• 제목/요약/키워드: polymer structure

검색결과 2,254건 처리시간 0.054초

Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • 한국세라믹학회지
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    • 제40권12호
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

Transflective liquid crystal display with single cell gap and simple structure

  • Kim, Mi-Young;Lim, Young-Jin;Jeong, Eun;Chin, Mi-Hyung;Kim, Jin-Ho;Srivastava, Anoop Kumar;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.340-343
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    • 2008
  • This work reports the simple fabrication of the single cell gap transflective liquid crystal display (LCD) using wire grid polarizer. The nano sized wire grid polarizer was patterned on common electrode itself, on the reflective part of FFS (Fringe field switching) mode whereas the common electrode was unpatterned at transmissive part. However, this structure didn't show single gamma curve, so we further improved the device by patterning the common electrode at transmissive part. As a result, V-T curve of proposed structure shows single gamma curve. Such a device structure is free from in-cell retarder, compensation film and reflector and furthermore it is very thin and easy to fabricate.

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모서리가 제거된 팔면체 인장모델을 이용한 다공성 폴리머 박막의 반복변형거동 수치해석 (Numerical Analysis of Cyclic Deformation of Polymer Foam Film Using Stretched Truncated Octahedron Model)

  • 유위경;이영석
    • 한국정밀공학회지
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    • 제27권3호
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    • pp.104-110
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    • 2010
  • Cyclic deformations of polymer foam film are simulated using the finite element method. Material of polymer foam film is polypropylene (PP). The calculated polymer foam film is micro-scale thin film has cellular structure. The polymer foam film is used in ferro-electret applications. The polymer foam film is idealized to one cell structure as lens shaped stretched truncated octahedron model. Cyclic deformation is performed by uniaxial stretching. Stretching direction is perpendicular to plane of cellular film. Various cyclic strain amplitudes, pore wall thicknesses, pore shape are investigated to find deformation tendency of cellular structure. Consequently, cellular structure has various macroscopic stresses on cyclic deformation with various pore thickness and pore shape.

Structures of Two-dimensional Ring Polymer Solutions using Bond Fluctuation Model

  • Shin, Donghan;Lee, Eunsang;Jung, YounJoon
    • EDISON SW 활용 경진대회 논문집
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    • 제5회(2016년)
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    • pp.155-162
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    • 2016
  • This study attempts to reveal structures of two-dimensional ring polymer solutions in various polymer concentrations ranging from dilute to concentrated regime. Polymer sizes, single molecule structure factors, bond correlation functions and monomer density distribution functions from center of mass are given in order to clarify the polymer structures. Our study shows that a ring in dilute solution maintain pseudo-circular structure with self-avoiding walk (SAW) statistics, and it seems to be composed of two connecting SAW linear chains. In semidilute solutions, ring polymers are not entangled with each other and adopt collapsed configurations. Such assumption of collapsed structures in the semidilute regime gives an overlap concentration of ${\varphi}^*{\sim}N^{-1/2}$ where N is degree of polymerization. By normalizing the polymer concentration by these overlap concentration, we find universal behaviors of polymer sizes and structure factors regardless of N.

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X-ray Scattering Studies on the Structure of Porcine Pepsin in Various pH Solutions

  • Jin, Kyeong-Sik;Jin, Sang-Woo;Yoon, Jin-Hwan;Heo, Kyu-Young;Kim, Jae-Han;Kim, Hee-Soo;Ree, Moon-Hor
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.348-348
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    • 2006
  • In the present study, porcine pepsin in various pH conditions was investigated by small-angle X-ray scattering (SAXS) in order to detailed information on the structure and its variations with pH conditions. These analyses identified the structure of pepsin, and compared with that obtained by single crystallography. Moreover, this study found the structure' variations with changing pH conditions. All the results will be discussed with considering the conformational characteristics of pepsin in solution and further correlate to the biological and spectroscopic characteristics reported previously.

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Strain hardening behavior of linear polymer melts

  • Hong Joung Sook;Ahn Kyung Hyun;Lee Seung Jong
    • Korea-Australia Rheology Journal
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    • 제16권4호
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    • pp.213-218
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    • 2004
  • Linear high-density polyethylene (PE) was controlled to induce strain-hardening behavior by introducing a small amount of second component with an anisotropic structure. In order to form an anisotropic structure in the PE matrix, the polymer was extruded through a twin-screw extruder, and the structure was controlled by varying the extrusion conditions. Depending on conditions, the second component formed a film, thread and droplet structure. If the second component was kept rigid, the morphology evolution could be delayed and the second component could maintain its film or thread structure without further relaxation. In par­ticular, the second component of the thread structure made a physical network and gave rise to remarkable strain hardening behavior under high extension. This study suggests a new method that induces strain hard­ening behavior by introducing a physically networked second component into the linear polymer melt. This result is anticipated to improve the processibility of linear polymers especially when extensional flow is dominant, and to contribute to our understanding of strain hardening behavior.

