• 제목/요약/키워드: polyvinyl acetate

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Glucose Sensing Properties of Electrospinning-Synthesized ZnO Nanofibers (전기방사로 합성된 산화아연 나노섬유의 Glucose 감응특성)

  • Choi, Jong-Myoung;Byun, Joon-Hyuk;Kim, Sang Sub
    • Korean Journal of Materials Research
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    • v.25 no.12
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    • pp.655-658
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    • 2015
  • The development of glucose biosensors has been attracting much attention because of their importance in monitoring glucose in the human body; such sensors are used to diagnose diabetes and related human diseases. Thanks to the high selectivity, sensitivity to glucose detection, and relatively low-cost fabrication of enzyme-immobilized electrochemical glucose sensors, these devices are recognized as one of the most intensively investigated glucose sensor types. In this work, ZnO nanofibers were synthesized using an electrospinning method with polyvinyl alcohol zinc acetate as precursor material. Using the synthesized ZnO nanofibers, we fabricated glucose biosensors in which glucose oxidase was immobilized on the ZnO nanofibers. The sensors were used to detect a wide range of glucose from 10 to 700 M with a sensitivity of $10.01nA/cm^2-{\mu}M$, indicating that the ZnO nanofiber-based glucose sensor can be used for the detection of glucose in the human body. The control of nanograins in terms of the size and crystalline quality of the individual nanofibers is required for improving the glucose-sensing abilities of the nanofibers.

Preparation and Dissolution Characteristics of A Gastro-Retentive Tablet System Containing Gabapentin (가바펜틴을 함유한 위체류성 정제의 제조 및 용출 평가)

  • You, Kwang-Hee;Lee, Pung-Sok;Oh, Eui-Chaul
    • Journal of Pharmaceutical Investigation
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    • v.39 no.4
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    • pp.269-273
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    • 2009
  • The objective of this investigation was to develop a gastro-retentive(GR) dosage form of gabapentin and was to evaluate of its dissolution characteristics. GR tablet consists of expandable core tablet matrix and semi-permeable membrane coating. Poloxamer 407 and sodium bicarbonate were used to prepare the core matrix. Polyvinly acetate dispersion (Kollicoat $SR30D^{(R)}$) and polyvinyl alcohol-polyethylene glycol copolymer ((Kollicoat $IR^{(R)}$)) were employed to form the semi-permeable membrane. The GR tablets significantly expanded up to fivefold in simulated gastrointestinal fluids with no apparent damage of the coating membrane over 12 hours. Also, the swelling rate was controllable with the amount of sodium bicarbonate. The drug release was observed to be substantially sustained based on coating level. The release rate of gabapentin from the GR tablet was gradually slowed down as the coasting amount was increased. The gabapentin GR tablet with 8% coating level showed a pseudo-zero order release kinetics over 12 hours. These results suggest that this swellable GR tablet system having semi-permeable membrane coating can be applicable for hydrophilic drug substances like gabapentin.

Compressive Shear and Bending Performance of Compressed Laminated Wood after Microwave Heating

  • Park, Cheul-Woo;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.5
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    • pp.539-547
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    • 2012
  • To manufacture laminated wood with improved mechanical properties by providing uniform adhesiveness, the adhesive was applied and the plate adhesive was laminated on the wood surface. Then, after laminating the wood on the top part of the adhesivebond, it was heated and dried while the adhesive was stiffened using microwaves, and the test piece was manufactured by compressing it with the press machine for thirty minutes. The temperature and the water content were examined according to the heating time of the wood heated with the microwave, and testing was conducted on the shear strength and flexural strength of the wood. In addition, the microstructure of the adhesive bond between the wood was recorded to confirm the penetrabilityinto the wood structure for the adhesive. After the test was conducted, it was found that the test piece manufactured with wood that has its water content leveled with the microwave heating showed improved shear strength and bending strength compared to the standard test piece. With regard to adhesives, liquefied polyvinyl acetate resin and plate's PVB resin were found to have superior adhesive strength. Also, after filming the cellular microstructure, it was found that when the laminated wood is heated with microwaves, the infiltration of the adhesive into the inside of the wood becomes easy, which makes it effective for improving adhesiveness.

