• Fire Science and Engineering
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• v.14 no.2
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• pp.7-13
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• 2000

We had investigated thermal stability, Ignition temperature and fire gas for polyurethane foams used for manikin, cushion and interior finishing material. Decomposition of polyurethane foams with temperature was investigated using a DSC and the weight loss with temperature increase using a TGA in order to find the thermal hazard of polyurethane foams, and the ignition temperature of polyurethane foams according to species. We studied constant temperature among ignition temperature measuring methods. In addition, noxious gases for polyurethane foams according to combustion condition were analyzed using gas analyzer and GASTEC. As results, initial decomposition temperature of polyurethane foam used for interior finishing material was lower than those for manikin and cushion, and exothermic energy was higher. Ignition temperature of polyurethane foam of interior finishing material was $420^{\circ}$. All of combustion forms at $427^{\circ}$ and under were smoldering combustion, and it was combustion at $500^{\circ}$. As furnace temperature was increased, concentration of noxious gases such as carbon oxide, carbon dioxide, and hydrogen cyanide was increased. And nitrogen oxide at combustion condition($500^{\circ}$) was over 10 ppm.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.15-16
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• 2016

The roof-top of deteriorated building is necessary to improve that performance of waterproof and heat insulation is lowered. However, the existing method is difficult to supply due to complicated process and high cost. Therefore, practical condition and demand for occupant considered, it is necessary to develop inexpensive and easy method, such as a floating floor method using thermal insulation. This study is experiments on foundational experiment was conducted on the bending strength. A polyurethane board for experiment forms a square and it has various size that 25cm, 33cm, 50cm, and 100cm. Meanwhile, the uniform load of 200kg/㎡ which general working load is applied to the bending strength.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.11-12
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• 2011

This study examine Effect of Change of Compressive Strength of Concrete Members with Insulating Gang form on Temperature History of Concrete Positions. Test show, insulating gang forms differences and gang forms have 10℃ on peak point temperature of surface and Center if temperature history have 24Mpa by change of compressive strength. In addition, there have 14℃(16℃) on peak point temperature of surface and Center if temperature history have 40(60)Mpa. Therefore, insulating gang forms have an effect insulating performance.

• Carbon letters
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• v.22
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• pp.60-69
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• 2017

Nitrogen-doped carbon nanosheets with a developed porous structure were prepared from polyurethane foams by hydrothermal carbonization following $ZnCl_2$ chemical activation. Scanning electron microscopy, thermogravimetric analysis, Fourier transform infrared spectroscopy, solid state $^{13}C$ nuclear magnetic resonance (NMR) spectra and X-ray photoelectron spectroscopy were used to characterize the nitrogen-doped carbon nanosheet structure and composition. The removal of Cr(VI) by the N-doped carbon nanosheets was investigated. The results showed that the maximum removal capacity for chromium of 188 mg/g was found at pH=2.0 with PHC-Z-3. pH had an important effect on Cr(VI) removal and the optimal pH was 2.0. Moreover, amino groups and carboxyl groups in the nitrogen-doped carbon nanosheet played important roles in Cr(VI) removal, and promoted the reduction of Cr(VI) to Cr(III).

• Composites Research
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• v.34 no.1
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• pp.16-22
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• 2021

Polyurethane foam (PUF) can be manufactured in soft, semi-rigid, and hard forms, so it is used in various fields industrially. Among them, rigid PUF has excellent mechanical properties and low thermal conductivity, and is used as a thermal insulation material for buildings and as a cold insulation material in the natural gas transportation field. In this field, there is a steady demand on higher mechanical strength and lower thermal conductivity. In this study, a rigid PUF was manufactured, and the microstructure and physical properties were studied according to the impeller type (propeller, dispersed turbine) of the agitator. Through FE-SEM and Micro-CT analysis, it was confirmed that the average pore size of the foam manufactured with the dispersed turbine was 21.5% smaller than that of the pore made by the propeller. The compressive strength was improved by 15.4%, and the thermal conductivity decreased by 3.1% in the foam with small pores. This result can be utilized for fabricating PUF composites.

