• Title/Summary/Keyword: pore distribution

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The Effect of PVA-Al(III) Complex on Pore Formation and Grain Growth of $UO_2$ Sintered Pellet (II) (PVA-A(III) 착물이 $Uo_2$ 소결체의 기공형성과 결정립성장에 미치는 영향(II))

  • 이신영;김형수;노재성
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.782-790
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    • 1999
  • The compressibility sinterability sintering behaviour and thermal stability of AlOOH added UO2 pellt and PVA-Al(III) complex added UO2 pellet were investigated respectively. Compared with characteristics of AlOOH added UO2 pellet the green density and the sintered density of PVA-Al(III) complex added UO2 pellet were lowered but the grain size and the pore size of that were more increased in accordance with higher compacting pressure. The AlOOH added UO2 pellet had the grain size of about 14${\mu}{\textrm}{m}$ with monomodal pore size distribution while the PVA-Al(III) complex added UO2 pellet had the grain size of about 42 ${\mu}{\textrm}{m}$ with bimodal pore size distribution. The PVA-A(III) complex added UO2 pellet had a similiar open porosity to the AlOOH added UO2 pellet and a lower resintered density change than the AlOOH added UO2 pellet.

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The Rehydration Properties of Amorphous Alumina Powder in Low Water/Alumina Ratio (낮은물/알루미나 비에서 비정질 알루미나 분말의 수화특성)

  • 박병기;서정권;이정민;서동수
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1085-1093
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    • 1998
  • Amorphous alumina powder prepared by the fast calcination of aluminum trihydroxide(Al(OH)3 gibbsite) for 0.5 second at 580$^{\circ}C$ was investigated rehydration propeties. Phase composition crystal size and mor-phology surface area pore volume and pore size distribution of pesudo-boehmite and bayerite crystals changed with temperature time water/alumina ratio and particle size when amorphous alumina rehydrated with water. Phase compositions were examined with XRD and DTA and crystal sized morphologies were investigaed with SEM and TEM. Also rehydration properties of amorphous alumina were in-vestigated by measuring the surface area pore volume and pore size distribution.

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A Study on the Micropores of BTCA Finished Cotton Fabrics (BTCA로 방추가공된 면직물의 미세기공구조 측정)

  • 최연주;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.7
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    • pp.1078-1084
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    • 2002
  • Cotton fabrics were treated with 1,2,3,4-butanetetracarboxylic acid(BTCA) to impart durable press performance, which is formaldehyde-free DP finishing reagent. The pore structures of BTCA treated cottons were compared using a reverse gel permeation chromatographic technique(reverse GPC). A series consisting 4 kinds of water soluble sugars was used to study the elution characteristics of columns prepared from cotton fibers. From these data, differences in pore size distribution in the control and BTCA treated cottons were distinguished. BTCA crosslinks cellulose molecules provided wrinkle resistance to the treated cotton fabrics through ester linkages. Although crosslinking of cotton with BTCA reduced accessible internal volume across the entire range of pore size, differences in line pores were larger than in small pores. BTCA treated cotton exhibited reductions over 40% in large pore sizes.

Effect of Vapor Pressure of Adsorbate on Adsorption Phenomena (흡착질의 증기압이 흡착에 미치는 영향)

  • Kim, Sang-Won;Kwon, Jun-Ho;Kang, Jeong-Hwa;Song, Seung-Koo
    • Journal of Environmental Science International
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    • v.17 no.1
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    • pp.67-75
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    • 2008
  • Adsorption process is largely influenced by pore structures of adsorbents and physical properties of adsorbates and adsorbents. The previous studies of this laboratory was focused on the role of pore structures of adsorbents. And we found some pores of adsorbates which have larger pore diameters than the diameter of adsorbate are filled with easily. In this study the effects of physical and chemical properties of adsorbates and adsorbents, such as pore size distribution, vapor pressure on adsorption were investigated more thoroughly at the concentration of adsorbate of 1000 ppm. The adsorption in the pore ranges of $2{\sim}4$ times of adsorbates's diameter could be explained by space filling concept. But there was some condensation phenomena at larger pore ranges. The errors between the adsorbed amount of non-polar adsorbates and the calculated amounts by considering factors were found to be 44.46%, positively, and -142%, negatively. When vapor pressure is considered, the errors between the adsorbed amount of non-polar adsorbates and the calculated amounts were in the range of $1.69%{\sim}32.25%$ positively, and negatively $-1.08%{\sim}-63.10%$.

Analysis of Pore Structure for Porous Body with Coal Fly ash and Clay (석탄회-점토계 다공체의 기공구조 분석)

  • 이기강;박천주
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.64-70
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    • 1998
  • Porous body was prepared from coal fly ash 70 wt%0clay 30 wt% slip using DCC(Direct Coagulated Casting) method. Effect of the specific gravity of the slip on the pore size and distribution of the sintered body was examined by the SEM observation of microstructure and mercury porosimetry measurement of the pore size distribution. Average pore size of the porous sintered body was about 2.5μm for all slips with specific gravity of 1.55, 1.60 and 1.65g/cm3, respectively. Sintered body prepared from the slip of specific gravity of 1.60g/cm3 have the narrowest pore size distribution. slip of specific gravity of 1.55g/cm3 shows broader pore size distribution due to slow gellation process. Slip of specific gravity of 1.65g/cm3 required large amount of deflocculant and showed large variation of the viscosity with addition of coagulant which resulted in very unstable slip properties.

