• Title/Summary/Keyword: polymethyl methacrylate

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Improvement of Graphene's Electrical Properties by ICP Cleaning

  • Gang, Sa-Rang;Ra, Chang-Ho;Yu, Won-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.629-629
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    • 2013
  • Graphene is a carbon based material and it has intriguing features, such as phenomenally strong, thin, flexible, transparent and conductive, those make it attractive for a broad range of applications.Unfortunately, graphene is extremely sensitive to contamination. When we fabricate graphene devices, electrical properties of graphene are altered [1], and the charge carrier mobility drops accordingly by orders of magnitude. This significant impact on electron mobility occurs because any surrounding medium could act as a dominant source of extrinsic scattering, which effectively reduces the mean free path of carriers [2,3]. The dominant contaminant is generated through fabrication stage by polymethyl methacrylate (PMMA) [4], or photo resist (PR). Surface contamination by these residues has long been a critical problem in probing graphene's intrinsic properties. If we clearly solve this problem, we can get highly performed graphene devices. Here, we will report on graphene cleaning process by Induced Coupled Plasma (ICP). We demonstrated how much decomposition of residue impact on improving electrical properties of graphene.

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Fabrication and Characterization of Porous Nickel Membrane for High Precision Gas Filter by In-situ Reduction/Sintering Process (In-situ 환원/소결법을 이용한 다공성 니켈 멤브레인 가스필터의 제조 및 평가)

  • Kim, Nam-Hoon;Song, Han-Bok;Choi, Sung-Churl;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.16 no.4
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    • pp.262-267
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    • 2009
  • Disk type porous nickel membrane was fabricated by in-situ reduction/sintering process using compacted NiO/PMMA (PMMA; Polymethyl methacrylate) mixture at $800^{\circ}C$ in hydrogen atmosphere. The porosity (49$\sim$58%) of these membrane was investigated as an amount of PMMA additive. The thermal decomposition and reduction behavior of NiO/PMMA were analyzed by TG/DTA in hydrogen atmosphere and the activation energy for the hydrogen reduction of NiO and thermal degradation of PMMA was calculated as 61.1 kJ/mol, evaluated by Kissinger method. Finally, the filtering performance and pressure drop were measured by particle counting system.

수성 고분자 - 탄소나노튜브 복합 분산 용액을 이용한 전계 방출 소자의 제작

  • Jeong, Hyeok;Kim, Do-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.66.2-66.2
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    • 2011
  • A polymer-based multi-walled carbon nanotube (MWCNT) field emission device was fabricated from a composite dispersion of MWCNTs and waterborne polymethyl methacrylate (PMMA). The waterborne PMMA synthesized through the emulsion polymerization method was added to minimize the reagglomeration of dispersed MWCNTs with surfactants in water, and increase the adhesion between the and the substrate. The field emission properties of the fabricated device were optimized by adjusting the density of the emitter and the adhesion between the MWCNTs and the substrate. These were done by controlling the polymer concentration added to the MWCNT dispersion, as well as the amount of spray coating on the substrate. The results confirm the successful fabrication of a polymer-based MWCNT field emission device with a low field of 1.07 $V/{\mu}m$ and a good electric field enhancement factor of 2445. The device was fabricated by adding 0.8 mg/mL of polymer solution to the MWCNT dispersion and applying 20 cycles of spray coating. Application of this same MWCNT/polymer composite solution to a flexible polymer substrate also resulted in the successful fabrication of an electric field emission device with uniform emission and long time stability.

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Influence of Loading Position and Reaction Gas on Etching Characteristics of PMMA in a Remote Plasma System (Remote 플라즈마에서 위치 및 반응기체에 따른 PMMA의 식각 특성 분석)

  • Ko, Cheonkwang;Lee, Wongyu
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.483-488
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    • 2006
  • Etching process of PMMA (Polymethyl Methacrylate) on glass surface was investigated by dry etching technique using remote plasma. To determine the etching characteristics, the remote plasma etching was conducted for various process parameters such as plasma power, reaction gas and distance from plasma generation. As the distance from the plasma generation was increased, the etch rate of PMMA was linearly decreased by radical density in plasma. PMMA has removed by reactive radicals in the plasma. The etch rate increased with plasma power because of more reactive radicals. The etch rate and surface roughness of PMMA increased with $O_2$ concentration in the etchant.

