• Title/Summary/Keyword: polypropylene composite

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Formaldehyde and TVOC Emission of Bio-Composites with Attached Fancy Veneer

  • Lee, Byoung-Ho;Kim, Hee-Soo;Kim, Ki-Wook;Lee, Se-Na;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.2
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    • pp.46-55
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    • 2008
  • This study assesses the formaldehyde and TVOC emissions from bio-composites with attached fancy veneer manufactured using wood flour and polypropylene (PP) measured using the Field and Laboratory Emission Cell (FLEC) method and 20 L small chamber method. To determine and compare the effects of the adhesive, samples were prepared with different manufacturing methods. In the FLEC result, the formaldehyde emission level of the bio-composites with attached veneer by hot-press was the lowest than pure bio-composite and bio-composite attached veneer using adhesive. The TVOC emission levels are similar to the formaldehyde emission. The TVOC emission level is very low in all of the samples except fancy veneer that is attached with bio-composites using adhesive. The TVOC emission varies depending on how attaching fancy veneer. The results of the 20 L small chamber method were very similar to those obtained with the FLEC, but the correlation was not perfect. However, the FLEC method requires a shorter time than the 20 L small chamber method to measure the formaldehyde and TVOC emissions. The internal bonding strength exceeded the minimum value of $0.4N/mm^2$ specified by the KS standard. All of the bio-composites with attached veneer satisfied the KS standard.

Fabrication of ZnO and TiO2 Nanocomposite Fibers and Their Photocatalytic Decomposition of Harmful Gases (ZnO와 TiO2 함유 복합나노섬유의 제조와 유해물질분해 성능 평가)

  • Hur, Yoon-Sun;Lee, Seung-Sin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.11
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    • pp.1297-1308
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    • 2011
  • This research investigates the application of ZnO (zinc oxide) nanoparticles and $TiO_2$ (titanium dioxide) nanoparticles to polypropylene nonwoven fabrics via an electrospinning technique for the development of textile materials that can decompose harmful gases. To fabricate uniform ZnO nanocomposite fibers, two types of ZnO nanoparticles were applied. Colloidal $TiO_2$ nanoparticles were chosen to fabricate $TiO_2$ nano- composite fibers. ZnO/poly(vinyl alcohol) (PVA) and $TiO_2$/PVA nanocomposite fibers were electrospun under a variety of conditions that include various feed rates, electric voltages, and capillary diameters. The morphology of electrospun nanocomposite fibers was examined with a field-emission scanning electron micro- scope and a transmission electron microscope. Decomposition efficiency of gaseous materials (formaldehyde, ammonia, toluene, benzene, nitrogen dioxide, sulfur dioxide) by nanocomposite fiber webs with 3wt% nano-particles (ZnO or $TiO_2$) and 7$g/m^2$ web area density was assessed. This study shows that ZnO nanoparticles in colloid were more suitable for fabricating nanocomposite fibers in which nanoparticles are evenly dispersed than in powder. A heat treatment was applied to water-soluble PVA nanofiber webs in order to stabilize the electrospun nanocomposite fibrous structure against dissolution in water. ZnO/PVA and $TiO_2$/PVA nanofiber webs exhibited a range of degradation efficiency for different types of gases. For nitrogen dioxide, the degradation efficiency was 92.2% for ZnO nanocomposite fiber web and 87% for $TiO_2$ nanocomposite fiber web after 20 hours of UV light irradiation. The results indicate that ZnO/PVA and $TiO_2$/PVA nano- composite fiber webs have possible uses in functional textiles that can decompose harmful gases.

A Study on Improving the Non-Combustible Properties of High-Density Fiber Cement Composites (고밀도 섬유 시멘트 복합체 불연특성 개선에 관한 연구)

  • Song, Tae-Hyeob;Jang, Kyong-Pil
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.521-528
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    • 2021
  • The high-density fiber composite manufacturing method by the extrusion molding method has the characteristic that continuous production is possible, and the product is molded through a mold forming a specific cross-section. OPC is used as a defect material, an appropriate amount of SiO2 is supplied for CaO reaction activity, and high density and high strength are expressed through steam and autoclave curing. However, due to the use of organic reinforcing fibers, the flame duration exceeds the regulations during the non-combustible performance test, making it difficult to secure performance. In this study, the product was produced by mixing alkali-resistant organic fiber and fly ash having voids as a binder by replacing the existing polypropylene fiber. appeared to be possible.

