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http://dx.doi.org/10.7473/EC.2015.50.1.035

POSS/Polyurethane Hybrids and Nanocomposites: A Review on Preparation, Structure and Performance  

Diao, Shuo (Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology)
Mao, Lixin (Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology)
Zhang, Liqun (Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology)
Wang, Yiqing (Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology)
Publication Information
Elastomers and Composites / v.50, no.1, 2015 , pp. 35-48 More about this Journal
Abstract
Polyhedral oligomeric silsesquioxane (POSS) is an important inorganic-organic hybrid material with a three-dimensional structure. Polyurethane (PU) is a widely applied polymer that has versatile properties with the change of two phase structure. When POSS is incorporated into PU by physical or chemical methods, many properties can be greatly improved, such as mechanical properties, thermal stability, biodegradation resistance, and water resistance. This paper reviews the recent progress in preparation, structure, and performance of POSS-modified polyurethane from the viewpoint of physical blending and chemical modification.
Keywords
polyhedral oligomeric silsesquioxane; polyurethane nanocomposites;
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1 R. Hernandez, J. Weksler, A. Padsalgikar, T. Choi, et al., "A comparison of phase organization of model segmented polyurethanes with different intersegment compatibilities", Macromolecules, 41, 9767 (2008).   DOI
2 A. M. Castagna, A. Pangon, T. Choi, G. P. Dillon, and J. Runt, "The role of soft segment molecular weight on microphase separation and dynamics of bulk polymerized polyureas", Macromolecules, 45, 8438 (2012).   DOI
3 Z. S. Petrovic and J. Ferguson, "Polyurethane elastomers", Prog. Polym. Sci., 16, 695 (1991).   DOI
4 R. Udagama, E. Degrandi-Contraires, C. Creton, C. Graillat, T. F. McKenna, and E. Bourgeat-Lami, "Synthesis of Acrylic-Polyurethane Hybrid Latexes by Miniemulsion Polymerization and Their Pressure-Sensitive Adhesive Applications", Macromolecules, 48, 2632 (2011).
5 A. Samimi and S. Zarinabadi, "Application Polyurethane as Coating in Oil and Gas Pipelines", Int. J. Sci. Invest., 43 (2012).
6 L. F. Cabeza, A. Castell, M. Medrano, I. Martorell, G. Perez, and I. Fernande, "Experimental study on the performance of insulation materials in Mediterranean construction", Energ. Buildings, 42, 630 (2010).   DOI
7 M. S. El-Shahawi, A. S. Bashammakh, A. A. Al-Sibaai, M. I. Orief, and F. M. Al-Shareef, "Solid phase preconcentration and determination of trace concentrations of total gold (I) and/or (III) in sea and wastewater by ion pairing impregnated polyurethane foam packed column prior flame atomic absorption spectrometry", Miner. Process, 100, 110 (2011).   DOI
8 D. W. Scott, "Thermal Rearrangement of Branched-Chain Methylpolysiloxanes1", Am. Chem. Soc., 68, 356 (1946).   DOI
9 F. J. Feher, D. A. Newman, and J. F. Walzer, "Silsesquioxanes as models for silica surfaces", J. Am. Chem. Soc., 111, 1741 (1989).   DOI
10 J. D. Lichtenhan, Y. A. Otonari, and M. J. Carr, "Linear hybrid polymer building blocks: methacrylate-functionalized polyhedral oligomeric silsesquioxane monomers and polymers", Macromolecules, 28, 8435 (1995).   DOI
11 P. D. Lickiss and F. Rataboul, "Fully condensed polyhedral oligosilsesquioxanes (POSS): from synthesis to application", Adv. Organomet. Chem., 57, 1 (2008).
