• Title/Summary/Keyword: polymer-vae

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Study on Characteristics of Liner and Cover Material in Waste Landfill using VAE Resin (VAE 수지를 활용한 폐기물 매립지의 차수재 특성 연구)

  • Lee, Seung-Jae;Lee, Won-Ki
    • Journal of Environmental Science International
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    • v.28 no.5
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    • pp.503-509
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    • 2019
  • To prevent environmental pollution caused by leakage of leachate from waste landfill, vinyl acetate-ethylene (VAE) resin is applied to liner and cover materials to improve their performance. Styrene, styrene butadiene rubber, and VAE are widely used as polymer resins that have excellent water resistance and durability. Further, VAE resin is known to have additional advantages such as adhesion to nonpolar materials and resistance to saponification as a copolymer. In this study, the effect of VAE content on the properties of liner and cover materials was studied. The water and air content ratios, bending and compressive strengths, water absorption ratio, and coefficient of permeability of these materials were measured. The liner and cover materials with 4 wt% VAE showed good properties.

Mechanical Properties and Field Implementation of Floor Mortar Incorporated with VAE Polymer (VAE 폴리머를 이용한 모르타르 바닥재의 역학적 특성과 현작 적용성)

  • Bang, Jin-Wook;Lee, Sun-Mok;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.27-34
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    • 2017
  • Recently, the importance of the industrial warehouse floor has been increasing due to the development of the distribution and logistics industry. In this present study, an early-hardening polymer floor mortar which can compensate for the limitation of conventional cement based floor mortar regarding fluidity and long curing time was developed. In order to achieve the early-hardening of mortar characteristic ultra rapid hardening cement was used as binder. Four types of mixture proportions in accordance with the vinyl acetate ethylene(VAE) polymer contents with range from 10% to 20% and the other proto proportion without VAE polymer were designed. Mechanical experiments including the fluidity test, compressive strength test, bending test, bond test, and abrasion test were conducted for all mixture proportions. From the flow test result, it was possible to achieve the high flow with 250 mm by controlling the amount of superplasticizer. The incorporation of VAE polymer was found to affect the compressive strength reduction, however, the flexural strength was higher than that of the proto mixture, and it was evaluated to increase the compressive strength / flexural strength ratio. Moreover, at least 2.6 times higher bond strength and more than 4 times higher abrasion resistance were secured. From the mechanical experiments results, the optimum mixing ratio of the VAE polymer was determined to be 10%. As a result of application and monitoring, it shows that it has excellent resistance to cracking, discoloration, impact, and scratch as well as bond performance compared to the cement based floor mortar.

Effect of VAE Type Powder Polymer on Strength Properties of High Strength Polymer Cement Mortars (VAE 분말수지가 고강도 폴리머 시멘트 모르타르의 강도 특성에 미치는 영향)

  • Choi, Jung-Gu;Lee, Gun-Cheol;Ko, Kyung-Taek;Ryu, Gum-Sung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.299-306
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    • 2015
  • In construction materials area, many research on polymer for cement-based materials have been conducted. In spite of these research, general research scope is limited to the normal strength range, and thus in this research, for both normal and high strength range mixtures, the strength and mechanical properties of high strength cement mortar incorporating Vinyle Acetate-Ethylene(VAE) type powder polymer are evaluated. As a result of experiment, in the case of high strength mixture, as the amount of VAE polymer addition was increased the compressive and flexural strengths were decreased while the tensile and bonding strengths were increased because of the formation of the polymer membrane inside of the mortar matrix.

