• Title/Summary/Keyword: polymer wall

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Preparation and Evaluation of Sustained Release Aspirin Microcapsules Using Eudragit $RS^{\circledR}$ Polymer (Eudragit $RS^{\circledR}$를 이용한 지속 방출형 아스피린 마이크로캅셀의 제조 및 평가)

  • Chun, In-Koo;Shin, Dong-Won
    • YAKHAK HOEJI
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    • v.32 no.1
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    • pp.26-39
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    • 1988
  • Eudragit $RS^{\circledR}$ polymer was used as a wall material for the microencapsulation of aspirin by a phase separation method from chloroform-cyclohexane system with 5% polyisobutylene (PIB) in cyclohexane, and microcapsules obtained were evaluated by particle size analysis, scanning electron microscopy (SEM), drug release and drug stability test. With PIB as a coacervation inducing agent, smooth and tight microcapsules with less aggregation were obtained. Below 1 : 0.3 core-wall ratio, it was possible to coat individual particle. Variation of production conditions showed that increasing the proportion of wall material, particle size and wall thickness of microcapsules and the concentration of paraffin wax in cyclohexane as a sealant sustained drug release rates effectively. SEM confirmed that larger microcapsules after drug release did not rupture into smaller particles but contained a few small pores on the surface. Aspirin release from Eudragit $RS^{\circledR}$ coated microcapsules was independent of the pH of medium, and the mechanism of drug release from non-sealed and sealed microcapsules appeared to fit Higuchi matrix model kinetics. Aspirin in the mixture of aspirin microcapsules and sodium bicarbonate was by far more stable than that in the mixture of pure aspirin and sodium bicarbonate.

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Enhancement of Electrocatalytic Activity upon the Addition of Single Wall Carbon Nanotube to the Redox-hydrogel-based Glucose Sensor

  • Kim, Suk-Joon;Quan, Yuzhong;Ha, Eunhyeon;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.33-37
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    • 2021
  • In electrochemical glucose sensing, the enhancement of the sensitivity and the response time is essential in developing stable and reliable sensors, especially for continuous glucose monitoring. We developed a method to increase the sensitivity and to shorten the response time for the sensing upon the appropriate addition of single wall carbon nanotube onto the osmium polymer-based hydrogel electrode. Also, the background stabilization is dramatically enhanced.

A Study on the Drag Reduction of Shear Thinning Fluid with Vertical upward Turbulent Flow (전단박화유체의 수직상향 난류유동시 저항감소에 관한 연구)

  • Cha, Kyong-Ok;Kim, Bong-gag;Kim, Jea-Geun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.12
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    • pp.1647-1656
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    • 1998
  • The drag reduction is the phenomenon that occurs only when the shear stress from the wall of pipe is beyond the critical point. The drag reduction increase as the molecular weight, concentration of the polymer and Reynolds number increase, but it is limited by Virk's maximum drag reduction asymptote. Because of the strong shear force for the polymer on the turbulent flow, the molecular weight and the drag reduction do not decrease. Such mechanical degradation of the polymer occurs in all polymer solvent systems. This paper is to identify and develop high performance polymer additives for fluid transportations with the benefits of turbulent drag reduction. In addition, drag reduction in vertical flow by measuring the pressure drop and local void fraction on vertical-up flow of close system is evaluated.

Experimental Study on Frictional Drag Reduction of Turbulent Flow by Polymer Solution Injection (폴리머 수용액 주입에 의한 난류마찰저항 감소에 대한 실험 연구)

  • 김형태;김덕수;김우전
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.3
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    • pp.9-15
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    • 2003
  • An experimental study has been carried out as a basic research for development of the friction drag reduction technology for ships by polymer injection. Experimental apparatus and procedures have been devised and prepared to measure the changes of the wall friction with injection of a polymer solution and basic experimental data on the friction drag reduction are obtained for a turbulent fiat-plate boundary layer and fully-developed channel flows. Variations of the friction drag reduction with some important parameters of polymer injection, such as the concentration of polymer solution, its injection flow rate and the measuring position downstream from the injection slot, are also investigated. Important experimental data and results obtained in the present study are presented. The amount of friction drag reduction up to 50% is observed.

Evaluation of Shear Strength of Unreinforced Masonry Walls Retrofitted by Fiber Reinforced Polymer Sheet (FRP로 보강한 비보강 조적 벽체의 전단강도 산정)

  • Bae, Baek-Il;Yun, Hyo-Jin;Choi, Chang-Sik;Choi, Hyun-Ki
    • Journal of the Korea Concrete Institute
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    • v.24 no.3
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    • pp.305-313
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    • 2012
  • Unreinforced masonry buildings represent a significant portion of the existing and historical buildings around the world. Recent earthquakes have shown the need for seismic retrofitting for these types of buildings. Various types of retrofitting materials (i.e., shotcrete, ECC and Fiber Reinforced Polymer sheets (FRPs)) for unreinforced masonry buildings (URM) have been developed. Engineers prefer to use FRPs, because these materials enhance the shear strength of the wall without expansion of wall sectional area and adding weight to the total structure. However, the complexity of the mechanical behavior of the masonry wall and the lack of experimental data from walls retrofitted by FRPs may cause problems for engineers to determine an appropriate retrofitting level. This paper investigate in-plane behavior of URM and retrofitted masonry walls using two different types of FRP materials to determine and provide information for the retrofitting effect of FRPs on masonry shear walls. Specimens were designed to idealize the wall of a low-rise apartment which was built in 1970s in Korea with no seismic reinforcements with an aspect ratio of 1. Retrofitting materials were carbon FRP and Hybrid sheets which have different elastic modulus and ultimate strain capacities. Consequently, this study evaluated the structural capacity of masonry shear walls and the retrofitting effect of an FRP sheet for in-plane behavior. Also, the results were compared to the results obtained from the evaluation method for a reinforced concrete beam retrofitted with FRPs.