Pentacene Thin Film Transistors with Various Polymer Gate Insulators

  • Kim, Jae-Kyoung;Kim, Jung-Min;Yoon, Tae-Sik;Lee, Hyun-Ho;Jeon, D.;Kim, Yong-Sang
    • Journal of Electrical Engineering and Technology
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    • v.4 no.1
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    • pp.118-122
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    • 2009
  • Organic thin film transistors with a pentacene active layer and various polymer gate insulators were fabricated and their performances were investigated. Characteristics of pentacene thin film transistors on different polymer substrates were investigated using an atomic force microscope (AFM) and x-ray diffraction (XRD). The pentacene thin films were deposited by thermal evaporation on the gate insulators of various polymers. Hexamethyldisilazane (HMDS), polyvinyl acetate (PVA) and polymethyl methacrylate (PMMA) were fabricated as the gate insulator where a pentacene layer was deposited at 40, 55, 70, 85, 100 oC. Pentacene thin films on PMMA showed the largest grain size and least trap concentration. In addition, pentacene TFTs of top-contact geometry are compared with PMMA and $SiO_2$ as gate insulators, respectively. We also fabricated pentacene TFT with Poly (3, 4-ethylenedioxythiophene)-Polysturene Sulfonate (PEDOT:PSS) electrode by inkjet printing method. The physical and electrical characteristics of each gate insulator were tested and analyzed by AFM and I-V measurement. It was found that the performance of TFT was mainly determined by morphology of pentacene rather than the physical or chemical structure of the polymer gate insulator

Fabrication of Organic TFT wi th PVP Gate Insulating layer (PVP 게이트 절연막을 이용한 유기박막트랜지스터 제작)

  • Jang Ji-Geun;Seo Dong-Gyoon;Lim Yong-Gyu;Chang Ho-Jung;Oh Myung-Hwan
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2005.09a
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    • pp.83-88
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    • 2005
  • 유기 절연층을 갖는 유기 박막트랜지스터 (organic TFT)를 제작하여 소자 성능을 조사하였다. 유기 절연층의 형성에서는 polyvinyl 계열의 PVP(poly-4-vinylphenol)와 PVT(polyvinyltoluene)를 용질로, PGMEA (propylene glycol mononethyl ether acetate)를 용매로 사용하였다. 또한, 열경화성 수지인 poly(melamine-co-formaldehyde)를 경화제로 사용하여 유기 절연층의 cross-link 를 시도하였다. MIM 구조로 유기 절연층의 특정을 측정한 결과, PVT는 PVP에 비해 절연 특성이 떨어지는 경향을 보였다. 게이트 절연막의 제작에서 PVP를 cobpolymer 방식과 cross-linked 방식으로 실험 해 본 결과, cross-link 방식에서 낮은 누설전류 특성을 나타내었다. OTFT 제작에서는 PVP를 용질로, poly(melanine-co-formaldehyde)를 경화제로 사용한 cross-linked PVP 를 게이트 절연막으로 이용하였다. PVP copolymer($20\;wt\%$)에 $10\;wt\%$ poly(melamine- co-formaldehyde)를 혼합한 cross-linked PVP 를 게이트 절연막으로 사용하여 top contact 구조의 OTFT를 제작한 결과 약 $0.23\;cm^2/Vs$의 정공 이동도와 약 $0.4{\times}10^4$의 평균 전류점멸비를 나타내었다.

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Physical and Mechanical Properties of Laminated Board from Betung Bamboo (Dendrocalamus asper)

  • Muhammad Navis ROFII;Michael Jose MAIRING;Tomy LISTYANTO;Ihak SUMARDI;Rudi HARTONO
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.4
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    • pp.383-392
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    • 2024
  • Laminated bamboo is an engineered bamboo technology to maintain its mechanical durability for both construction and furniture materials. This study was conducted to assess the properties of laminated bamboo made from Betung bamboo at different culm positions and laminate orientations. The materials used in this study were 4-year Betung bamboo (Dendrocalamus asper) obtained from a community forest in Yogyakarta and polyvinyl acetate resin as adhesive. Two factors were applied for this study, i.e., culm position (lower, middle, and upper) and laminate orientations (vertical and horizontal direction). To examine the mechanical properties, a static bending test and the hardness test were performed in accordance with ASTM D1037-99. Moisture content and density were determined in accordance with BS 373-1957. The results indicated that there was no interaction between the culm position and laminate orientation on the moisture content, density, static bending properties and hardness. The culm position affected the static bending and hardness, with the higher position of the culm resulting a greater strength. The laminate orientation also affected the strength of laminated bamboo, with the vertical direction resulting in higher strength than the horizontal.