Machine learning techniques for reinforced concrete's tensile strength assessment under different wetting and drying cycles

  • Ibrahim Albaijan;Danial Fakhri;Adil Hussein Mohammed;Arsalan Mahmoodzadeh;Hawkar Hashim Ibrahim;Khaled Mohamed Elhadi;Shima Rashidi
    • Steel and Composite Structures
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    • v.49 no.3
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    • pp.337-348
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    • 2023
  • Successive wetting and drying cycles of concrete due to weather changes can endanger the safety of engineering structures over time. Considering wetting and drying cycles in concrete tests can lead to a more correct and reliable design of engineering structures. This study aims to provide a model that can be used to estimate the resistance properties of concrete under different wetting and drying cycles. Complex sample preparation methods, the necessity for highly accurate and sensitive instruments, early sample failure, and brittle samples all contribute to the difficulty of measuring the strength of concrete in the laboratory. To address these problems, in this study, the potential ability of six machine learning techniques, including ANN, SVM, RF, KNN, XGBoost, and NB, to predict the concrete's tensile strength was investigated by applying 240 datasets obtained using the Brazilian test (80% for training and 20% for test). In conducting the test, the effect of additives such as glass and polypropylene, as well as the effect of wetting and drying cycles on the tensile strength of concrete, was investigated. Finally, the statistical analysis results revealed that the XGBoost model was the most robust one with R2 = 0.9155, mean absolute error (MAE) = 0.1080 Mpa, and variance accounted for (VAF) = 91.54% to predict the concrete tensile strength. This work's significance is that it allows civil engineers to accurately estimate the tensile strength of different types of concrete. In this way, the high time and cost required for the laboratory tests can be eliminated.

Effect of Reinforcing Fiber Types on Lap Splice Performance of High Performance Fiber Reinforced Cementitious Composite(HPFRCC) (보강 섬유 종류에 따른 고인성 시멘트 복합체내에서 철근의 겹침 이음 성능)

  • Jeon, Esther;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.19 no.2
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    • pp.153-161
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    • 2007
  • This paper investigates the lap splice performance of structural steel bars embedded in high performance fiber reinforced cementitious composite(HPFRCC) with various matrix ductilities. Matrix ductility is governed fiber type and fiber volume fraction. Fiber types were polypropylene(PP), polyethylene(PE) and hybrid fiber[polyethylene fiber+steel cord(PE+SC)]. The lap splice length$(l_d)$ was calculated according to the relevant ACI code requirements for reinforcing bars in normal concrete. As the result of tests, lap splice strength of HPFRCC using PE1.5 and hybrid fiber increased by up to $82{\sim}91$ percent more than that of concrete. Splice strength and energy absorption capacity of PE0.75+SC0.75 or PE1.5(fiber volume fraction 1.5%) specimen increased more than that of PP2.0(fiber volume fraction 2.0%) specimen. Therefore lap splice performance depends on fiber tensile strength and Young's modulus more than fiber volume fraction. Also, HPFRCC appear multiple crack and ductile postpeak behavior due to bridging of fiber in cementitious composite.

Color Change and Tensile Properties of Wood Flour Reinforced Polypropylene Composites; Influence of Photostabilizers

  • Lee, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.171-178
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    • 2009
  • A comparative analysis of the hindered amine light stabilizers (HALS) and UV abosrber (UVA) and their respective photostabilizing effect on wood plastic composites (WPCs) are reported in this study. The influence of accelerated weathering on the mechanical properties of the composites and the microscopic morphology of a degraded layer on the cross section and the surface were studied. UV absorbers were more efficient at preventing composite lightening than was UV stabilizer. The amount of whitening decreased with the increase of photostabilizers. With the addition of a UV absorber (Tinuvin360), the tensile modulus and strength of the composites increased slightly. However, the addition of a light stabilizer (Tinuvin770) and a UV absorber decreased the tensile modulus and strength of the composites. After 250 and 500 hr exposure, tensile modulus and strength of the un stabilized and stabilized composites decreased. The tensile strength of UV absorber (Chimassorb81)-stabilized composites was significantly greater than that of control and light stabilizer (Tinuvin770)- and UV absorber (Tinuvin360)-stabilized composites. UV absorber-stabilized samples showed less whitening and photodegradation than control and light stabilizer-stabilized samples.