A Study on the Drag Reduction with Polymer Additives (고분자물질(高分子物質) 첨가(添加)에 따른 마찰저항감소(摩擦抵抗減少)에 관한 연구(硏究))

  • Kim, J.G.;Cha, K.O.;Choi, H.J.;Kim, C.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.2
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    • pp.198-207
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    • 1996
  • It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity, and turbulent intensity whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with the inner diameter of 24mm and the length of 1,500mm. The polymer materials used are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results showed that the drag reduction of co-polymer is higher than that of polyacrylamide. Mean liquid velocities increased as polymer was added, and turbulent intensity decreased inversely near the pipe wall.

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Field Application of Permeable Polymer Concrete Pipe for Drainage (집.배수용 투수성 폴리머 콘크리트 관의 농업 수리시설물의 현장적용)

  • 민정기;연규석;성찬용
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.6
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    • pp.136-143
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    • 2003
  • This study is performed to evaluate performance of the developed pipe when using for underground drainage in fm land, the efficiency of the pipe is examined such as quantity of drainage, water temperature and other field performance in all weather condition. Results of this study, the higher permeability through wall of the pipe is achieved by making various size pores using open-graded aggregate. And in all weather conditions, permeable polymer concrete pipe perform much better than conventional perforated pipes. During rice farming period, quantity of drainage the permeable polymer concrete pipe is 1.25 time greater than conventional perforated pipes. Therefore, use of the permeable polymer concrete pipe is greater advantages when considering collecting and draining capacity compared with conventional perforated pipes.

Drag Reducton of Pipe Wall For Fluid Flow due to Injected Polymer Solution - III. Consideration of Entrance Region Flow of Drag Reducing Fluids- (고분자용액에 의한 유체수송관벽의 저항감소 -III. 저항감소유체의 입구흐름 영역에 대한 고찰-)

  • 김영보;유경옥
    • Fire Science and Engineering
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    • v.5 no.2
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    • pp.21-35
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    • 1991
  • As a part of studies of drag reduction phenomenon, at the entrance flow region of abrupt contraction tube flowing water, dilute and concentrated drag reducing polymer solutions contraction losses are estimated experimentally. Futher more, entrance lengths are considered theoretically and are measured experimentally. In the present experiment, fluid temperature is fixed l$0^{\circ}C$ and flow rates are 3,000

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Study of Equivalent Retention among Different Polymer-Solvent Systems is Thermal Field-Flow Fractionation

  • 김원숙;박영훈;문명희;유유경;이대운
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.868-874
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    • 1998
  • An equivalent retention has been experimentally observed in thermal field-flow fractionation (ThFFF) for different polymer-solvent systems. It is shown that iso-retention between two sets of polymer-solvent systems can be obtained by adjusting the temperature difference (ΔT) according to the difference in the ratio of ordinary diffusion coefficient to thermal diffusion coefficient. This method uses a compensation of field strength (ΔT) in ThFFF at a fixed condition of cold wall temperature. It is applied for the calculation of molecular weight of polymers based on a calibration run of different standards obtained at an adjusted AT. The polymer standards used in this study are polystyrene (PS), polymethylmethacrylate (PMMA), and polytetrahydrofuran (PTHF). Three carrier solvents, tetrahydrofuran (THF), methylethylketone (MEK) and ethylacetate (ETAc) were employed. Though the accuracy in the calculation of molecular weight is dependent on the difference in the slope of log λ vs. log M which is related to Mark-Houwink constant a, it shows reasonable agreement within about 6% of relative error in molecular weight calculation for the polymer-solvent systems having similar a value.

A Study on Improvement of Flow Characteristics for Thin-Wall Injection Molding by Rapid Mold Heating (급속 금형가열에 의한 박육 사출성형의 유동특성 개선에 관한 연구)

  • Park Keun;Kim Byung H.
    • Transactions of Materials Processing
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    • v.15 no.1 s.82
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    • pp.15-20
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    • 2006
  • The rapid thermal response (RTR) molding is a novel process developed to raise the temperature of mold surface rapidly to the polymer melt temperature prior to the injection stage and then cool rapidly to the ejection temperature. The resulting filling process is achieved inside a hot mold cavity by prohibiting formation of frozen layer so as to enable thin wall injection molding without filling difficulty. The present work covers flow simulation of thin wall injection molding using the RTR molding process. In order to take into account the effects of thermal boundary conditions of the RTR mold, coupled analysis with transient heat transfer simulation is suggested and compared with conventional isothermal analysis. The proposed coupled simulation approach based on solid elements provides reliable thin wall flow estimation for both the conventional molding and the RTR molding processes.