• Title/Summary/Keyword: pore

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Influence of Hot Pressing on the Pore Structure of Nafion Electrolyte Membrane Investigated by 1H NMR

  • Jeonga, Soon-Yong;Han, Oc-Hee
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1559-1562
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    • 2009
  • The influence of hot pressing on the pore structures of Nafion membranes was investigated by observing the Nafion before and after hot pressing with $^1H$ nuclear magnetic resonance (NMR) spectroscopy. The freezing point depression and chemical shift data of water in the Nafion indicated the presence of two different pore size ranges in Nafion. Hot pressing mainly reduced the sizes and number of the big pores. The reduction of water uptake and proton conductivity after hot pressing was explained by this variation of pore size and number. We demonstrated the potential application of chemical shift data and NMR cryoporometry experiments to measure the relative pore sizes, on a nano scale, and numbers.

Fabrication of Metal Nanohoneycomb Structures and Their Tribological Behavior

  • Kim, Sung-Han;Lee, Sang-Min;Choi, Duk-Hyun;Lee, Kun-Hong;Park, Hyun-Chul;Hwang, Woon-Bong
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.101-110
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    • 2008
  • Metal nanohoneycomb structures were fabricated by E-beam evaporation and a two-step anodization process in phosphoric acid. Their tribological properties of adhesion and friction were investigated by AFM in relation to the pore size of the nanohoneycomb structures. Variations of the adhesive force are not found with pore size, but formation of the pore greatly reduces the adhesive force compared to the absence of pore structure. The coefficient of friction increased nonlinearly with pore size, due to surface undulation around the pore. Tribological properties do not differ greatly between the original nanohoneycomb structure and the metal nanohoneycomb structure.

A Study on Manufacturing Problem Solving of Scaffold with Pore Using 3SC Practical TRIZ and Machine Learning (3SC 실용트리즈와 머신러닝을 이용한 기공을 가진 인공지지체 제조문제 해결에 관한 연구)

  • Lee, Song-Yeon;Huh, Yong Jeong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.25-30
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    • 2019
  • In this paper, we have analyzed manufacturing problems of the scaffold with pores using FDM 3D printer and PLGA. We suggested the solutions using 3SC practical TRIZ. We selected the final solution used machine learning. We reduced number of experiments using most influential factor after analysis print factors. We printed the scaffold and measured pore size. We created the regression model using python tensorflow. The print condition data of measured pore size was used as training data. We predicted the pore size of printed condition using regression model. We printed the scaffold using the predicted the print condition data. We quantitatively compare the predicted scaffold pore size data and the measured scaffold pore size data. We got satisfactory result.

Finite Element Simulation of a Pore Closing Process during Upsetting in Open Die Forging (자유단조에서 업세팅 공정 중 기공 압착 과정의 유한요소 시뮬레이션)

  • Lee, M.C.;Cho, J.H.;Choi, I.S.;Jang, S.M.;Joun, M.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.79-83
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    • 2008
  • We carry out three-dimensional simulation of pore closing processes during upsetting in open die forging. Several pores on a plane section of a cylindrical material are traced at the same time and the results of hydrostatic pressure and effective strain are discussed to reveal the parameters affecting pore closing phenomena. Five different sizes of pores are also investigated by simulation to reveal the pore size effect in pore closing during upsetting. AFDEX 3D is employed for this study.

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An Improved Method of Pore Size Distribution Analysis

  • Cho, Hyun-Woo;Ahn, Woon-Sun;Halsey, G. D.
    • Bulletin of the Korean Chemical Society
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    • v.9 no.2
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    • pp.94-98
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    • 1988
  • An improvement over the method of pore size distribution analysis has been made in this work. The improved method is based upon the idea of the micro pore analysis of Mikhail, Brunauer, and Bodor, and utilizes the V-t curve of nitrogen adsorption. Two pore models are assumed, and the deviation of the initial slope of the V-t plot is ascribed to the pore filling and to the adsorption on the wall of unfilled pores. The improved method of this work is very convenient in that the analysis starts from the small pore regions. The method of this work is however quite distinct from the similar V-t plot method proposed by Sellevold and Radjy. The proposed method is applied to a few adsorbents, and very satisfactory results are obtained. The cumulative surface area calculated by this method also agrees very well with those obtained by the BET plot or by the t-method.

