한 반순환여과양식시스템의 배출수 내 고형물 응집 효율 및 입도 분포)

  • Seo, Junhyuk;Woon, Sungchun;Kim, Jisoo;Park, Jeonghwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.55 no.1
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    • pp.10-16
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    • 2022
  • Interest in effluent treatment is currently increasing and the use of polymetric coagulants is considered as a pretreatment of physical filtration prior to effluent discharge to increase solids recovery. A jar test evaluated effluent treatment efficiency of polymeric coagulants for semi-recirculating aquaculture systems. The particle coagulation efficiency and distribution were evaluated at different polymer dosages in freshwater and seawater effluents. The polymer was added at 0.005-0.08 mL/g of total suspended solids (TSS) in the effluents. TSS in the supernatant after coagulation decreased with increasing polymer dose in the freshwater, while showing no corresponding changes with dose in the seawater. However, in all treatments for both effluents, the removal efficiency was above 90%, regardless of the dose in the tested range. Both the De Brouckere Mean Diameter (DBMD) and volumetric median diameter (VMD) were all above 100 ㎛ in the freshwater effluent. In the seawater effluent, the particle size appeared to be larger than that in freshwater, ranging from 400-1,000 ㎛ for both DBMD and VMD. Considering that the typical pore size of physical filtration in aquaculture is between 60 and 200 ㎛, the use of polymers is expected to improve the practicality of physical filtration for efficient treatment.

Detectability of Pore Defect in Wind Turbine Blade Composites Using Image Correlation Technique (이미지 상관 기법을 이용한 풍력 발전 블레이드용 복합재료의 기공 결함 검출능)

  • Kim, Jong Il;Huh, Yong Hak;Lee, Gun Chang
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.10
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    • pp.1201-1206
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    • 2013
  • Defects that occur during the manufacturing process or operation of a wind turbine blade have a great influence on its life and safety. Typically, defects such as delamination, pore, wrinkle and matrix crack are found in a blade. In this study, the detectability of the pores, a type of defect that frequently occur during manufacturing, was examined from the full field strain distribution determined with the image correlation technique. Pore defects were artificially introduced in four-ply laminated GFRP composites with $0^{\circ}/{\pm}45^{\circ}$ fiber direction. The artificial pores were introduced in consideration of their size and location. Three different-sized pores with diameter of 1, 2 and 3 mm were located on the top and bottom surface and embedded. By applying static loads of 0-200 MPa, the strain distributions over the specimen with the pore defects were determined using image correlation technique. It was found the pores with diameter exceeding 2 mm can be detected in diameter.

Preparation and Characterization of Porous Sintered Body Made from Coal Bottom Ash and Dredged soil (석탄(石炭) 바닥재와 준설토(浚渫土)를 이용한 다공성(多孔性) 소결체(燒結體)의 제조 및 특성 평가)

  • Kim, Kang-Duk;Kang, Seung-Gu
    • Resources Recycling
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    • v.19 no.1
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    • pp.33-39
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    • 2010
  • The spheric sintered body with $6{\pm}2mm$ diameter was manufactured in a rotary kiln at $1125^{\circ}C$/15 min using green body formed by pelletizing the batch powder composing of coal bottom ash produced from power plant and dredged soil by 70:30, wt%. And the physical properties of sintered body (BD) were analyzed to confirm the possibility for applying to an absorbent to restore a contaminated soil. The sintered body had a giant pore above 100 ${\mu}m$ and a fine pore below 10 ${\mu}m$, and bulk density was 1.4. Also its specific surface area, porosity and void proportion were $12.0m^2/g$, 30.1% and 38.2% respectively. The crushed body (BD-C), produced by crushing a BD specimen into an irregular shape with a aspect ratio of about 2, was similar to BD specimen at bulk density and pore size distribution. But it had superior values of specific surface area, porosity and void proportion compared with BD specimen owing to a decreased apparent volume due to conversion of closed pore existed at interior of BD to open pore during a crushing process. The IEP of sintered body occurred at about pH=5, so the optimum pH condition of reacting aqueous solution could be known before bonding a microbe to the sintered body. Hence, the optimum void proportion and porosity of an absorbent can be obtained by appropriate mixing a BD with BD-C from the base data calculated in this study.