Characterization of Mechanical Property Change in Polymer Aerogels Depending on the Ligand Structure of Acrylate Monomer

  • Lee, Kyu-Yeon;Jung, Hae-Noo-Ree;Mahadik, D.B.;Park, Hyung-Ho
    • 마이크로전자및패키징학회지
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    • 제23권3호
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    • pp.15-20
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    • 2016
  • In an effort to overcome the weakness of aerogel, polymer aerogels have been prepared by copolymerizing the different types of monomers through sol-gel process. Polymerizing the successive phase of a high internal phase emulsion, which has interconnected porous structure, porous polymer aerogel can be manufactured. In this paper, we use the styrene/divinylbenzene chain as a basic monomer structure, and additionally use 2-ethylhexyl methacrylate (2-EHMA) or 2-ethylhexyl acrylate (2-EHA) as monomers for distinguishing the visible mechanical properties of synthesized polymer aerogel. We can observe the different tendency of polymer aerogels by kinds of monomer or ratio. Flexibility and microstructure can be changed by the types of monomer. EHA polymer aerogel shows high flexibility and thin microstructure, and EHMA polymer aerogel shows high hardness and thick microstructure. EHA/EHMA polymer aerogel shows the intermediate nature between them. By utilizing the mechanical properties of three types of polymer aerogels to adequate situation or environment, polymer aerogels could be used as drug agent, ion exchange resin, oil filter and insulator, and so on.

POSS/Polyurethane Hybrids and Nanocomposites: A Review on Preparation, Structure and Performance

  • Diao, Shuo;Mao, Lixin;Zhang, Liqun;Wang, Yiqing
    • Elastomers and Composites
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    • 제50권1호
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    • pp.35-48
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    • 2015
  • Polyhedral oligomeric silsesquioxane (POSS) is an important inorganic-organic hybrid material with a three-dimensional structure. Polyurethane (PU) is a widely applied polymer that has versatile properties with the change of two phase structure. When POSS is incorporated into PU by physical or chemical methods, many properties can be greatly improved, such as mechanical properties, thermal stability, biodegradation resistance, and water resistance. This paper reviews the recent progress in preparation, structure, and performance of POSS-modified polyurethane from the viewpoint of physical blending and chemical modification.

자동차 부품 적용을 위한 Segregated structure를 갖는 전자파 차폐용 고분자 복합소재 연구동향 (Electromagnetic Shielding Polymer Composites with Segregated Structure for Automotive Part Application: A Review)

  • 이진우;서종환
    • Composites Research
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    • 제35권4호
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    • pp.223-231
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    • 2022
  • 최근 미래 모빌리티 시장의 급격한 성장으로 자동차에 전장부품이 다량 탑재되면서 부품간 오작동을 최소화하기 위해 자동차 시장에서도 전자파 차폐에 대한 중요성이 커지고 있다. 이에 따라 전기전도성 고분자 복합소재(Conductive Polymer Composites, CPC)가 자동차용 차폐재로 각광받고 있으나, 산업에 일반적으로 요구되는 20 dB 이상의 전자파 차폐 성능 달성을 위해서는 고 함량의 전도성 필러 충진이 요구되므로 기계적 물성 향상, 원가 절감 측면에서 CPC의 전도성 필러 함량을 줄이기 위한 연구가 필수적이다. 본 논문에서는 이 중 필러 함량을 획기적으로 줄일 수 있는 Segregated structure 필러 네트워크 기반의 CPC를 제조하기 위한 공법들을 소개하고, 각 제조 공법 별 전자파 차폐 성능을 비교하고 분석하였다.

네마틱 백정의 표면 액정 배향에관한 폴리이미드막의 분자 구조의 효과 (Effect of the Molecular Structure of Rubbed Polyimide Films for Surface Liquid Crystal Alignment of Nematic Liquid Crystal)

  • 서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.232-234
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    • 1996
  • We have investigated the effect of molecular structure of polymer of rubbed polyimide (PI) films for surface liquid crystal alignment. To obtain surface alignment effect of Polymer molecular structure, we measured the polar (out of plane-tilt) anchoring strength and surface ordering of 5CB on rubbed PI surfaces. We have found that the polar anchoring strength of 5CB is depend on the polymer molecular structure of these unidirectionally rubbed PI surfaces.

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