• International Journal of Safety
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• v.9 no.1
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• pp.6-11
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• 2010

Thermal analysis, heating test on gram scale and simulation of exothermic behavior based on kinetic analysis has been conducted in order to evaluate thermal hazards of self-polymerization of MDI. The exothermic reactions of MDI are expected to be the polymerization which forms carbodiimide and carbon dioxide, dimerization and trimerization. When MDI is kept in adiabatic condition during 1 week (10080 hours), the simulated result shows runaway reaction can occur in the case that initial temperature was more than $130^{\circ}C$. The relationship between the initial temperature (T, $^{\circ}C$) and TMR is given in a following equation. TMR=$4.493{\times}10^{-7}$ exp ($9.532{\times}10^3$/(T+273.15)) We propose that the relationship gives important criteria of handling temperature of MDl to prevent a runaway reaction.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.2
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• pp.79-86
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• 2022

Numerous fabrication techniques have been used to mimic cylindrical natural tissues, such as blood vessels, tendons, ligaments, and skeletal muscles. However, most processes have limitations in achieving the biomimetic properties of multilayered and porous architectures. In this study, to embrace both features, a novel self-assembly method was proposed using electrospun microfibrous sheets. A bilayer microfibrous structure, comprising two sheets with different internal stresses, was fabricated by electrospinning a polycaprolactone (PCL) sheet on a uniaxially stretched thermoplastic polyurethane (TPU) sheet. Then, by removing the stretching tension, the sheet was rolled into a hollow cylindrical structure with a specific internal diameter. The internal diameter could be quantitatively controlled by adjusting the thickness of the PCL sheet against that of the TPU sheet. Through this self-assembly method, biomimetic cylindrical structures with multilayer and porous features can be manufactured in a stable and controllable manner. Therefore, the resulting structures may be applied to various tissue engineering scaffolds, especially vascular and connective tissues.

• Proceedings of the KSR Conference
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• 2011.10a
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• pp.297-302
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• 2011

Railway construction in the random vibration natural phenomena, as well as a relatively regular train loads for dynamic loads, such as a usability and safety should be ensured. Vibration due to train loads and seismic vibrations caused by wind compared to the typically very small in size, rather than the safety of the structure affects the usability. Recently in the downtown area, ground and underground facilities, such as a permanent facility that may cause excessive vibration increases, associated with the construction of these transportation facilities on ground vibrations of structures has been increasing concern and complaint. More recently, high-speed train vibration and noise due to furnace is increasing. In order to solve this problem, such as soundproof considering several feet, but by applying the vibration and noise reduction measures insufficient for the study is Free. In this study, track structure, track, and the inside of the building to support the system, the different forms of neurological history and share about the history cheonanahsan high-speed rail, if passed by the bus stop on the train loads of noise, and the history of interior noise and vibration measurement / analysis of measurement results to assess the relative comparison with the relevant provisions were reviewed. Based on this history, future plans for the design of the bridge to reflect the results of a study is intended to provide information. Waiting for the analysis of vibration and noise reduction, cheonanahsan history passed quietly in the train, on average, appeared to 67.53dB and 65.41dB nervous week on average, were measured with the history. Nervous week waiting room of history and the history cheonanahsan radically different shapes and sizes, so a direct comparison is impossible, but the vibration caused by the disc on the base of the polyurethane elastomer disk is not supported by GERB SYSTEM Waiting more effective in reducing the noise level considered in The main materials for railway and for the localization will help to ensure affordability is considered.

• Clean Technology
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• v.18 no.1
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• pp.14-21
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• 2012

The pros and cons of green building thermal insulation materials and systems have been reviewed from traditional thermal insulation materials such as mineral wool and polyurethane to new thermal insulation materials like VIP and aerogel and future insulating VIM and DIM. VIPs and aerogels with very low thermal conductivity can use for green buildings to significantly increase residential area by reducing energy consumption. Aerogels can be produced as not only opaque and but also translucent forms, thus enabling a wide range of possible building application. For building applications, there are many properties to consider like building site adaptability and mechanical strength, fire protection, cost and environmental impact.