12 R. H. Baney and X. Cao, "Polysilsesquioxanes", Silicon-Containing Polymers, 157 (2000).
13 G. Li, L. Wang, H. Ni, and C. U. Pittman Jr, "Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: a review", J. Inorg. Organomet. Polym., 11, 123 (2001).   DOI
14 Y. Liu, X. Yang, W. Zhang, and S, Zheng, "Star-shaped poly (${\varepsilon}$-caprolactone) with polyhedral oligomeric silsesquioxane core", Polymer, 47, 6814 (2006).   DOI
15 M. A. Hoque, Y. H. Cho, and Y. Kawakami, "High performance holographic gratings formed with novel photopolymer films containing hyper-branched silsesquioxane", React. Funct. Polym, 67, 1192 (2007).   DOI
16 Y. Ni, S. Zheng, and K. Nie, "Morphology and thermal properties of inorganic-organic hybrids involving epoxy resin and polyhedral oligomeric silsesquioxanes", Polymer, 45, 5557 (2004).   DOI
17 B. H. Tan, H. Hussain, and C. B. He, "Tailoring Micelle Formation and Gelation in (PEG-P (MA-POSS)) Amphiphilic Hybrid Block Copolymers", Macromolecules, 44, 622 (2011).   DOI
18 F. Mammeri, C. Bonhomme, F. Ribot, and S. Dire, "New monofunctional POSS and its utilization as dewetting additive in methacrylate based free-standing films", J. Chem. Mater., 21, 4163 (2009).   DOI
19 N. Fritz, H. C. Koo, Z. Wilson, E. Uzunlar, and Z. Wen, "Electroless deposition of copper on organic and inorganic substrates using a Sn/Ag catalyst", J. Electrochem. Soc., 111, 1741 (1989).
20 J. Wei, B. H. Tan, Y. Bai, J. Ma, and X. Lu, "Self-assembly behaviors of telechelic poly (styrene-Ran-sodium styrenesulfonate) with polyhedral oligomeric silsesquioxane as End groups", J. Phys. Chem. B, 115, 1929 (2011).   DOI
21 S. Sulaiman, A. Bhaskar, J. Zhang, R. Guda, T. Goodson Iii, and R. M. Laine, "Molecules with perfect cubic symmetry as nanobuilding blocks for 3-D assemblies. Elaboration of octavinylsilsesquioxane. Unusual luminescence shifts may indicate extended conjugation involving the silsesquioxane core", Chem. Mater., 20, 5563 (2008).   DOI
22 E. Kharlampieva, V. Kozlovskaya, B. Wallet, et al., "Cocross-linking silk matrices with silica nanostructures for robust ultrathin nanocomposites", ACS nano, 2, 7053 (2010).
23 K. Koh, S. Sugiyama, T. Morinaga, K. Ohno, Y. Tsujii, et al., "Precision synthesis of a fluorinated polyhedral oligomeric silsesquioxane-terminated polymer and surface characterization of its blend film with poly (methyl methacrylate)", Macromolecules, 38, 1264 (2005).   DOI   ScienceOn
24 S. C. Chan, S. W. Kuo, H. S. She, H. M. Lin, H. F. Lee, and F. C. Chang, "Supramolecular aggregations through the inclusion complexation of cyclodextrins and polymers with bulky end groupss", J. Polym. Sci. Polym. Chem., 45, 125 (2007).   DOI
25 R. H. Baney, M. Itoh, A. Sakakibara, and T. Suzuki, "Silsesquioxanes", Chem. Rev., 95, 1409 (1995).   DOI
26 G. Li, L. Wang, H. Ni, and C. U. Pittman Jr, "Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: a review", J. Inorg. Organomet. Polym., 11, 123 (2001).   DOI
27 K. Xie, Y. Zhang, and Y. Yu, "Preparation and characterization of cellulose hybrids grafted with the polyhedral oligomeric silsesquioxanes (POSS)", Carbohyd. Polym., 77, 858 (2009).   DOI
28 S. A. Madbouly and J. U. Otaigbe, "Recent advances in synthesis, characterization and rheological properties of polyurethanes and POSS/polyurethane nanocomposites dispersions and films", Prog. Polym. Sci., 43, 1283 (2009).
29 W. Zhang, B. Fang, A. Walther, and A. H. Muuller, "Synthesis via RAFT polymerization of tadpole-shaped organic/inorganic hybrid poly (acrylic acid) containing polyhedral oligomeric silsesquioxane (POSS) and their self-assembly in water", Macromolecules, 42, 2563 (2009).   DOI   ScienceOn
30 J. Y. Lee, Y. M. Lee, B. Bhattacharya, Y. C. Nho, and J. K. Park, "Solid polymer electrolytes based on crosslinkable polyoctahedral silsesquioxanes (POSS) for room temperature lithium polymer batteries", J. Solid. State. Electr., 14, 1445 (2010).   DOI
31 M. Xue, X. Zhang, Z. Wu, H. Wang, X. Ding, and X. Y Tian, "Preparation and Flame Retardancy of Polyurethane/POSS Nanocomposites", Chin. J. Chem. Phys., 26, 445 (2013).   DOI
32 H. J. Kim, C. K. Kim, and Y. Kwon, "Ablation and fire-retardant properties of hydroxyl-terminated polybutadiene-based polyurethane-g-polyhedral oligomeric silsesquioxane composites", High Perform Polym., (2014).