Particle Size-Related Dust and Quartz Concentration of Stone Grinding Operations (석재가공 공정에서 발생되는 분진과 석영의 입자크기별 농도 특성)

  • Kim, Seong-Hwan;Bae, Hye Jeong;Jung, Jong-Hyon;Phee, Young Gyu
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.462-470
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    • 2014
  • Objectives: The purpose of this study was to evaluate quartz concentrations in airborne respirable dust and particle size-related quartz concentrations. Methods: Respirable dust samples were collected using a 10 mm Dorr-Oliver nylon cyclone equipped with a 37 mm, $5{\mu}m$ pore size PVC filter. Dust samples were collected with a Marple's personal cascade impactor from stone grinding operations in five stone-related business located in the Gyeongsangbuk-do area. Results: The geometric mean of quartz concentration in the respirable dust was $0.170mg/m^3$, and the rate of exceeding the Korean Occupational Exposure Limit(KOEL) was 93.3%. The quartz concentration by particle size shows that it was the highest($0.115mg/m^3$) in stage 5($3.50-6.00{\mu}m$), which corresponds with the size of respirable particle. The smaller the particle sizes were, the higher quartz the content became. The mass fractions of inhalable, thoracic, and respirable dust were 72.1%, 36.0%, and 14.4%. Conclusions: The rate of the quartz concentration in respirable dust from stone grinding operations exceeding the American Conference of Governmental Industrial Hygienists Threshold Limit Values was 100%, which means proper work environmental management is required through regular working environmental measurements. Given that the stone grinding operations had a higher small size dust concentrations, there is a need to reduce respirable dust, such as through wet operation and local exhaust ventilation.

Preparation of Silica Particles by Emulsion-Gel Process Using Membrane Emulsification (막유화 에멀젼-겔 공정에 의한 실리카 입자의 제조)

  • Yeon, Song-Hee;Youm, Kyung-Ho
    • Membrane Journal
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    • v.20 no.2
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    • pp.87-96
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    • 2010
  • We prepared spherical silica particles by controlling various conditions of emulsion-gel procedure using a lab-scale membrane emulsification system equipped with SPG (Shirasu porous glass) membrane having pore size of 2.6 ${\mu}m$. We determined the effects of process parameters of membrane emulsification (dispersed phase pressure, stabilizer and emulsifier concentration in continuous phase, $H_2O$/TEOS ratio, ratio of dispersed phase to continuous phase) on the mean size and size distribution of silica particles. The increase of the dispersed phase pressure and ratio of dispersed phase to continuous phase led to the increase in the mean size of silica particles. On the contrary, the increase in stabilizer and emulsifier concentration and $H_2O$/TEOS ratio caused the reduction of the mean size of particles. Through controlling these parameters, monodisperse spherical silica particles with about 3 ${\mu}m$ of the mean size were finally prepared.

Preparation of Silica Microgels Using Membrane Emulsification Method (막유화법을 이용한 실리카 마이크로겔의 제조)

  • Youm, Kyung-Ho;Kwak, No-Shin
    • Membrane Journal
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    • v.19 no.2
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    • pp.122-128
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    • 2009
  • We prepared monodispersed spherical silica microgels by controlling various conditions of emulsification procedure using a lab-scale membrane emulsification system equipped with SPG (Shirasu porous glass) porous membrane having pore size of $1.5{\mu}m$. We determined the effects of process parameters of membrane emulsification (ratio of dispersed phase to continuous phase, sodium silicate concentration, emulsifier concentration, dispersed phase pressure, stirring speed) on the mean size and size distribution of silica microgels. The increase of the ratio of dispersed phase to continuous phase, dispersed phase pressure and sodium silicate concentration led to the increase in the mean size of microgels. On the contrary, the increase in emulsifier concentration and stirring speed of the continuous phase caused the reduction of the mean size of microgels. Through controlling these parameters, monodisperse spherical silica microgels with about $6{\mu}m$ of the mean size were finally prepared.

Preparation and Characterization of the Asymmetric Microporous Poly(vinylidene fluoride) (PVDF) Blend Membranes with Hydrophilic Surfaces

  • Hwang, Jeong-Eun;JeGal, Jong-Geon
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.1-11
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    • 2007
  • To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.

EFFECT OF COATING COMPOSITION IN DOUBLE COATING ON THE PENETRATION OF FINE PARTICLES INTO SUBSTRATE

  • Kim, Byeong-Soo;Douglas W. Bousfield
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.1-11
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    • 2000
  • The influence of the first coating layer on the properties of the second coating layer is reported. For various model coating composition, ratios of first and second coating weights are used to generate coating layers. The void volume, pore size distribution and light scatter coefficient of the coatings are measured. In some cases, the fine material from the second layer seems to penetrate the first layer to reduce the void fraction of the total system. Rapid setting coating, for example thin layers on porous first layer tends to generate porous coating layers.

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