• Title/Summary/Keyword: polymerization rate

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The Synthesis of Pyrrolidone-N-sulfonyl Chloride and Its Catalytic Effect in Anionic Polymerization of Pyrrolidone (Pyrrolidone-N-sulfonyl Chloride의 합성 및 Pyrrolidone-N-sulfonyl Chloride / KOH 촉매작용에 의한 Pyrrolidone의 음이온 중합)

  • W.J. Chung;S.K. Choi
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.402-411
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    • 1979
  • The synthesis of pyrrolidone-N-sulfonyl chloride has been carried out by the reaction of pyrrolidone with sulfuryl chloride in benzene. It was attempted to study the catalytic effect of pyrroldone-N-sulfonyl chloride as an initiator for anionic polymerization of pyrrolidone. It was found that as a concentration of initiator decreased, inherent viscosity of the resulting polymer increased up to 1.8 dl/g. The highest rate of polymerization and equilibrium conversion was observed when mole ratio of PNSC to KOH was 0.25. In general, the observed value of polymerization and equilibrium conversion in circumstances using PNSC/KOH catalysis system were higher than using $CO_2$/KOH catalysis system.

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An Evaluation of Thermal Stability of Raw Materials in the Vinyl Acetate Polymerization Process (비닐아세테이트 중합공정에서 원료물질의 열적 안정성 평가)

  • Lee, Keun-Won;Han, In-Soo;Lee, Jung-Suk
    • Journal of the Korean Society of Safety
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    • v.25 no.3
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    • pp.61-65
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    • 2010
  • Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.

A study on the polymerization of energetic prepolymer(GDNPF) (에너지를 함유한 선 폴리머인 Prepolymer(GDNPF) 제조 공정 연구)

  • Cheun, Young-Gu;Kim, Jin-Seuk
    • Journal of the Korea Institute of Military Science and Technology
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    • v.8 no.2 s.21
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    • pp.67-76
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    • 2005
  • We synthesized an energetic prepolymer(glycidyl dinitro propyl formal, GDNPF) for plastic-bonded explosive and measured its thermodynamic parameters. Glycidyl dinitro propyl formal(GDNPF) as an energetic monomer was epoxidized from allyl-2,2-dinitro propyl formal which is reacted with dinitro propyl alcohol and excess allyl alcohol, and then energetic polymer of GDNPF was polymerized by cationic ring opening polymerization. Thermodynamic parameters were obtained from the ceiling temperature($T_c$) values of 1 mole monomer at reaction temperature. We varied feed rate of monomer, concentration of initiator and monomer to control molecular weight and polydispersity of prepolymer (GDNPF). The activated monomer polymerization has been executed with precisely controlled feed of GDNPF monomer to reactor in the complex state catalyst generated by $BF_3{\cdot}(C_3H_5)_2$ and 1,4-butanediol in $C_2H_4Cl_2$. Number average molecular weight(Mn), polydispersity(Pd), hydroxy number and glass transition temperature($T_g$) of prepolymer(GDNPF) were $2,500{\sim}3,000,\;1.2{\sim}1,3,\;0.6{\sim}0.8eq/kg\;and\;-20{\sim}-25^{\circ}C$ respectively.

Electrical Properties of Plasma Polymerized Hexamethyldisiloxane Thin Film (플라즈마 중합법에 의한 헥사메틸디실록산 박막의 전기적 특성)

  • 이상희;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.1
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    • pp.43-47
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    • 2001
  • Plasma polymerized hexamethyldisiloxane thin film was fabricated by employing an inter-electrode capacitively coupled type apparatus under the following conditions : carrier gas flow rate of 11 sccm, reaction pressure of 0.1 torr, discharge frequency of 13.56 MHz and discharge power of 30∼90 W. Polymerization rate of thin film fabricated at the discharge power of 90W is 32.5nm/min. Relative dielectric constant and dielectric loss tangent of thin film shows 3.2∼3.8 and 2.6x10$\^$-3/∼4.51x10$\^$-3/ respectively in the frequency range of 1 kHz∼1 MHz. As the annealing temperature is increased, the relative dielectric constant gradually decreases while the dielectric loss tangent increases. The current density increase gradually with increasing annealing temperature and electric field. The electric conduction of the heaxamethyldisiloxane thin film shows Schottky effect.

