• Title/Summary/Keyword: polyurethane foams

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Comparisons of Thermal-moisture Properties in Combination of 3D spacer and Polyurethane(PU) Foam for Mold Brassiere Cups (몰드 브래지어 컵의 제작을 위한 3D 스페이서 패브릭과 폴리우레탄(PU) 폼 조합에 따른 열·수분 전달 특성 비교)

  • Lee, Hyun Young;Park, Huiju
    • Korean Journal of Human Ecology
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    • v.24 no.2
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    • pp.285-295
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    • 2015
  • To identify optimized thermal properties of mold brassiere cup for improved thermal comfort during summer, we compared the thermal resistance and the water vapor permeability of Polyurethane (PU) foam, 3D spacer fabric and the two combined materials of the PU foam and the 3D spacer fabric. Four experimental mold brassieres were made of the materials for wearing test. Six women in their twenties evaluated the wearing sensation in the hot and humid environment. The changes in microclimate temperature and humidity while wearing test brassiere cups were measured. Results indicate that thermal resistance increased as more PU foam were combined, while the water vapor permeability was higher as the content of the 3D spacer fabric increased at thickness of 18mm and over. However, in the wear test, the PU foam brassiere was the most preferred in all ambient conditions due to its soft, flexible and smooth texture, despite its high thermal resistance and low water vapor permeability. This indicates that the textures of mold foams are more dominant properties than thermal properties for mold foams in determining the wear comfort of mold brassieres.

Flame Retardant Properties of Polyurethane by the Addition of Phosphorus Compounds (인계 화합물의 첨가에 의한 폴리우레탄의 난연성)

  • Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.20 no.4 s.64
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    • pp.110-115
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    • 2006
  • Polyurethane(PU) was mixtured by the treatment with flame retardants such as Tri(chloroisopropyl) phosphate(TCPP), Triethyl phosphate(TEP) and Trimethyl phosphate(TMP) at about $90^{\circ}C$. Rigid polyurethane foam was produced using the mixured products as flame retardants. The mechanical property and flammability of rigid polyurethane was investigated. The mixtured polyurethane shows reduced flammability over virgin polyurethane. Mechanical strength of mixtured polyurethane also shows as high as that of virgin polyurethane. In order to evaluate flame retardant properties of the mixtured polyurethane foams, heat release rate(HRR) of the foam was measured by cone calorimeter. Scanning electron micrograph of mixtured PU shows uniform cell morphology as virgin PU.

A Study on Foaming Characteristics of Polyurethane Reaction Injection Molding using Cup Foam Test (컵 발포시험을 이용한 폴리우레탄 반응사출성형의 발포 특성에 관한 연구)

  • Youn, J.W.;Kim, H.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.106-109
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    • 2008
  • Polyurethane has been one of the most important materials for automobile elastic parts such as bumper, head rest, instrument panel and so on since it covers very wide range of mechanical characteristics with low production costs. The process variables such as formulation of ingredients and mold temperature, mixing speed, etc. can affect the quality of produced polyurethane foams so that process conditions should be determined appropriately. In this study, foaming behaviors of semi-rigid polyurethane were investigated by conducting cup foam tests with 2 major process variables such as environmental temperature and blowing agent content.

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A Study on Foaming Characteristics of Polyurethane Depending On Environmental Temperature and Blowing Agent Content (반응온도와 발포제 함량에 따른 폴리우레탄 발포특성에 관한 연구)

  • Kim, H.S.;Youn, J.W.
    • Transactions of Materials Processing
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    • v.18 no.3
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    • pp.256-261
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    • 2009
  • Polyurethane has been one of the most important materials for automobile elastic parts such as bumper, head rest, instrument panel and so on since it covers very wide range of mechanical characteristics with low production costs. The processing variables such as formulation of ingredients and mold temperature, mixing speed, etc. can affect the quality of produced polyurethane foams so that process conditions should be determined appropriately. In this study, foaming behaviors of semi-rigid polyurethane were investigated by conducting cup foam tests with two major processing variables such as environmental temperature and blowing agent content. In addition, it was verified that processing conditions of real practice can be determined effectively by considering foaming characteristics obtained by the cup foam tests.