Research on chloride ion diffusivity of concrete subjected to CO2 environment

  • Zhang, Shiping;Zhao, Binghua
    • Computers and Concrete
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    • v.10 no.3
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    • pp.219-229
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    • 2012
  • Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

A Study on the Pore Pressure Dissipation Test of the Piezocone (피에오콘의 간극수압 소산시험에 관한 연구)

  • 황대진;김철웅
    • Geotechnical Engineering
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    • v.13 no.6
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    • pp.25-36
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    • 1997
  • A degree of consolidation at any time can be evaluated by using cone penetration test after soil improvement. In this case, after stopping the penetration of a piezocone, pore pressure dissipation(PPD) best is carried out until the pore pressure remains constant. Since the hydraulic conductivity of soft ground is very small, it takes very long time to finish the PPD test. This research is performed to develop a method overcoming this problem of the PPD test and reducing the test time. The analyses are carried out in the following ways : an equilibrium pore pressure can be determined by using pore pressure measured in the middle of the test, which is predicted by hyperbolic, Asaoka and Hoshino methods. And this equilibrium pore pressure is compared with the one measured in a test of long duration. As a result of the study, it is found that Hoshino method is the best way to predict the equilibrium pore pressure in a teat of short duration. And it is proposed as a methodology to fond a minimal time in which we can get an equilibrium pore pressure.

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Computer Tomography as a Tool for Physical Analysis in an Anthropogenic Soil

  • Chun, Hyen Chung;Park, Chan Won;Sonn, Yeon Kyu;Cho, Hyun Joon;Hyun, Byung Keun;Song, Kwan Cheol;Zhang, Yong Seon
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.549-555
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    • 2013
  • Human influence on soil formation has dramatically increased as the development of human civilization and industry. Increase of anthropogenic soils induced research of those soils; classification, chemical and physical characteristics and plant growth of anthropogenic soils. However there have been no reports on soil pore properties from the anthropogenic soils so far. Therefore the objectives of this study were to test computer tomography (CT) to characterize physical properties of an anthropogenic paddy field soil and to find differences between natural and anthropogenic paddy field soils. Soil samples of a natural paddy field were taken from Ansung, Gyeonggi-do (Ansung site), and samples of an anthropogenic paddy field were from Gumi in Gyeongsangnam-do (Gasan) where paddy fields were remodeled in 2011-2012. Samples were taken at three different depths and analyzed for routine physical properties and CT scans. CT scan provided 3 dimensional images to calculate pore size, length and tortuosity of soil pores. Fractal analysis was applied to quantify pore structure within soil images. The results of measured physical properties (bulk density, porosity) did not show differences across depths and sites, but hardness and water content had differences. These differences repeated within the results of pore morphology. Top soil samples from both sites had greater pore numbers and sizes than others. Fractal analyses showed that top soils had more heterogeneous pore structures than others. The bottom layer of the Gasan site showed more degradation of pore properties than ploughpan and bottom layers from the Ansung site. These results concluded that anthropogenic soils may have more degraded pore properties as depth increases. The remodeled paddy fields may need more fundamental remediation to improve physical conditions. This study suggests that pore analyses using CT can provide important information of physical conditions from anthropogenic soils.

Prediction of Soil-Water Characteristic Curve and Relative Permeability of Jumunjin Sand Using Pore Network Model (공극 네트워크 모델을 이용한 주문진표준사의 함수특성곡선 및 상대투수율 예측에 관한 연구)

  • Suh, Hyoung Suk;Yun, Tae Sup;Kim, Kwang Yeom
    • Journal of the Korean Geotechnical Society
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    • v.32 no.1
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    • pp.55-62
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    • 2016
  • This study presents the numerical results of soil-water characteristic curve for sandy soil by pore network model. The Jumunjin sand is subjected to the high resolution 3D X-ray computed tomographic imaging and its pore structure is constructed by the web of pore body and pore channel. The channel radius, essential to the computation of capillary pressure, is obtained based on the skeletonization and Euclidean Distance transform. The experimentally obtained soil-water characteristic curve corroborates the numerically estimated one. The pore channel radius defined by minimum radii of pore throat results in the slightly overestimation of air entry value, while the overall evolution of capillary pressure resides in the acceptable range. The relative permeability computed by a series of suggested models runs above that obtained by pore network model at high degree of saturation.

Dynamic Characteristics of Gravity Quay Wall during Generation of Excess Pore Pressure in Backfill Soils (뒤채움지반에서의 과잉간극수압 발생이 중력식 안벽구조물의 동적특성에 미치는 영향 분석)

  • Hwang Jae-Ik;Kim Myoung-Mo
    • Journal of the Korean Geotechnical Society
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    • v.21 no.1
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    • pp.123-131
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    • 2005
  • In this research, shaking table tests for three types of gravity quay wall system were performed to analyze the influence of excess pore pressure in backfill soils on the natural frequency of gravity quay wall systems. The elastic modulus of backfill soils was also estimated from the back analyses using the results of the shaking table tests. From the test results, it was observed that as the magnitude of excess pore pressures increased, the natural frequency of the gravity quay wall system decreased and vice versa. The natural frequency was about 44Hz when no excess pore pressure was generated in backfill soils, and decreased to about 16Hz at the pore pressure ratio of 0.55. The elastic modulus of backfill soils reached the constant maximum value when the pore pressure ratio was less than 0.2, and abruptly decreased as the pore pressure ratio became larger than that. The elastic modulus of backfill soils decreased to $10\%$ of the maximum value when the pore pressure ratio was 0.55.