• 한국분말재료학회지
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• 제20권1호
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• pp.37-42
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• 2013

$YAG:Ce^{3+}$ phosphor powders were synthesized using a $Al_2O_3$ seed (average particle size: 5 ${\mu}m$) by the polymer solution route. PVA solution was added to the sol precursors consisting of the seed powder and metal nitrate salts for homogeneous mixing in atomic scale. All dried precursor gels were calcined at $500^{\circ}C$ and then heated at $1400^{\circ}C{\sim}1500^{\circ}C$ in $N_2/H_2$ atmosphere. The final powders were characterized by using XRD, SEM, PSA, PL and PKG test. All synthesized powders were crystallized to YAG phase without intermediate phases of YAM or YAP. The phosphor properties and morphologies of the synthesized powders were strongly dependent on the PVA content. Finally, the synthesized $YAG:Ce^{3+}$ phosphor powder heated at $1500^{\circ}C$, which is prepared from 12:1 PVA content and has an average particle size of 15 ${\mu}m$, showed similar phosphor properties to a commercial phosphor powder.

• Archives of Metallurgy and Materials
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• 제66권3호
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• pp.799-802
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• 2021

The nano-sized Y₂O₃ dispersed W composite powder is prepared by ultrasonic spray pyrolysis of a tungsten precursor using ammonium metatungstate hydrate and a polymer addition solution method using Y-nitrate. XRD analysis for calcined powder showed the formation of WO₂ phase by partial oxidation of W powder during calcination in air. The TEM and phase analysis for further hydrogen reduction of calcined powder mixture exhibited that the W powder with a uniform distribution of Y₂O₃ nanoparticles can be successfully produced. These results indicate that the wet chemical method combined with spray pyrolysis and polymer solution is a promising way to synthesis the W-based composites with homogeneous dispersion of fine oxide particles.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
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• pp.196.2-196
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• 2003

• 한국분말재료학회지
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• 제12권4호
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• pp.249-254
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• 2005

Titanium dioxide was prepared by Polymer Complex Solution Method(PCSM) according to the mole ratio of Titanium (IV) isopropoxide(TTIP)/solvent and polymer(Poly Ethylene Glycol). Polymer electrolytes were usually made by dispersing preproduced ceramic nanoparticles in a polymer matrix. Using this method, pure and nano-sized $TiO_2$ powder was synthesized through a simple procedure and polymer entrapment route. At the optimum amount of the polymer, the titanium ions are dispersed in solution and a homogeneous polymeric network is formed. The maximum intensity of anatase phase of $TiO_2$ was achieved by calcining at $500^{\circ}C$ for 2h. The synthesized $TiO_2$ powders were nano-sized and the average size was about 50nm. Anatase/Rutile ratio of the synthesized $TiO_2$ was 70%/30%.

• 한국재료학회지
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• 제28권1호
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• pp.12-17
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• 2018

$In_2O_3$ doped $WO_3$ powders were prepared by a polymer solution route and their $NO_2$ gas sensing properties were analyzed. The synthesized powders showed nano-sized particles with specific surface areas of $6.01{\sim}21.5m^2/g$ and the particle size and shape changed according to the content of $In_2O_3$. The gas sensors fabricated with the synthesized powders were tested at operating temperatures of $400{\sim}500^{\circ}C$ and 100~500 ppm concentrations of $NO_2$ atmosphere. The particle size and $In_2O_3$ content affected on the initial sensor resistance in an air atmosphere. The highest sensitivity (8.57 at $500^{\circ}C$), which was 1.77 higher than the sensor consisting of the pure $WO_3$ sample, was measured in the 0.5 mol% $In_2O_3$ doping sample. In addition, the response time and recovery time were improved by the addition of $In_2O_3$.