Dielectric Properties of Ceramic/Polymer Composites at Microwave Frequencies

  • Kim, Eung-Su;Jeon, Chang-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.19.1-19.1
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    • 2011
  • Effects of particle size, crystal structures and multilayer structures of $ATiO_3$, $ATa_2O_6$, $ANb_2O_6$, $AWO_4$, and $AMoO_4$ (A=Ni, Mg, Zn, Co) ceramic fillers on the dielectric properties of polystyrene (PS), polypropylene (PP) and polytetrafluoroethylene (PTFE) polymer matrices were investigated at microwave frequencies. The microwave dielectric properties of $ATiO_3$ (ilmenite), $ATa_2O_6$ (tri-rutile), $ANb_2O_6$ (columbite), AWO4 (wolframite), and AMoO4 (wolframite) ceramics were largely dependent on the structural characteristics of oxygen octahedra. The dielectric constant (K) of the composites was increased with the ceramic content. However, the dielectric loss (tan ${\delta}$) of the composites was affected by the type of ceramics and the crystallinity of polymers. For the composites with same amount of ceramics, the K was decreased and the tan ${\delta}$ was increased with the particle size of ceramics. Also, the dielectric properties of the composites were dependent on the multilayer structures with different arrangements. Several theoretical models have been employed to predict the effective dielectric properties of the composites. The frequency dependence of dielectric properties and the temperature coefficient of resonant frequency (TCF) of the composites were also discussed.

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A Study on the Processing Characteristic in the Compression Molding of Hybrid Thermoplastic Composites (하이브리드 열가소성 복합재료의 압축성형에서 공정특성에 관한 연구)

  • Heo, Seok-Bong;Lee, Joong-Hee;Shin, Gwi-Su;Rhee, Kyoung-Yop
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.12
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    • pp.2550-2555
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    • 2002
  • Hybrid composites usually are defined as composites having different types of reinforcements such as fibers and particles. The major advantage of hybrid composites is able to control the material properties such as optical, electrical, and mechanical properties. For this reason, hybrid composites are widely used in automotive, marine, household, and electrical industries. The objective of this work was to investigate processing characteristics in the compression molding of hybrid thermoplastic composites. The mechanical properties of composites manufactured in various forming conditions were monitored. The composites contained randomly oriented long carbon fiber and carbon black in polypropylene(PP) matrix were used. The carbon fiber contents of composites were 5%, 10%, 15%, and 20%, and carbon black contents were 5%, 10%, 15%, 20%, and 25% by weight. Compression molding was conducted at various mold temperatures. Crstallinity was also measured by using X-RD. The tensile modulus of the composites increased with increasing the mold temperature. However, the impact strength of the composites decreased as the mold temperature increased.

Basic Characteristics of High Performance Concrete Mixing Organic Fiber (유기섬유 복합 혼입 고성능 콘크리트의 기초적 특성)

  • Park, Byung-Kwan;You, Ji-Young;Lee, Joung-Ah;Jin, Cheng-Ri;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.87-91
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    • 2008
  • The study examined fire resistance of concrete followed by change of mixed rate in PP and NY composite fiber and the results were as follows. In the event of fluidity in concrete not set, plane satisfied 600±100, its target slump flow, and fluidity was reduced as organic fiber's mixed rate was increased. Air amount satisfied 3.0±1.0, its target air amount, and didn't have distinct differences in reduction and increase according to organic fiber's kind and change of its mixed rate. However, it had a tendency that fluidity was reduced as the mixed rate was increased. In characteristics of hardening concrete, the 28th day compressive strength followed by organic fiber's kind and change of its mixed rate didn't have a lot of differences and satisfied high strength scope as about 70MPa. In spalling characteristics after fire resistance test, spalling was happened in non-mixture, plane combination, and P1N0. In other combinations, spalling resistance was happened. The relic compressive strength rate was 56%, the best condition, in P3N1(PP0.03%, NY0.01% compositeness) mixing PP fiber with NY fiber at once.

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Effect of Alkyl Ketene Dimer(AKD) on Red Algae Reinforced Biocomposites (AKD 처리한 홍조류섬유 보강 바이오복합재료의 특성)

  • Lee, Min-Woo;Park, Dong-Hui;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.2
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    • pp.66-71
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    • 2011
  • Biocomposites were fabricated with biodegradable polymers and natural fibers. Biocomposites have benefits of low cost, low density, and biodegradability over inorganic fiber composite, and give comparable strength properties. Hydrophobic polymer used for sizing in paper industry, AKD (Akenyl Keten Dimer), was applied to natural fibers, red algae fibers (RAF) in this study, to make fiber surfaces more compatible to hydrophobic nature of matrix polymers. Composites with RAF, kenaf, glass fibers, and carbon fibers have been fabricated by a compression molding method and their thermo-mechanical properties have been studied. Also, the thermal dimensional stability test was done from at 30 to $100^{\circ}C$. The storage moduli and the thermo-mechanical stabilities of polypropylene and poly lactic acid based biocomposites were improved by reinforcing with the RAF and much more with AKD treated fibers. Dimensional stability of biocomposite was also markedly improved by AKD pretrement on RAF.