Study on a Change of Mechanical Property of denture Resin by Carbon Fiber Filler Content (탄소섬유 첨가에 따른 의치상 레진의 탄성력 관찰)

  • Kim, Ho-Sung
    • Journal of Technologic Dentistry
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    • v.36 no.3
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    • pp.165-169
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    • 2014
  • Purpose: This study is a mechanical strength supplementation of denture base resin Polymethyl methacrylate (PMMA) is in general use for denture base resin of the partial and full denture, however, The polymerization process of PMMA is not stabilized. Because of compatibility problems, preceding studies were performed, which were enhancing mechanical strength(Camilo Machado 2007),(Ana M. 2008), addition filler to materials property(Ayse Mese, 2008), self curing method(Hiroshi Shimizu, 2008). Methods: The carbon fiber and polyacetal filler, reinforced the mechanical strength for improving the stability of denture base resin were supplemented to the self cured resin. The Modulus of elasticity and the restoring force were calculated by tensile test. Results: The strengths of the heat and self cured resin were respectively decreased and increased, when the filler was supplemented to the denture base resin and the modulus of elasticity of both heat and self cured resin were not increased, when the filler was supplemented to the denture base resin. Conclusion: The restoring forces of self cured resin containing 10% filler were increased, when the filler was supplemented to the denture base resin.

Effects of Various Post-Treatments of Carbon Nanotube Films for Reliable Field Emission

  • Han, Jae-Hee;Lee, Su-Hong;Berdinsky, Alexander S.;Yoo, Ji-Beom;Park, Chong-Yun;Choi, Jin-Ju;Jung, Tae-Won;Han, In-Taek;Kim, Jong-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1462-1465
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    • 2005
  • In this report, the FE characteristics of carbon nanotubes (CNTs) treated using both thermal annealing and mechanical coatings on the as-grown CNTs system atically studied. It was found that in the high temperature annealed samples, CNTs were attacked at its root during annealing due to a small amount of oxygen, and were pulled out of the substrate in places after FE measurements because of the contact resistance. However, for the mechanically coated samples both with spin on glass (SOG) and polymethyl methacrylate (PMMA), CNTs were found to be nearly intact after FE measurements and showed reliable FE characteristics over repeatable voltage scan. The reliability of CNTs during FE could be owing to the strong adhesion of CNTs to the substrate both by SOG and PMMA coatings.

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The electrical characteristics of pentacene field-effect transistors with polymer gate insulators

  • Kang, Gi-Wook;Kang, Hee-Young;Park, Kyung-Min;Song, Jun-Ho;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.675-678
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    • 2003
  • We studied the electrical characteristics of pentacene-based organic field-effect transistors (FETs) with polymethyl methacrylate (PMMA) or poly-4-vinylphenol (PVP) as the gate insulator. PMMA or PVP was spin-coated on the indium tin oxide glass substrate that serves as gate electrodes. The source-drain current dependence on the gate voltage shows the FET characteristics of the hole accumulation type. The transistor with PVP shows a higher field-effect mobility of 0.14 $cm^{2}/Vs$ compared with 0.045 $cm^{2}/Vs$ for the transistor with PMMA. The atomic force microscope (AFM) images indicate that the grain size of the pentacene on PVP is larger than that on PMMA. X-ray diffraction (XRD) patterns for the pentacene deposited on PVP exhibit a new Bragg reflection at $19.5{\pm}0.2^{\circ}$, which is absent for the pentacene on PMMA. This peak corresponds to the flat-lying pentacene molecules with less intermolecular spacing.