Impact Fracture Behavior under Temperature Variation and Compressive·Flexural Strength of Cement Composites using VAE Powder Polymer and PVA Fiber (PVA 섬유와 VAE 분말 폴리머를 사용한 시멘트복합체의 압축·휨강도 및 온도변화에 따른 충격파괴거동)

  • Heo, Gwang-Hee;Park, Gong-Gun;Kim, Chung-Gil;Lee, Hyung-Joon;Choi, Won-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.102-112
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    • 2019
  • This paper studies impact fracture behavior under temperature variation and compressive flexural strength of cement composites using VAE(vinyl acetate ethylene) powder polymer and PVA(polyvinyl alcohol) fiber. Impact test were conducted in the temperature range selected for the $-35^{\circ}C$, $0^{\circ}C$ and $35^{\circ}C$. In this experimental study, impact test were carried out using a drop impact testing machine (Ceast 9350) to obtain such as displacement, time, and impact fracture energy of normal specimen and and cement composites specimen. As test results, the use of VAE powder polymer and PVA fiber were observed to enhance the flexural strength of mortar. The compressive strength of PVA fibers reinforced cement composites was slightly decreased at 28 days, but the flexural strength was observed to increase 24.4% of normal mortar strength. As a result of the drop impact tests, PVA fiber reinforced cement composites specimens showed microcracks due to energy dispersion and crack prevention with bridge effect of the fibers, and scabbing or perforation by impact was suppressed. On the other hand, the normal mortar and VAE powder polymer cement composites specimens were carried out to the perforation and macro crack. Most of normal mortar and the cement composites subjected to impact load on specimens shows mostly local brittle failure. The impact resistant performance of the specimen with PVA fiber was greatly improved due to the increase of flexure performance.

Airtightness performance evaluation of ultra-high performance concrete using polymer coating materials (그래핀을 활용한 폴리머 도막재료의 물리적 특성 평가)

  • Lee, Hyun Seung;Kim, Kang Min;Yoon, Seob;Seo, Tae Suk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.257-258
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    • 2023
  • In this study, it was conducted to improve the physical properties of VAE polymer matrix used as a coating material. A nanocomposite was manufactured using graphene as a reinforcing agent based on a VAE matrix. As a result, improvements in tensile strength, adhesion strength, and porosity were confirmed.

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Film Properties of Cold Blending Emulsion Between Poly(vinyl Acetate) and Poly(vinyl acetate-co-ethylene) Emulsion (Poly(vinyl acetate)와 Poly(vinyl acetate-co-ethylene) 에멀젼을 이용한 상온 블렌드 에멀젼의 Film 특성)

  • Kim, Ho-Young;Yoo, Sung-Hee;Choi, Yong-Hae
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.117-124
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    • 2011
  • This study was made on the poly(vinyl acetate) (PVAc) and poly(vinyl acetate- ethylene) (VAE) emulsion polymer blend which used PVA as protective colloid, and the PVA used as protective colloid was existed in each emulsion film before blend and even in the film after the blend consecutively. It makes us expect excellent adhesive power among particles that form the blend. Emulsion blends with different Tg are important target of concerning, and PVAc/VAE emulsion blend suggested simple and excellent research method. As a result of blend, elongation was lowered by the increase of PVAc, and the plasticizer used in making PVAc affected on the Tg of blend and lowered Tg of VAE emulsion, and the synergy effect of two blends was seen for the tensile strength, thermal resistance, and adhesive strength.

Properties of Permeable Block using Artificial Permeable Pipe and Polymer Powder VAE to Improve Permeability (투수성을 개선시키기 위해 인공투수관 및 분말형 폴리머 VAE를 사용한 투수블록의 특성)

  • Yoo, Beong-Young;Lee, Won-Gyu;Pyeon, Su-Jeong;Kim, Dea-Yeon;Lee, Sang-Soo
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.5
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    • pp.447-453
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    • 2018
  • Since 1960, Korea the town center was developed intensively due to rapid industrial development. As a result of the development, the population was concentrated in urban areas and the green area was decreased. Due to the decrease of the green area, the circulation system of the rainwater was changed, hence the rainwater was not introduced into the groundwater., On the other hand, the water on the surface of the road was changed into the water for flowing to the river and evaporation. The changes in the water flow cause many problems, and the depletion of the groundwater does not create an environment in which microorganisms and plants can live. in Korea, permeable pavement construction is increased to solve these problems, but existing pavement blocks have many problems. The pores of the permeable block are clogged due to the accumulation of dust or whitening phenomenon, and the permeability is lost. In this study, the solution of the problems of existing permeable block were suggested by using polymer and artificial permeable pipe, and strength, permeability and service life are increased, The relationship between the substitution rate of the polymer and the mixing ratio of the artificial permeable pipe was analyzed.