Immobilization of Rhizopus chinesis using Polyurethane Foams (Polyurethane Foam을 이용한 리파아제 생산 균주 Rhizopus chinesis의 고정화)

  • 주지선;류희욱장용근
    • KSBB Journal
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    • v.7 no.3
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    • pp.172-178
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    • 1992
  • A simple and effective method has been developed for the immobilization of lipase producing Rhizopus chinensis on polyurethane foam. In this method, the fungal cells with 1, 3 specific lipase in there inside are immobilized within the foam matrix. Four types of commercially available polyurethane foam were tested. The ultimate purpose of the process is to produce low-cost biocatalysts for lipase-catalyzed reactions, which are being increasingly used for industrial applications. Effects of several parameters were studied on the cell loading and the hydrolytic activity of intracellular lipase after acetone drying. These parameters were the type, size, and amount of polyurethane foam. In all the cases, the intracellular lipase activity obtained with the foam was approximately twice greater than that obtained in the absence of the foam.

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Polymeric Material Application for The Production of Ceramic Foam Catalyst

  • Sangsuriyan, Anucha;Yeetsorn, Rungsima;Tungkamani, Sabaithip;Sornchamni, Thana
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.21-30
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    • 2015
  • Ceramic foams are prepared as positive images corresponding to a plastic foam structure which exhibits high porosities (85-90%). This structure makes the ceramic foams attractive as a catalyst in a dry reforming process, because it could reduce a high pressure drop problem. This problem causes low mass and heat transfers in the process. Furthermore, the reactants would shortly contact to catalyst surface, thus low conversion could occur. Therefore, this research addressed the preparation of dry reforming catalysts using a sol-gel catalyst preparation via a polymeric sponge method. The specific objectives of this work are to investigate the effects of polymer foam structure (such as porosity, pore sizes, and cell characteristics) on a catalyst performance and to observe the influences of catalyst preparation parameters to yield a replica of the original structure of polymeric foam. To accomplish these objectives industrial waste foams, polyurethane (PU) and polyvinyl alcohol (PVA) foams, were used as a polymeric template. Results indicated that the porosity of the polyurethane and polyvinyl alcohol foams were about 99% and 97%. Their average cell sizes were approximate 200 and 50 micrometres, respectively. The cell characteristics of polymer foams exhibited the character of a high permeability material that can be able to dip with ceramic slurry, which was synthesized with various viscosities, during a catalyst preparation step. Next, morphology of ceramic foams was explored using scanning electron microscopy (SEM), and catalyst properties, such as; temperature profile of catalyst reduction, metal dispersion, and surface area, were also characterized by $H_2-TPR$ and $H_2-TPD$ techniques, and BET, respectively. From the results, it was found that metal-particle dispersion was relatively high about 5.89%, whereas the surface area of ceramic foam catalysts was $64.52m^2/g$. Finally, the catalytic behaviour toward hydrogen production through the dry reforming of methane using a fixed-bed reactor was evaluated under certain operating conditions. The approaches from this research provide a direction for further improvement of marketable environmental friendly catalyst production.

An Experiment on Reduction of Infrasonic Underwater Self-Noise (초저주파 대역 수중 자체소음 저감에 관한 실험 연구)

  • Lee, Seong-Wook;Lee, Yong-Kuk;Kim, Seong-Ryul
    • The Journal of the Acoustical Society of Korea
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    • v.30 no.1
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    • pp.17-21
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    • 2011
  • The effects of screening hydrophones with open-cell foams for reduction of the infrasonic self-noise induced by the flow around hydrophones are investigated by at-sea experiment. Test results of the 10 ppi polyurethane open-cell foams with different thickness show that the foams of 1 cm and 3 cm thickness reduce the flow-induced self-noises up to 20 dB and 28 dB at the frequency band of 2-10 Hz, respectively.

