• Title/Summary/Keyword: polymer wall

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Improvement of Flow Characteristics for Thin-Wall Injection Molding by Rapid Beating (급속 가열에 의한 박육 사출성형의 유동특성 개선)

  • Kim, Byung;Park, Keun
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.09a
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    • pp.9-12
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    • 2005
  • The rapid thermal response (RTR) molding is a novel process developed to raise the temperature of mold surface rapidly to the polymer melt temperature prior to the injection stage and then cool rapidly to the ejection temperature. The resulting filling process is achieved inside a hot mold cavity by prohibiting formation of frozen layer so as to enable thin wall injection molding without filing difficulty. The present work covers flow simulation of thin wall injection molding using the RTR molding process. In order to take into account the effects of thermal boundary conditions of the RTR mold, coupled analysis with transient heat transfer simulation is suggested and compared with conventional isothermal analysis. The proposed coupled simulation approach based on solid elements provides reliable thin wall flow estimation fur both the conventional molding and the RTR molding processes

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The Laminating process for Single Substrate Flexible LCD

  • Bae, Kwang-Soo;Choi, Yoon-Seuk;Kim, Hak-Rin;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1125-1128
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    • 2007
  • The laminating technique for developing flexible liquid crystal display was demonstrated by using a thin UV curable polymer film and a plastic substrate with patterned polymer wall structure. We adopted the rigid wall structure to provide a solid mechanical support for the stable molecular alignment of liquid crystals (LCs) in the device. The cover film was prepared to have an ability of aligning LC molecules by patterning a micro-groove structure using the soft-lithographic process. These two substrates can be assembled tightly by the laminating and one-step UV irradiation process because of the adhesive nature of the used UV curable polymers. Proposed method can be used to fabricate the flexible LC display with simplicity and also be applicable for a cost-effective roll-to-roll process.

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The Effect of Single Wall Carbon Nanotubes on the Dipole Orientation and Piezoelectric Properties of Polymeric Nanocomposites

  • Kang, Jin-Ho;Park, Cheol;Gaik Steven J.;Lowther Sharon E.;Harrison Joycelyn S.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.245-245
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    • 2006
  • Recent studies of single wall carbon nanotube (SWNT)/polyimide nanocomposites indicate that these materials have a potential to provide the combination of structural integrity and sensing/actuation capability. This study shows the effect of the SWNT type and concentration on the dipole orientation and piezoelectric properties of the electroactive polymide nanocomposites using a thermally stimulated current (TSC) spectroscopy. These nanocomposites exhibit very thermally stable piezoelectric properties up to $150^{\circ}C$. This presentation will highlight the dipole orientation and electroactive characteristics of the SWNT/polyimide nanocomposites and discuss their potential multifunctional aerospace applications.

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A study on the mix desing for stabilizing liquid of sluryy wall (Slury Wall용 안정액의 배합설계에 관한 연구)

  • ;;;Motoshige Ariyama
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.457-462
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    • 1999
  • The purpose of this study is to design the requirements for the materials of stabilizing slurry and to determine the optimum slruuy mix design used in the underground wall of Inchon LNG #213 and 214 tank. After the materials and mix conditions of stabilizing slurry investigated and tested, we propose materials and optimum mix design according to testing items including funnel viscosity, we propose materials and optimum mix design according to testing items including funnel viscosity, fluid loss, cake thickness and specific gravity. As this results, we select optimum mix design that the upper limit ratio of bentonite is 2.0%, polymer is 0.1% considering the funnel viscosity and dispersion agent is 0.05% considering the fluid loss. Also we select all materials which are composed of GTC4 as bentonite, KSTP as polymer and Bentocryl as dispersion agent. All test results are satisfied our specifications for stabilizing slurry.

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Conductive Polymer Coated Electro-active Paper (EAPap) as Hybrid Actuator (전도성 폴리머와 셀룰로오스 종이를 결합한 EAPap 작동기)

  • Yun, Sung-Ryul;Kim, Jae-Hwan;Ounaies, Zoubeida;Deshpande, S.D.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.11a
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    • pp.275-278
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    • 2004
  • Electro-Active Paper (EAPap) is attractive for EAP actuator due to its merit in terms of light weight, dry condition, large displacement output, low actuation voltage and low power consumption. The EAPap is based on cellulose paper, and is shown to involve primarily transport of ions in response to an external electric field. This actuating mechanism is similar to conductive polymer based actuators. For performance improvement of EAPap, hybrid actuators are tried. The actuators based on cellulose paper attached conducting polypyrrole, polyaniline and single wall carbon nanotube/polyaniline(emeraldine base) have been achieved by Electro chemical deposition and mechanical deposition of the polymers onto cellulose paper.

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Effects of polymer support fluid on shaft resistance of offshore bored piles

  • Chungsik Yoo;Chun-Won Shin
    • Geomechanics and Engineering
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    • v.33 no.5
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    • pp.519-528
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    • 2023
  • In this paper, we present the results of an experimental study on the effect of polymer support fluid on shaft resistance of offshore bored piles. A series of pullout tests were performed on bored piles installed under various boundary conditions considering different types of grounds and support fluids, and a range of support fluid exposure times. Contrary to previous studies concerning onshore bored piles, a time dependent effect of polymer fluid on shaft resistance was observed in all ground types. The adverse effect of polymer support fluid on the shaft resistance, however, was considerably less than bentonite support fluid for a given exposure time. No significant reduction in shaft resistance was evident when limiting the exposure time of the polymer support fluid to the side wall of the borehole within 2-3 hours. The degree to which the polymer fluid affects shaft resistance seemed to vary with the ground type. A proper consideration should be given to the time dependent effect of polymer fluid on shaft resistance of bored piles installed in offshore construction environment to limit its adverse effect on the pile performance. The practical implications of the findings are discussed.