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Basic Studies on Propellant Casting (II). Effects of Solid Additives on Urethane Polymerization (추진제 성형에 관한 기초연구 (제2보). 우레탄 중합에 미치는 첨가제 효과)

  • Young Gu Cheun;Ik Choon Lee;Shi Choon Kim
    • Journal of the Korean Chemical Society
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    • v.25 no.4
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    • pp.214-218
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    • 1981
  • Kinetic studies were carried out on urethane polymerization reaction of hydroxyl-terminated polybutadiene with isophorone diisocyanate under presence of Hexogen as solid additive. The rate was found to increase with the amount of Hexogen added. However the rate acceleration was not a catalytic effect but solely due to an increase of activation entropy. The reaction was a good 2nd order process with nearly constant activation energy of 8.4 kcal/mole.

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Preparation of Microcapsules Containing Fragrant Oil and Its Application to Textile Finishing

  • Hwang, Jun-Seok;Kim, Jin-Nam;Wee, Young-Jung;Ryu, Hwa-Won;Yun, Jong-Sun;Jang, Hong-Gi;Kim, Sun-Ho
    • 한국생물공학회:학술대회논문집
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    • 2005.10a
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    • pp.860-863
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    • 2005
  • The microcapsules containing fragrant oil as functional material were prepared by in-situ polymerization with prepolymer that was made from melamine-formaldehyde (MF) as wall material of microcapsules. The effects of polymerization variables, such as the nature and concentration of surfactants, stirring rate, and stirring time, on the size and distribution of the particles were investigated. Fourier transform-infrared spectroscopy (FT-IR), thermal analysis, particle size analysis, scanning electron microscopy (SEM) observation were used to investigate the characteristics of microcapsules. Through the FT-IR and SEM analysis, we found that the prepared microcapsules were containing fragrant oil and the shape of particle was spherical. The nature and concentration of surfactants, stirring rate, and stirring time had profound effects on the particle size and particle size distribution.

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Effect of Light Intensity on the Polymerization Rate of Composite Resin Using Real-time Measurement of Volumetric Change

  • La, Sung-Ho;Lee, In-Bog;Cho, Byeong-Hoon;Son, Ho-Hyun
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.589.1-589
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    • 2001
  • The aim of this study is to evaluate the effect of light intensity variation on the polymerization rate of composite resin using IB system(experimental equipment designed by Dr. IB Lee) by which real-time volumetric change of composite can be measured. Methods: Three commercial composites [Z100(Z1), AeliteFil(AF), SureFil(SF)] were photopolymerized with Variable Intensity Polymerizer unit (Bisco, U.S.A.) under the variable light intensity (75/150/225/300/375/450㎽$^2$) during 20sec.(omitted)

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FINITE ELEMENT STRESS ANALYSIS OF CLASS V COMPOSITE RESIN RESTORATION SUBJECTED TO CAVITY FORMS AND PLACEMENT METHODS (와동 형태와 충전 방법에 따른 Class V 복합 레진 수복치의 유한요소법적 응력 분석)