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Effect of scattered x-rays on subject contrast and image sharpness

  • Arimura, Hidetaka;Date, Takuji;Morikawa, Kaoru;Kubota, Hideaki;Matsumoto, Masao;Kanamori, Hitoshi
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 1999.11a
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    • pp.278-281
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    • 1999
  • The purpose of this study is to investigate the effect of the scattered x-rays on the subject contrast and image sharpness for various tube voltages. For the purpose, we measured the scatter-to-primary ratio(SPR) for the tube voltages f 50 to 100kV and obtained the tube voltage dependence of the subject contrast of an aluminum plate in a polymethyl methacrylate(PMMA) phantom. Furthermore, the overall modulation transfer functions(MTFs), which consist of MTFs of a screen-film system and scatter FTMs, were obtained for tube voltages of 50 to 100 kV. The subject contrast decreased with the tube voltage due to that the SPR increased with the tube voltage and that the difference in effective linear attenuation coefficients between the object and its surroundings decreased with the tube voltage. The maximum frequency of the overall MTF decreased from about 2 mm$\^$-1/ to 1 mm$\^$-1/ with the tube voltage increasing from 50 to 100 kV.

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탄소나노튜브 첨가에 따른 복합나노섬유의 기계적-광학적 특성 변화

  • Lee, Mi-Hyeon;Song, U-Seok;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.289-289
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    • 2010
  • 나노섬유는 지름이 수십에서 수백 나노미터(1나노미터=10억분의1m)에 불과한 초극세 물질로 비표면적이 매우 크고[1], 제작이 간편하여, 사용되어지는 고분자의 종류에 따라 에너지 환경 의료 관련 분야에서 전극소재 필터재 피복재 인공 피부등 다양한 분야에서의 활용이 가능하여 전 세계적으로 연구개발이 활발하게 이루어지고 있다. 그러나 그 자체만으로 응용하기에는 그 기계적 전기적 특성의 한계 때문에 응용의 다양성에 제약을 받고 있다. 그러나 그 자체만으로 응용하기에는 그 기계적 열적 전기적 특성을 가진 탄소나노튜브를 첨가한 복합나노섬유에 의해 그 응용영역의 한계를 넓혀가고 있다.[2] 본 연구에서는 전도성 고분자인 polymethyl methacrylate (PMMA)에 multi-walled carbon nanotubes (MWCNTs)를 첨가한 복합나노섬유를 전기방사법(electrospinning method)을 통해서 제조하였다. [2~3] CNTs 첨가농도에 따른 제조된 복합나노섬유의 형상변화와 섬유내의 CNTs 배열상태를 각각 주사전자 현미경(scanning electron microscope: SEM)과 투과전자현미경(transmission electron microscope: TEM)을 이용하여 관찰하였다. 또한, 복합나노섬유의 광학 특성 변화를 CNTs 첨가농도에 따라서 FT-IR과 Raman spectroscopy등을 이용하여 조사하였으며, 나노섬유의 tensile strength의 측정을 통해 CNTs 함량에 따른 기계적 특성 변화를 분석하였다.

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Fabrication of Grooved Pattern for the Light Guide Plate of TFT-LCD with CO2 Laser (CO2 레이저 빔을 이용한 TFT-LCD 도광판의 패턴 제작에 관한 연구)

  • 김경동;백창일;송철기;안성훈
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.147-150
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    • 2002
  • A light guide panel is an element of the LCD backlight module that is often used for the display of compact electronic devices. In this study, a laser marking system is proposed to fabricate light guide panel, which can be replaced of other manufacturing methods such as silk printing, stamping, and v-cutting methods. The objectives of this research are the establishment of laser marking system, evaluation of laser marking parameters, understanding marking process, application to PMMA, reliability test and quality inspection. A 50W $CO_2$ laser (CW) was used to perform different experiments in which, the influence of some processing parameters (average power, scanning speed) on the geometry and quality of groove pattern was studied. The width of the etched grooves increases with increasing a laser power and decreasing a scan speed. In order to analyze surface characteristics and optical properties (luminance, uniformity), SEM photography and BM7 (luminance measuring system) were used. As a result, the optimal conditions of the process parameters were determined.

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