• Title/Summary/Keyword: polymer structure

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Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

Transflective liquid crystal display with single cell gap and simple structure

  • Kim, Mi-Young;Lim, Young-Jin;Jeong, Eun;Chin, Mi-Hyung;Kim, Jin-Ho;Srivastava, Anoop Kumar;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.340-343
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    • 2008
  • This work reports the simple fabrication of the single cell gap transflective liquid crystal display (LCD) using wire grid polarizer. The nano sized wire grid polarizer was patterned on common electrode itself, on the reflective part of FFS (Fringe field switching) mode whereas the common electrode was unpatterned at transmissive part. However, this structure didn't show single gamma curve, so we further improved the device by patterning the common electrode at transmissive part. As a result, V-T curve of proposed structure shows single gamma curve. Such a device structure is free from in-cell retarder, compensation film and reflector and furthermore it is very thin and easy to fabricate.

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Numerical Analysis of Cyclic Deformation of Polymer Foam Film Using Stretched Truncated Octahedron Model (모서리가 제거된 팔면체 인장모델을 이용한 다공성 폴리머 박막의 반복변형거동 수치해석)

  • Yoo, Ui-Kyung;Lee, Young-Seog
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.3
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    • pp.104-110
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    • 2010
  • Cyclic deformations of polymer foam film are simulated using the finite element method. Material of polymer foam film is polypropylene (PP). The calculated polymer foam film is micro-scale thin film has cellular structure. The polymer foam film is used in ferro-electret applications. The polymer foam film is idealized to one cell structure as lens shaped stretched truncated octahedron model. Cyclic deformation is performed by uniaxial stretching. Stretching direction is perpendicular to plane of cellular film. Various cyclic strain amplitudes, pore wall thicknesses, pore shape are investigated to find deformation tendency of cellular structure. Consequently, cellular structure has various macroscopic stresses on cyclic deformation with various pore thickness and pore shape.

Structures of Two-dimensional Ring Polymer Solutions using Bond Fluctuation Model

  • Shin, Donghan;Lee, Eunsang;Jung, YounJoon
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.155-162
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    • 2016
  • This study attempts to reveal structures of two-dimensional ring polymer solutions in various polymer concentrations ranging from dilute to concentrated regime. Polymer sizes, single molecule structure factors, bond correlation functions and monomer density distribution functions from center of mass are given in order to clarify the polymer structures. Our study shows that a ring in dilute solution maintain pseudo-circular structure with self-avoiding walk (SAW) statistics, and it seems to be composed of two connecting SAW linear chains. In semidilute solutions, ring polymers are not entangled with each other and adopt collapsed configurations. Such assumption of collapsed structures in the semidilute regime gives an overlap concentration of ${\varphi}^*{\sim}N^{-1/2}$ where N is degree of polymerization. By normalizing the polymer concentration by these overlap concentration, we find universal behaviors of polymer sizes and structure factors regardless of N.

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X-ray Scattering Studies on the Structure of Porcine Pepsin in Various pH Solutions

  • Jin, Kyeong-Sik;Jin, Sang-Woo;Yoon, Jin-Hwan;Heo, Kyu-Young;Kim, Jae-Han;Kim, Hee-Soo;Ree, Moon-Hor
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.348-348
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    • 2006
  • In the present study, porcine pepsin in various pH conditions was investigated by small-angle X-ray scattering (SAXS) in order to detailed information on the structure and its variations with pH conditions. These analyses identified the structure of pepsin, and compared with that obtained by single crystallography. Moreover, this study found the structure' variations with changing pH conditions. All the results will be discussed with considering the conformational characteristics of pepsin in solution and further correlate to the biological and spectroscopic characteristics reported previously.

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Strain hardening behavior of linear polymer melts

  • Hong Joung Sook;Ahn Kyung Hyun;Lee Seung Jong
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.213-218
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    • 2004
  • Linear high-density polyethylene (PE) was controlled to induce strain-hardening behavior by introducing a small amount of second component with an anisotropic structure. In order to form an anisotropic structure in the PE matrix, the polymer was extruded through a twin-screw extruder, and the structure was controlled by varying the extrusion conditions. Depending on conditions, the second component formed a film, thread and droplet structure. If the second component was kept rigid, the morphology evolution could be delayed and the second component could maintain its film or thread structure without further relaxation. In par­ticular, the second component of the thread structure made a physical network and gave rise to remarkable strain hardening behavior under high extension. This study suggests a new method that induces strain hard­ening behavior by introducing a physically networked second component into the linear polymer melt. This result is anticipated to improve the processibility of linear polymers especially when extensional flow is dominant, and to contribute to our understanding of strain hardening behavior.