• 한국세라믹학회지
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• 제41권2호
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• pp.151-157
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• 2004

안정한 산화물 세라믹스 재료로서 mullite와 cordierite는 우수한 열적, 화학적 특성 때문에 구조재료에서부터 전자재료에 이르는 폭넓은 용도에 사용되어지고 있다. 그럼에도 불구하고, mullite는 천연에서는 산출되지 않기 때문에 합성에 의해서만 제조되고 있다. 또한, cordierite는 합성온도폭이 좁아 고순도의 미립 분말을 제조하기 어려운 재료이다. Mullite 역시 고상반응법 등의 합성법으로는 균질한 재료로의 합성이 어렵다. 그렇기 때문에 sol-gel법 등의 다양한 합성법에 의해 이들 재료에 관한 연구가 계속되고 있다. 본 연구에서는 국내의 원료를 이용하여 sol-gel법에서와 같은 고순도의 미립의 분말을 좀 더 낮은 온도에서 합성이 가능하며, 상대적으로 저가의 원료를 사용함으로서 경제적인 방법인 PVA를 polymer carrier로서 이용한 solution-polymerzation 합성법에 의해 mullite와 cordierite를 합성하였다. 그 결과, mullite, cordierite는 각각 120$0^{\circ}C$, 125$0^{\circ}C$에서 단일의 결정상이 생성되었으며 비표면적 20$m^2$/g 이상의 미립의 분말이 생성됨을 확인할 수 있었다.

• Current Applied Physics
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• 제18권11호
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• pp.1300-1305
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• 2018

The tunable electronic performance of the solution-processed semiconductor metal oxide is of great significance for the printing electronics. In current work, transparent thin-film transistors (TFTs) with indium-zinc oxide (IZO) were fabricated as active layer by a simple eco-friendly aqueous route. The aqueous precursor solution is composed of water without any other organic additives and the IZO films are amorphous revealed by the X-ray diffraction (XRD). With systematic studies of atomic force microscopy (AFM), X-ray photoemission spectroscopy (XPS) and the semiconductor property characterizations, it was revealed that the electrical performance of the IZO TFTs is dependent on the concentration of precursor solution. As well, the optimum preparation process was obtained. The concentrations induced the regulation of the electronic performance was clearly demonstrated with a proposed mechanism. The results are expected to be beneficial for development of solution-processed metal oxide TFTs.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 추계총회 및 연구발표회 초록집
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• pp.116.1-116
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• 2003

• Transactions on Electrical and Electronic Materials
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• 제11권2호
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• pp.54-60
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• 2010

Polymer-assisted deposition is a chemical solution route to high quality thin films. In this process, the polymer controls the viscosity and binds metal ions, resulting in a homogeneous distribution of metal precursors in the solution and the formation of crack-free and uniform films after thermal treatment. We review our recent effort to epitaxially grow metal-nitride thin films, such as hexagonal GaN, cubic TiN, AlN, NbN, and VN, mixed-nitride $Ti_{1-x}Al_xN$, ternary nitrides tetragonal $SrTiN_2$, $BaZrN_2$, and $BaHfN_2$, hexagonal $FeMoN_2$, and nanocomposite TiN-$BaZrN_2$.

• 한국세라믹학회지
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• 제51권5호
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• pp.424-429
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• 2014

YAG:$Ce^{3+}$ phosphor powders were synthesized using $Al(OH)_3$ seeds by means of a PVA-polymer-solution route. Various types of PVA with different molecular weights (different polymerization) were used. All dried precursor gels were calcined at $500^{\circ}C$ and then heated at $1500^{\circ}C$ in a mix of nitrogen and hydrogen gases. The final powders were characterized via XRD, SEM, PSA, PL, and PKG analyses. The phosphor properties and morphologies of the synthesized powders were dependent on the PVA type. As the molecular weight of the PVA was increased, the particle size gradually decreased with agglomeration, and the luminous intensity of the phosphor increased. However, the phosphor powder prepared from the PVA exhibiting very high molecular weight, showed a 531 nm (blue) shift from the 541 nm (yellow) wavelength of the YAG:$Ce^{3+}$ phosphor. Finally, the synthesized YAG:$Ce^{3+}$ phosphor powder prepared from the PVA with 89,000 - 98,000 molecular weight showed phosphor properties similar to those of a commercial phosphor powder, but without a post-treatment process.