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Comparison of pore analysis techniques of the paper (종이의 Pore 특성 측정 기법의 비교)

  • Nam, Ki-Young;Chung, Sun-Ki;Won, Jong-Myoung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2007.11a
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    • pp.179-186
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    • 2007
  • The best way to understand paper properties is to study paper structure. Paper is composed solid materials (pulp and other additives) and air three-dimensionally, it's important to understand pore structure of the paper. There are several method to analysis pore structure of the paper. Mercury intrusion technique is frequently used for the characterization of the porous paper, giving access to parameters such as pore size and pore distribution. But some researchers indicated mercury intrusion distorts the structure due to application of high pressure. So this paper suggest new analysis technique to pore structure of the paper. New pore analysis technique with SEM does not require high pressure, gives good resolution and measures pore structure.

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Effect of pore characteristics of activated carbon on adsorption of natural organic matter (활성탄의 세공이 자연유기물질의 흡착에 미치는 영향)

  • Pak, Jung-Sun;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.249-255
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    • 2011
  • It is complicate problem to optimize removing natural organic matter (NOM) by activated carbon in drinking water treatment because the activated carbon has heterogeneous surface area and pore structure. Seven different coals based activated carbons which have different pore structures were used in the study. Sand filtered effluents which normally used as GAC adsorber influent were used. The molecular weight distribution showed that most of the NOM was bigger than 10,000Da. In this study, systematical approaches such as characteristics of surface area and pore volume were evaluated on NOM adsorption. Especially, the adsorption capacities for NOM were evaluated by effect of micro-pores and meso-pores in surface area and pore structure. The results show that the higher ratio of meso-pore compare to the micro-pore has not only the better adsorption capacities for NOM but also the higher strongly-adsorbable fraction. Therefore, the overall adsorption capacity is increased with higher meso-pore ratio with existing of reasonable micro-pore surface area and volume.

Pore Structure of Non-Sintered Cement Matrix (비소성 시멘트 경화체의 공극구조)

  • Mun Kyoung-Ju;Park Won-Chun;Soh Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.329-332
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    • 2004
  • This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the pore structure of NSC Matrix. The result of experiment of pore structure properties, showed no considerable difference for total pore volume by cement mixing ratio but shows a large distinction in distribution of pore diameter. On the whole, pore-diameter of paste of NSC show that occupation ratio of pore diameter below 10mm is larger and is smaller than OPC and BFSC at pore diameter of over 10nm. Such a reason is that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Studies on the Pore of Coating Layer and Printability(III) -Effects of Properties of Latices on Pore of Coating Layer- (도공층의 공극과 인쇄적성에 관한 연구(제3보) -라텍스의 특성이 미치는 영향-)

  • 이용규;김창근
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.2
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    • pp.41-48
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    • 2001
  • This paper was made to evaluate the effect of the type of latex for coating on the printability by investigating the structure of pore such as the pore fraction, the number of pores, pore size and distribution of coated paper. The coated structure is mainly depend on the results of interaction between pigment and binder. It means that the structure of pore formed is chiefly affected by the type of latex. This physical properties of pore have a close relation with ink set-off associated with the drying rate, the speed of penetration of ink into base paper and printing gloss. Therefore it was necessary to find out the relationship between pore structure and the performance of printability by modifying the type of latex to vary the pore structure of coated paper. Acrylic latex was superior to S/B latex in the sedimentation volume, compressibility, smoothness, pore fraction and its number, the weight of transferred ink onto the coated paper and ink repellance. In contrast, water retention and ink setting were not good. in the comparison of anionic and amphoteric latex, amphoteric latex showed better performance in the thickness, smoothness, pore fraction and its number, pore size, the weight of ink transmitted and K&N ink receptivity, etc.

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The Relationship between Microstructure and Freezing Thawing Resistance of Polymer-Cement Mortars (폴리머-시멘트 모르타르의 미세구조 동결융합 저항성의 관계)

  • ;;田英治(Eiji Kamada)
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.949-956
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    • 1994
  • In order to investigate the relationship between pore size distribution and freezing-thawing resistance of mortars, polymer-cement mortars were prepared by using styrene-butadiene rubber latex, ethylene-vinyl acetate emulsion and polyacrylic ester emulsion with various polymer-cement ratios at constant flow. From the results of the test, polymer-cement mortars had a good pore size distribution for freezing-thawing resistance compared with unmodified mortars because of having a small pore volume in the pore radius range of 103~104 $\AA$ affecting on the frost damage. And the freezing-thawing resistance of polymer-cement mortars was improved with increasing polymer-cement ratio.

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