33 W. Hao, C. Fang, J. Yu, L. Zhang, and T. Xue, "Polyurethane electrospun mats strengthened and toughened by physically blended polyhedral oligomeric silsesquioxane", J. Appl. Polym. Sci., 131, 20 (2014).
34 S. Bourbigot, T. Turf, S. Bellayer, and S. Duquesne, "Polyhedral oligomeric silsesquioxane as flame retardant for thermoplastic polyurethane", Polym. Degrad. Stabil., 94, 1230 (2009).   DOI
35 E. Ayandele, B. Sarkar, and P. Alexandridis, "Polyhedral oligomeric silsesquioxane (POSS)-containing polymer nanocomposites", Nanomaterials, 2, 445 (2012).   DOI
36 J. D. Lichtenhan, "Polyhedral oligomeric silsesquioxanes: building blocks for silsesquioxane-based polymers and hybrid materials", Comment Inorg. Chem., 17, 115 (1995).   DOI
37 X. Gu, J. Wu, and P. T. Mather, "Polyhedral oligomeric silsesquioxane (POSS) suppresses enzymatic degradation of PCLbased polyurethanes", Biomacromolecules, 12, 3066 (2011).   DOI
38 G. Pan, "Polyhedral oligomeric silsesquioxane (POSS)", Physical Properties of Polymers Handbook, 577 (2007).
39 D. B. Cordes, P. D. Lickiss, and F. Rataboul, "Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes", Chem. Rev., 110, 2081 (2010).   DOI
40 A. K. Nanda, D. A. Wicks, S. A. Madbouly, and J. U. Otaigbe, "Nanostructured polyurethane/POSS hybrid aqueous dispersions prepared by homogeneous solution polymerization", Macromolecules, 39, 7037 (2006).   DOI
41 S. A. Madbouly, J. U. Otaigbe, A. K. Nanda, and D. A. Wicks, "Rheological behavior of POSS/polyurethane-urea nanocomposite films prepared by homogeneous solution polymerization in aqueous dispersions", Macromolecules, 40, 4982 (2007).   DOI
42 S. Turri and M. Levi, "Structure, dynamic properties, and surface behavior of nanostructured ionomeric polyurethanes from reactive polyhedral oligomeric silsesquioxanes", Macromolecules, 38, 5569 (2005).   DOI
43 K. N. Raftopoulos, C. Pandis, L. Apekis, P. Pissis, B. Janowski, K. Pielichowski, and J. Jaczewska, "Polyurethane-POSS hybrids: Molecular dynamics studies", Polymer, 5, 709 (2010).
44 K. N. Raftopoulos, M. Jancia, D. Aravopoulou, E. Hebda, K. Pielichowski, and P. Pissis, "POSS along the Hard Segments of Polyurethane. Phase Separation and Molecular Dynamics", Macromolecules, 46, 7378 (2013).   DOI
45 B. Janowski and K. Pielichowski, "A Kinetic Analysis of the Thermo-Oxidative Degradation of PU/POSS nanohybrid Elastomers", Silicon, 1, (2014).
46 J. P. Lewicki, S. J. Harley, A. Loui, K. Pielichowski, B. P. Mayer, B. Janowski, and R. S. Maxwell, "The influence of polyhedral oligomeric silsequioxanes on domain microstructure in polyurethane elastomers", Silicon, 5, 205 (2013).   DOI
47 S. Zhang, Q. Zou, and L. Wu, "Preparation and characterization of polyurethane hybrids from reactive polyhedral oligomeric silsesquioxanes", Macromol. Mater. Eng., 291, 895 (2006).   DOI
48 B. Janowski and K. Pielichowski, "Thermo (oxidative) stability of novel polyurethane/POSS nanohybrid elastomers", Thermochim. Acta, 478, 51 (2008).   DOI
49 J. P. Lewicki, K. Pielichowski, P. T. De La Croix, B. Janowski, D. Todd, and J. J. Liggat, "Thermal degradation studies of polyurethane/POSS nanohybrid elastomers", Polym. Degrad. Stabil., 95, 1099 (2010).   DOI
50 J. P. Lewicki, K. Pielichowski, M. Jancia, E. Hebda, R. L. Albo, and R. S. Maxwell, "Degradative and morphological characterization of POSS modified nanohybrid polyurethane elastomers", Polym. Degrad. Stabil., 104, 50 (2014).   DOI
51 B. X. Fu, B. S. Hsiao, S. Pagola, P. Stephens, H. White, et al., "Structural development during deformation of polyurethane containing polyhedral oligomeric silsesquioxanes (POSS) molecules", Polymer, 42, 599 (2001).   DOI
52 B. X. Fu, B. S. Hsiao, H. White, M. Rafailovich, et al., "Nanoscale reinforcement of polyhedral oligomeric silsesquioxane (POSS) in polyurethane elastomer", Polymer, 49, 437 (2000).