  • Son, Yoon-Hee;Cho, Byeong-Hoon;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.25 no.1
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    • pp.91-108
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    • 2000
  • Most of cervical abrasion and erosion lesions show gingival margin where the cavosurface angle is on cementum or dentin. Composite resin restoration of cervical lesion shrink toward enamel margin due to polymerization contraction. This shrinkage has clinical problem such as microleakage and secondary caries. Several methods to diminish contraction stress of composite resin restoration, such as modifying cavity form and building up restorations in several increments have been attempted. The purpose of this study was to compare polymerization contraction stress of composite resin in Class V cavity subjected to cavity forms and placement methods. In this study, finite element model of 5 types of Class V cavity was developed on computer tomogram of maxillary central incisor. The types are : 1) Box cavity 2) Box cavity with incisal bevel 3) V shape cavity 4) V shape cavity with incisal bevel 5) Saucer shape cavity. The placement methods are 1) Incisal first oblique incremental curing 2) Bulk curing. An FEM based program for light activated polymerization is not available. For simulation of curing dynamics, time dependent transient thermal conduction analysis was conducted on each cavity and each placement method. For simulation of polymerization shrinkage, thermal stress analysis was performed with each cavity and each placement method. The time-temperature dependent volume shrinkage rate, elastic modulus, and Poisson's ratio were determined in thermal conduction data. The results were as follows : 1. With all five Class V cavifies, the highest Von Mises stress at the composite-tooth interface occurred at gingival margin. 2. With box cavity, V shape cavity and saucer cavity, Von Mises stress at gingival margin of V shape cavity was lower than the others. And that of box cavity was lower than that of saucer cavity. 3. Preparing bevel at incisal cavosurface margin decreased the rate of stress development in early polymerization stage. 4. Preparing bevel at incisal cavosurface margin of V shape cavity increased the Von Mises stress at gingival margin, but decreased at incisal margin. 5. At incisal margin, stress development by bulk curing method was rapid at early stage. Stress development by first increment of incremental curing method was also rapid but lower than that by bulk curing method, however after second increment curing final stress was the same for two placement methods. 6. At gingival margin, stress development by incremental curing method was suddenly rapid at early stage of second increment curing, but final stress was the same for two placement methods.

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Study of Emulsion Polymerization Condition of Aqueous Adhesive (유화중합을 이용한 수분산성접착제의 중합조건에 관한 연구)

  • Lee, HaengJa;Park, JiSun;Lee, SangRok;Kim, JongMin;Chang, SangMok
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.470-475
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    • 2009
  • To study the optimal synthesis conditions of aqueous acrylic adhesive using emulsion polymerization, the effects of monomer, surfactant and initiator on the adhesive properties, such as conversion rate, particle size, peel strength, and glass transition temperature, were investigated. 2-EHA, n-BA and MMA were used as main monomers, 2-HEMA and AAc as functional monomers, SLS as surfactant and APS as initiator, respectively. The conversion rate was over 95% at 3.75% surfactant(SLS/monomer), 0.612% initiator(APS/monomer) and $82^{\circ}C$ reaction temperature. When the excess amount of surfactant or initiator was used, the peel strength represented decreasing tendency. The maximum conversion rate and peel strength were obtained at 65% 2-EHA/monomer, 20% BA/monomer, and 10% MMA/monomer.

Polymerization and Application of Contact Lens Materials (콘택트렌즈 재료의 합성과 응용에 관한 연구)

  • Song, Kyung-Sek;Lee, Jong-Heon;Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.2
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    • pp.129-134
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    • 2003
  • A wide variety of unsaturated vinyl derivatives can be induced to undergo free-radical chain polymerization. The capability to carry out a thermodynamically feasible polymerization relies on its kinetic feasibility on whether the proceeds at a reasonable rate under a given set of reaction conditions. Initiator or promoter is often required to achieve the kinetic feasibility. Only a few unsaturated monomers including methyl methacrylate(MMA) are known to absorb light between 250 and 500 nm which is the most convenient wavelength range. Also, the polysilanes with unusual optical and electronic properties have been used as ceramic precursors, deep UV photoresists, photoconductors. The hydrosilation has been used to make many interesting types of silicon containing polymers such as copolymer, dendrimers. Bulk polymerization of monomers with different molar radio of hydrosilanes(9:1 through 1:9) were performed. A quartz test tube charged with monomer and hydrosilane was degassed and irradiated with 250 nm UV for 6 hours. The polymer was taken in toluene, precipitated in hexane, filtered off, and dried. It was found that the initiators appeared to competitively and concurrently function as both chain initiation and transfer agents in the polymerization of vinyl monomers.

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