Strength Properties of High-Strength Polymer Cement Mortars Containing VAE Powder (VAE계 분말을 혼입한 고강도 폴리머 시멘트 모르타르의 강도 특성)

  • Choi, Jung-Gu;Lee, Gun-Cheol;Lee, Gun-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.19-20
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    • 2014
  • This study is to find out the tensile strength and bonding strength of VAE powder as a preliminary study for the application of the powder to the high strength concrete. The result of the study showed that the compressive strength decreases when more polymers is put into the concrete. On the other hand, it showed that the tensile strength and the bonding strength get improved when the more polymers are put into the concrete. Especially in case of the mixture for high strength concrete, it was found out that more strength is produced than the ordinary concrete.

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Corrosion Protection of Rebars Using High Durability Polymer Cementitious Materials for Environmental Load Reduction (환경부하저감형 고내구성 폴리머 시멘트계 재료를 이용한 철근 부식저감기술)

  • Kim, Wan-Ki;Chung, Seung-Jin
    • KIEAE Journal
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    • v.10 no.5
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    • pp.131-137
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    • 2010
  • The building industry must aim at high-durability and sustainability. A holistic life cycle based approach is recommended to reduce the environmental load. In recent years, technical innovations in the construction industry have advanced to a great extent, and caused the active research and development of high-performance and multifunctional construction materials. Nowadays, various polymer powders have been commercialized to manufacture construction materials in the form of prepackaged-type products, which have rapidly been developed for lack of skilled workmen in construction sites. Recently, terpolymer powders of improved quality have been developed and commercialized as cement modifiers. And, hydrocalumite is a material that can adsorb the chloride ions (Cl-) causing the corrosion of reinforcing bars and liberate the nitrite ions (NO2-) inhibiting the corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. The purpose of this study is to ascertain the self-corrosion inhibition function of polymer-modified mortars using redispersible powders with hydrocalumite. Polymer-modified mortars using VA/E/MMA and VAE redispersible powders are prepared with various calumite contents and polymer-binder ratios, and tested for chloride ion penetration depth, corrosion inhibition. As a result, regardless of the polymer-binder ratio, the replacement of ordinary portland cement with hydrocalumite has a marked effect on the corrosion-inhibiting property of the polymer-modified mortars. Anti-corrosion effect of polymer-modified mortars using VA/E/MMA terpolymer powder with hydrocalumite is higher than that of VAE copolymer powder.

Properties of Polymer-Modified Mortars Using VAE Redispersible Powders

  • Joseph Ango, Aaron;Yang-Seob, Soh
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.252-255
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    • 2003
  • Recently, there is a growing trend in the United States toward replacing latex additives in polymer-modified cement mortars with redispersible polymer powders. This movement is relatively new in the U.S. but is further advanced in Europe due to the more extensive use of cement and concrete in residential construction. Hitherto, in Korea - there is a very diminutive movement towards this growing trend. Thus, there is limited availability of data on redispersible polymer powders. This study investigates the effectiveness of redispersible polymer powder on improvement of the mechanical properties of modified mortar. It was concluded from the results of the experiments that the size of the dispersed polymer particles, variations in glass transition points (Tg), and variations in minimum film formation temperature (MFT) influenced the strength development of the modified mortars, and optimum strength in modified mortars using redispersible powders can be achieved when the Tg which accounts for the degree of powder flexibility is considered.

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