53 P. T. Knight, K. M. Lee, H. Qin, and P. T. Mather, "Biodegradable thermoplastic polyurethanes incorporating polyhedral oligosilsesquioxane", Biomacromolecules, 9, 2458 (2008).   DOI
54 Y. Ti and D. Chen, "Temperature dependence of hydrogen bond in Fe-OCAP/polyurethane blends", J. Appl. Polym. Sci., 130, 2265 (2013).   DOI
55 Q. Guo, P. T. Knight, J. Wu, and P. T. Mather, "Blends of paclitaxel with POSS-based biodegradable polyurethanes: morphology, miscibility, and specific interactions", Macromolecules, 43, 4991 (2010).   DOI
56 D. Neumann, M. Fisher, L. Tran, and J. G. Matisons, "Synthesis and characterization of an isocyanate functionalized polyhedral oligosilsesquioxane and the subsequent formation of an organic-inorganic hybrid polyurethane", J. Am. Chem. Soc., 124, 13998 (2002).   DOI
57 E. Markovic, K. Nguyen, S. Clarke, K. Constantopoulos, J. Matisons, and G. P. Simon, "Synthesis of POSS-polyurethane hybrids using octakis (m-isoprenyl-${\alpha}$, ${\alpha}^{\prime}$-dimethylbenzylisocyanato dimethylsiloxy) octasilsesquioxane (Q8M8TMI) as a crosslinking agent", J. Polym. Sci., Polym. Chem., 51, 5038 (2013).   DOI
58 L. Verdolotti, S. Colini, G. Porta, and S. Iannace, "Effects of the addition of LiCl, $LiClO_4$, and $LiCF_3SO_3$ salts on the chemical structure, density, electrical, and mechanical properties of rigid polyurethane foam composite", Polym. Eng. Sci., 51, 1137 (2011).   DOI
59 J. Zhang and C. P. Hu, "Synthesis, characterization and mechanical properties of polyester-based aliphatic polyurethane elastomers containing hyperbranched polyester segments", J. Am. Chem. Soc., 44, 3708 (2008).
60 D. Przadka, J. Jeczalik, E. Andrzejewska, B. Marciniec, M. Dutkiewicz, and M. Szlapka, "Novel hybrid polyurethane/POSS materials via bulk polymerization", React. Funct. Polym., 73, 114 (2013).   DOI
61 Y. Wei, F. Cheng, H. Li, and J. Yu, "Synthesis and properties of polyurethane resins based on liquefied wood", J. Appl. Polym. Sci., 92, 351 (2004).   DOI
62 Q. Zhang, H. He, K. Xi, X. Huang, X. Yu, and X. Jia, "Synthesis of N-Phenylaminomethyl POSS and its utilization in polyurethane", Macromolecules, 44, 550 (2011).   DOI
63 S. Vlad, D. Filip, D. Macocinschi, I. Spiridon, A. Nistor, L. M. Gradinaru, and V. E. Musteata, ""New polyetherurethanes based on cellulose derivative for biomedical applications", Optoelectron. Adv. Mater., 4, 407 (2010).