Characterization of Mechanical Property Change in Polymer Aerogels Depending on the Ligand Structure of Acrylate Monomer

  • Lee, Kyu-Yeon;Jung, Hae-Noo-Ree;Mahadik, D.B.;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.15-20
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    • 2016
  • In an effort to overcome the weakness of aerogel, polymer aerogels have been prepared by copolymerizing the different types of monomers through sol-gel process. Polymerizing the successive phase of a high internal phase emulsion, which has interconnected porous structure, porous polymer aerogel can be manufactured. In this paper, we use the styrene/divinylbenzene chain as a basic monomer structure, and additionally use 2-ethylhexyl methacrylate (2-EHMA) or 2-ethylhexyl acrylate (2-EHA) as monomers for distinguishing the visible mechanical properties of synthesized polymer aerogel. We can observe the different tendency of polymer aerogels by kinds of monomer or ratio. Flexibility and microstructure can be changed by the types of monomer. EHA polymer aerogel shows high flexibility and thin microstructure, and EHMA polymer aerogel shows high hardness and thick microstructure. EHA/EHMA polymer aerogel shows the intermediate nature between them. By utilizing the mechanical properties of three types of polymer aerogels to adequate situation or environment, polymer aerogels could be used as drug agent, ion exchange resin, oil filter and insulator, and so on.

POSS/Polyurethane Hybrids and Nanocomposites: A Review on Preparation, Structure and Performance

  • Diao, Shuo;Mao, Lixin;Zhang, Liqun;Wang, Yiqing
    • Elastomers and Composites
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    • v.50 no.1
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    • pp.35-48
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    • 2015
  • Polyhedral oligomeric silsesquioxane (POSS) is an important inorganic-organic hybrid material with a three-dimensional structure. Polyurethane (PU) is a widely applied polymer that has versatile properties with the change of two phase structure. When POSS is incorporated into PU by physical or chemical methods, many properties can be greatly improved, such as mechanical properties, thermal stability, biodegradation resistance, and water resistance. This paper reviews the recent progress in preparation, structure, and performance of POSS-modified polyurethane from the viewpoint of physical blending and chemical modification.

Electromagnetic Shielding Polymer Composites with Segregated Structure for Automotive Part Application: A Review (자동차 부품 적용을 위한 Segregated structure를 갖는 전자파 차폐용 고분자 복합소재 연구동향)

  • Lee, Jinwoo;Suhr, Jonghwan
    • Composites Research
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    • v.35 no.4
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    • pp.223-231
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    • 2022
  • With the rapid growth of the future mobility market, a large number of electronic parts are being used in automobile, and the importance of electromagnetic interference (EMI) shielding in the automobile market is growing to minimize malfunctioning among the parts. Accordingly, conductive polymer composites (CPCs) are getting a lot of attention as EMI shielding materials for the automotive, but there are still challenges in CPCs like high content of conductive filler to achieve proper EMI shielding effectiveness, and poor mechanical properties. This paper introduces main methods to manufacture CPCs with segregated filler structure, which can significantly reduce the filler content, and analyzes EMI shielding performance of each manufacturing method.

Effect of the Molecular Structure of Rubbed Polyimide Films for Surface Liquid Crystal Alignment of Nematic Liquid Crystal (네마틱 백정의 표면 액정 배향에관한 폴리이미드막의 분자 구조의 효과)

  • 서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.232-234
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    • 1996
  • We have investigated the effect of molecular structure of polymer of rubbed polyimide (PI) films for surface liquid crystal alignment. To obtain surface alignment effect of Polymer molecular structure, we measured the polar (out of plane-tilt) anchoring strength and surface ordering of 5CB on rubbed PI surfaces. We have found that the polar anchoring strength of 5CB is depend on the polymer molecular structure of these unidirectionally rubbed PI surfaces.

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