Non-isothermal TGA Analysis on Thermal Degradation Kinetics of Modified-NR Rubber Composites (비등온 TGA에 의한 개질NR고무복합재료지 열분해 Kinetics에 관한 해석)

  • Oh, Jeong-Seok;Lee, Joon-Mann;Ahn, Won-Sool
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.435-440
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    • 2009
  • Thermal degradation behavior of CR (chloroprene) -modified NR (natural rubber) compounds, having different sulfur/accelerator compositions, was studied by non-isothermal TGA method. Data were analyzed using both Kissinger and Flynn-Wall-Ozawa analysis to assess the activation energies. Activation energy obtained from Kissinger analysis was $147.0{\pm}2.0$ kJ/mol for all samples, showing little effect of sulfur/accelerator composition changes in the samples. On the other hand, activation energy from Flynn-Wall-Ozawa analysis exhibited much variations with conversion, showing average value of $211.6{\pm}19.0$ kJ/mol. From the results, it was considered that whole thermal degradation processes of the samples were composed of complex multiple step processes, of which reaction mechanisms were different from each other.

A Study on the Development of Sound Absorption Material Using Perlite for Noise Barrier Wall (펄라이트를 이용한 방음벽의 흡음소재 개발에 관한 기초적 연구)

  • Jo, Young-Kug;Yang, Ju-Kyung
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.653-660
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    • 2008
  • The purpose of this study is to analyze the optimal mix design of the sound absorption material that is made from perlite and various binder systems for noise barrier wall. The polymer cement slurry which is made from two types of polymer dispersions, and silicone type inorganic material are used as binder. The test specimens are prepared with various polymer cement ratios, binder ratios, and tested for strengths, freezing and thawing and sound absorption performance by the tube and the reverberation room methods. From the test results, the difference of sound absorption coefficient by the tube method is a little recognized, however, noise reduction coefficient (NRC) of test specimens bound by the polymer cement slurry is in the ranges of 0.48 to 0.51. They are a little higher than those bound by cement only, and are lower values than recommended value of 0.7 by the Ministry of Environment. However, the sound absorption coefficient of test specimens at low frequency range of 250 to 500 Hz by reverberation room method shows very high values as 0.84 to 1.00, and 0.57 to 0.77 at the high frequency. The test specimens with polymer cement slurry binder have a good balance between performance and cost, and have proper properties in strengths, freezing and thawing resistance as sound absorption material for noise barrier wall. It is apparent that the good sound absorption material can be produced according to the optimum mix design that is recommended from this study.

Historical Consideration of Lignin Models for Native Lignin Structure (리그닌 화학구조 모델의 역사적 고찰)

  • 황병호
    • Journal of Korea Foresty Energy
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    • v.23 no.1
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    • pp.45-68
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    • 2004
  • The word of lignin is derived from the Latin word 'ligum' meaning wood. Lignin is complex polymer consisting of coniferyl alcohol, sinapyl alcohol and p-coumaryl alcohol unit and has an amorphous, three dimensional network structure which is hard to be hydrolyzed by acid. Lignin is found in the cell wall of plants lignified. The mode of polymerization of these alcohols in the cell wall lead to a heterogeneous branched and cross-linked polymer in which phenyl propane units are linked by carbon-carbon and carbon-oxygen bonds. This polymerization of precursors, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol to lignin is formed by enzymic dehydrolyzation. The reaction is initiated by an electron transfer which results in the formation of resonance-stabilized phenoxy radical. The combination of these radicals produces a variety of dimers, trimers and oligomers and so on. Lignin research has been divided into basic and practical application field. The basic studies contains biosynthesis, chemical structure, distribution in the cell wall and reactivity by reductants, oxidants and organic solvents. The application research will be approached the reaction of lignin in various pulp making involving pulp bleaching and its effect on pulp qualities. Lignin also will be studied for the production of fine chemicals, polymer products and the conservation into an energy source like petroleum oil because the amount of lignin produced in pulp making process is more than 51,000,000 tons per year in the world. Both basic and application research must lay emphasis on the development for the utilization of lignin and the pulping process. But these researches can not be completed without understanding lignin structure containing functional groups. Therefore, this paper was focused on the review of lignin formulation which has been studied since 1948 in chronological order. This review was based on monomers, dimers, trimers and tetramers of phenyl propane unit structures which were isolated and identified by different methods from various wood.ious wood.

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Synthesis of transparent conductive film containing solution -deposited poly (3, 4-ethylenedioxythiophene) (PEDOT) and water soluble multi-walled carbon nanotubes

  • Tung, Tran Thanh;Kim, Won-Jung;Kim, Tae-Young;Lee, Bong-Seok;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.205-206
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    • 2008
  • The transparent conductive film was prepared by bar coating method of poly (3, 4-ethylenedioxythiophene) (PEDOT) and poly (sodium 4-stylenesulfonate) grafted multi-walled carbon nanotubes (MWNT-PSS) nanocomposites solution on the polyethylene terephthalate (PET) film. In this case, multi-wall carbon nanotubes was treated by chemical methods to obtain water soluble MWNT-PSS and then blending with PEDOT. The non-covalent bonding of polymer to the MWNT surface was confirmed by Fourier transform infrared (FT-IR), thermal gravimetric analysis (TGA) and Transmission electro microscope (TEM) investigation also showed a polymer-wrapped MWNT structure. Furthermore, the electrical, transmission properties of the transparent conductive film were investigated and compared with control samples are raw PEDOT films.

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