64 K. Y. Mya, Y. Wang, L. Shen, J. Xu, Y. Wu, X. Lu, and C. He, "Star-like polyurethane hybrids with functional cubic silsesquioxanes: Preparation, morphology, and thermomechanical properties", J. Polym. Sci., Polym. Chem., 47, 4602 (2009).   DOI
65 Y. Liu, Y. Ni, and S. Zheng, "Polyurethane networks modified with octa (propylglycidyl ether) polyhedral oligomeric silsesquioxane", Macromol. Chem. Phys., 207, 1842 (2006).   DOI
66 Q. Zhang, X. Huang, X. Wang, X. Jia, and K. Xi, "Rheological study of the gelation of cross-linking polyhedral oligomeric silsesquioxanes (POSS)/PU composites", Polymer, 55, 1282 (2014).   DOI
67 Q. Zhang, X. Huang, Z. Meng, X. Jia, and K. Xi, "N-Phenylaminomethyl hybrid silica, a better alternative to achieve reinforced PU nanocomposites", RSC Adv., 4, 18146 (2014).   DOI
68 G Markevicius, S Chaudhuri, C Bajracharya, R. Rastogi, J. Xiao, C. Burnett, and T. Q. Chastek, "Polyoligomeric silsesquioxane (POSS)-hydrogenated polybutadiene polyurethane coatings for corrosion inhibition of AA2024", Prog. Org. Coat., 75, 319 (2012).   DOI
69 H. Liu and S. Zheng, "Polyurethane networks nanoreinforced by polyhedral oligomeric silsesquioxane", Macromol. Rapid Commun., 26, 196 (2005).   DOI
70 K. Madhavan, D. Gnanasekaran, and B. S. R. Reddy, "Poly (dimethylsiloxane-urethane) membranes: effect of linear siloxane chain and caged silsesquioxane on gas transport properties", J. Polym. Res., 18, 1851 (2011).   DOI
71 K. Madhavan and B. S. R. Reddy, "Synthesis and characterization of polyurethane hybrids: Influence of the polydimethylsiloxane linear chain and silsesquioxane cubic structure on the thermal and mechanical properties of polyurethane hybrids", J. Appl. Polym. Sci., 113, 4052 (2009).   DOI
72 G. H. Lopes, J. Junges, R. Fiorio, M. Zeni, and A. J. Zattera, "Thermoplastic polyurethane synthesis using POSS as a chain modifier", Mater. Res., 15, 698 (2012).   DOI
73 M. Oaten and N. R. Choudhury, "Silsesquioxane-urethane hybrid for thin film applications", Macromolecules, 38, 6392 (2005).   DOI
74 R. Pan, R. Shanks, and L. L. Wang, "Crystallite Cluster Structure Formation Resulting from Semi-Enclosed Cage Interaction in TSI-POSS/PU Hybrid Composites", Advanced Materials Research, 1091, 19 (2015).   DOI
75 R. Pan, R. Shanks, and L. Wang, "Trisilanolisobutyl POSS/polyurethane hybrid composites: preparation, WAXS and thermal properties", Polym. Bull., 71, 2453 (2014).   DOI
76 L. Zheng, S. Hong, G. Cardoen, E. Burgaz, S. P. Gido, and E. B. Coughlin, "Polymer nanocomposites through controlled self-assembly of cubic silsesquioxane scaffolds", Macromolecules, 37, 8606 (2004).   DOI
77 K. Madhavan and B. S. R. Reddy, "Synthesis and characterization of poly (dimethylsiloxane-urethane) elastomers: Effect of hard segments of polyurethane on morphological and mechanical properties", J. Polym. Sci., Polym. Chem., 44, 2980 (2006).
78 K. N. Raftopoulos, S. Koutsoumpis, M. Jancia, et al., "Reduced Phase Separation and Slowing of Dynamics in Polyurethanes with Three-Dimensional POSS-Based Cross-Linking Moieties", Macromolecules, (2015).
79 K. Madhavan and B. S. R. Reddy, "Structure-gas transport property relationships of poly(dimethylsiloxane-urethane) nanocomposite membranes", J. Membrane Sci., 342, 291 (2009).   DOI   ScienceOn
80 V. N. Bliznyuk, T. A. Tereshchenko, M. A. Gumenna, Y. P. Gomza, A. V. Shevchuk, N. S. Klimenko, and V. V. Shevchenko, "Structure of segmented poly(ether urethane)s containing amino and hydroxyl functionalized polyhedral oligomeric silsesquioxanes (POSS)", Polymer, 49, 2298 (2008).   DOI
81 X. Wang, Y. Hu, L. Song, W. Xing, H. Lu, P. Lv, and G. Jie, "UV-curable waterborne polyurethane acrylate modified with octavinyl POSS for weatherable coating applications", J. Polym. Res., 18, 721 (2011).   DOI
82 E. H. Kim, S. W. Myoung, Y. G. Jung, and U. Paik, "Polyhedral oligomeric silsesquioxane-reinforced polyurethane acrylate", Prog. Org. Coat., 64, 205 (2009).   DOI