Study on the Physical Properties of Polyurethane Foam Synthesized by Castor Oil Based Polyol (피마자유 기반 폴리올에 따른 폴리우레탄 폼의 물성 변화 연구)

  • Lee, Sunghyun;Kim, Kwangin;Oh, Jeongseok;Yun, Mijung;Kim, Sangbum
    • Journal of the Korean Institute of Gas
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    • v.16 no.5
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    • pp.66-75
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    • 2012
  • Polyurethane foams were synthesized by substituting a portion of petroleum base polyether polyol with castor oil-derived polyol(COP). Contact angle tester and surface tensionmeter were used to examine the compatibility of petroleum base polyether polyol and COP. To investigate the optimum content of COP and surfactant, the content of COP has been changed from 0 wt% to 80 wt%. From the results of polyurethane foams synthesized by surfactant L-580K, DC-5950 and BF-2470, the best mechanical properties was observed when the content of COP was 30wt% and surfactant BF-2470.

Characteristics of Rigid Polyurethane Foams Blown by HFCs for LNG Storage Tank (HFC계 발포제를 사용한 LNG 저장탱크용 폴리우레탄 폼 단열재의 특성)

  • Lee Yeongbeom;Choi Sunghee;Choi Gunhyung
    • Journal of the Korean Institute of Gas
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    • v.9 no.1 s.26
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    • pp.16-20
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    • 2005
  • CFC-11 and HCFC-l4lb have been used as blowing agents for rigid polyurethane foam insulation of LNG storage tank. But CFC-11 and HCFC- l4lb deplete ozone layer in the stratosphere. So in leading countries, the use of CFC-11 has been prohibited since 1995 and the use of HCFC-l4lb will be prohibited from 2005. Much efforts and studies have been done about alternative blowing agents and insulations blown by alternative blowing agents. This paper deals with polyurethane foams (PUFs) blown by HFC-365mfc, shows their physical and mechanical characteristics and thermal performance. These data are compared with the results of PUFs blown by HCFC-l4lb. From these test results, PUFs blown by HFC-365mfc show good mechanical and thermal characteristics. It is possible to use PUFs blown by HFC-365mfc as main insulation of membrane type LNG storage tank.

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An Insight Into the Recycling of Waste Flexible Polyurethane Foam Using Glycolysis

  • Woo Seok Jin;Pranabesh Sahu;Gyuri Kim;Seongrok Jeong;Cheon Young Jeon;Tae Gyu Lee;Sang Ho Lee;Jeong Seok Oh
    • Elastomers and Composites
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    • v.58 no.1
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    • pp.32-43
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    • 2023
  • The worldwide use of polyurethane foam products generates large amounts of waste, which in turn has detrimental effects on the surroundings. Hence, finding an economical and environmentally friendly way to dispose of or recycle foam waste is an utmost priority for researchers to overcome this problem. In that sense, the glycolysis of waste flexible polyurethane foam (WFPF) from automotive seat cushions using different industrial-grade glycols and potassium hydroxide as a catalyst to produce recovered polyol was investigated. The effect of different molecular weight polyols, catalyst concentration, and material ratio (PU foam: Glycols) on the reaction conversion and viscosity of the recovered polyols was determined. The obtained recovered polyols are obtained as single or split-phase reaction products. Besides, the foaming characteristics and physical properties such as cell morphology, thermal stability, and compressive stress-strain nature of the regenerated flexible foams based on the recovered polyols were discussed. It was observed that the regenerated flexible foams displayed good seating comfort properties as a function of hardness, sag factor, and hysteresis loss compared to the reference virgin foam. With the growing demand for a sustainable and circular economy, a global valorization of glycolysis products from polyurethane scraps can be realized by transforming them into profitable substances.