Organic Thin Film Transistors with Cross-Linked PVP Gates (Cross-Linked PVP 게이트 유기 박막트랜지스터)

  • Jang Ji-Geun;Oh Myung-Hwan;Chang Ho-Jung;Kim Young-Seop;Lee Jun-Young;Gong Myoung-Seon;Lee Young-Kwan
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.37-42
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    • 2006
  • The preparation and processing of PVP-gate insulators on the device performance have been studied in the fabrication of organic thin film transistors (OTFTs). One of polyvinyl series, poly-4-vinyl phenol(PVP) was used as a solute and propyleneglycol monomethyl etheracetate(PGMEA) as a solvent in the formation of organic gate solutions. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compounds. From the measurements of electrical insulating characteristics of metal-insulator-metal (MIM) samples, PVP-based insulating layers showed lower leakage current according to the increase of concentration of PVP and poly (melamine-co-formaldehyde) to PGMEA in the formation of organic solutions. The PVP(20 wt%) copolymer with composition of 20 wt% PVP to PGMEA and cross-linked PVPs in which 5 wt% and 10 wt% poly (melamine-co-formaldehyde) hardeners had been additional]y mixed into PVP(20 wt%) copolymers were used as gate dielectrics in the fabrication of OTFTs, respectively. In our experiments, the maximum field effect mobility of $0.31cm^2/Vs$ could be obtained in the 5 wt% cross-linked PVP(20 wt%) device and the highest on/off current ratio of $1.92{\times}10^5$ in the 10 wt% cross-linked PVP(20 wt%) device.

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Effects of Passivation Thin Films by Spray Coatings on Properties of Flexible CIGS Solar Cells (스프레이코팅법에 의한 패시베이션 박막이 플렉시블 CIGS 태양전지의 특성에 미치는 영향)

  • Lee, Sang Hee;Park, Byung Min;Kim, Ki Hong;Chang, Young Chul;Pyee, Jaeho;Chang, Ho Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.57-61
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    • 2016
  • In order to protect the solar cells from the moisture and oxygen, we evaluated the electrical and optical properties for the $Cu(In,Ga)Se_2$ (CIGS) solar cells which were prepared by the spray coating method. Generally, the EVA (ethylene-vinyl acetate) films are laminated to protect the CIGS flexible solar cells, which results in a high cost process due to complicated devices. In this study, we tried to prepare the protection layers of the flexible CIGS flexible solar cells by using spray coating method instead of conventional laminating films in order to reduce the device weight as well as the process time. The CIGS solar cells with spray coating method showed an enhanced efficiency than the before treated sample (2.77% to 2.93%) and relatively proper water vapor transmission rate of the solar cells about 62.891 gm/[$m^2-day$].

Fabrication of CO2 Sensor Membrane by Photolithographic Method (사진식각법을 이용한 CO2 센서 감지막의 제조)

  • Park, Lee Soon;Kim, Sang Tae;Koh, Kwang-Nak
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.6-12
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    • 1998
  • A FET(Field Effect Transistor) type dissolved $CO_2$ sensor based on Severinghaus type $CO_2$ sensor was fabricated by the photolithographic process. The sensor consists of Ag/AgCl reference electrode and membranes (hydrogel membrane and $CO_2$ gas permeable membrane) on the pH-ISFET base chip. Ag/AgCl reference electrode was fabricated as follows. Ag layer was thermally evaporated and then its upper surface was chemically chloridized into the AgCl. The hydrogel used as an internal electrolyte solution was fabricated by a photolithographic method using 2-hydroxyethyl methacrylate(HEMA) and acrylamide. $CO_2$ permeable membrane on the top of the hydrogel layer was formed by photolithographic process with UV-oligomer. The FET type $pCO_2$ sensor fabricated by photolithographic method showed good linearity within the concentration range of $10^{-3}{\sim}10^0mole/{\ell}$ of dissolved $CO_2$ in aqueous solution with high sensitivity.

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Effect of Adhesives and Finger Pitches on Bending Creep Performances of Finger-Jointed Woods

  • Park, Han-Min;Oh, Seong-Won;Byeon, Hee-Seop
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.5 s.133
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    • pp.57-65
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    • 2005
  • Following our previous reports for finger-jointed woods with various finger profiles studied for the efficient use of small diameter logs and woods containing various defects, twelve types of finger-jointed woods glued with three kinds of adhesives and with two sizes of finger pitches were made with sitka spruce and red pine. The effects of the adhesives and finger pitches on bending creep performances of finger-jointed woods were investigated. The shape of creep curves differed among the used adhesives and finger pitches of finger-jointed woods for both tested species. Their creep curves showed a linear behavior beyond about one hour, and the N values fitted to power law increased with increasing finger pitches. The initial deformation increased with increasing finger pitches, regardless of the tested species and kinds of adhesives, whereas the effect of finger pitches on the creep deformation was not clear. For finger-jointed woods glued with polyvinyl acetate (PVAc) resin, creep failure occurred in 106 hours after the load was applied. And the difference of the creep compliance between finger-jointed woods glued with resorcinol-phenol formaldehyde (RPF) resin and aqueous vinyl urethane (AVU) resin was small. The ratios for creep performances of finger-jointed woods glued with RPF resin and AVU resin versus solid wood were higher in creep deformation than initial deformation for both species, and the difference between both adhesives was not found. The relative creep decreased with increasing finger pitches, and the marked differences was not found between RPF resin and AVU resin.